Section 2 - Composition, Information on Ingredients

CAS#	Chemical Name	Percent	EINECS/ELINCS
111-90-0	Diethylene glycol monoethyl ether	> 98	203-919-7

Section 3 - Hazards Identification

Appearance: clear, colorless liquid. Flash Point: 91 deg C.
Warning! Causes eye irritation. At elevated temperatures, vapor may cause irritation of eyes and respiratory tract. Combustible liquid and vapor. May form explosive peroxides. May cause kidney damage. Hygroscopic (absorbs moisture from the air).
Target Organs: Kidneys, eyes.


Potential Health Effects
Eye: Causes eye irritation.
Skin: May cause mild skin irritation. Continued absorption may cause kidney damage. A single prolonged skin exposure is not likely to result in the material being absorbed in harmful amounts. Prolonged or widespread skin contact may result in the material being absorbed in harmful amounts.
Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause kidney damage. May cause central nervous system depression.
Inhalation: High vapor concentrations may cause drowsiness. May cause respiratory tract irritation. Low hazard for usual industrial handling. May cause kidney damage. Material has a very low vapor pressure at room temperature, so inhalation exposures are not expected unless material is heated or misted.
Chronic: May cause kidney damage.

Section 4 - First Aid Measures

Eyes: In case of contact, immediately flush eyes with plenty of water for a t least 15 minutes. Get medical aid.
Skin: In case of contact, flush skin with plenty of water. Remove contaminated clothing and shoes. Get medical aid if irritation develops and persists. Wash clothing before reuse.
Ingestion: If swallowed, do not induce vomiting unless directed to do so by medical personnel. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible liquid and vapor.
Extinguishing Media: Use water spray, alcohol foam, CO2, dry chemical.
Flash Point: 91 deg C ( 195.80 deg F)
Autoignition Temperature: 204 deg C ( 399.20 deg F)
Explosion Limits, Lower:1.20 vol %
Upper: 23.5 vol %
NFPA Rating: (estimated) Health: 2; Flammability: 2; Instability: 0

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition. Provide ventilation. Prevent runoff from entering drains, sewers, or streams.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. If peroxide formation is suspected, do not open or move container. Keep away from heat and flame.
Storage: Store in a tightly closed container. After opening, purge container with nitrogen before reclosing. Periodically test for peroxide formation on long-term storage. Addition of water or appropriate reducing materials will lessen peroxide formation. All peroxidizable substances should be stored away from heat and light and be protected from ignition sources.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits

Chemical Name	ACGIH	NIOSH	OSHA - Final PELs
Diethylene glycol monoethyl ether	none listed	none listed	none listed

OSHA Vacated PELs: Diethylene glycol monoethyl ether: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear chemical splash goggles.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to minimize contact with skin.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties

Physical State: Liquid
Appearance: clear, colorless
Odor: Mild fruity characteristic odor.
pH: Not available.
Vapor Pressure: 0.126 mm Hg @ 25 deg C
Vapor Density: 4.6 (air=1)
Evaporation Rate:0.02 (butyl acetate=1)
Viscosity: 4.5 cP @ 20 deg C
Boiling Point: 197 deg C @ 760 mm Hg
Freezing/Melting Point:-80 deg C
Decomposition Temperature:Not available.
Solubility: Soluble.
Specific Gravity/Density:0.99 @ 20/20°C
Molecular Formula:C6H14O3
Molecular Weight:134.17

Section 10 - Stability and Reactivity

Chemical Stability: Hygroscopic: absorbs moisture or water from the air. Under normal storage conditions, peroxidizable compounds can form and accumulate peroxides which may explode when subjected to heat or shock. This material is most hazardous when peroxide levels are concentrated by distillation or evaporation.
Conditions to Avoid: Light, ignition sources, moisture, excess heat, prolonged exposure to air.
Incompatibilities with Other Materials: Strong oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information

RTECS#:      
CAS# 111-90-0: KK8750000
LD50/LC50:
CAS# 111-90-0:
     Dermal, guinea pig: LD50 = >32 gm/kg;
     Draize test, rabbit, eye: 500 mg Moderate;
     Draize test, rabbit, eye: 125 mg Mild;
     Draize test, rabbit, skin: 500 mg/24H Mild;
     Inhalation, rat: LC50 = >5240 mg/m3/4H;
     Oral, mouse: LD50 = 6600 uL/kg;
     Oral, mouse: LD50 = 7250 mg/kg;
     Oral, rabbit: LD50 = 3620 mg/kg;
     Oral, rat: LD50 = 5500 uL/kg;
     Oral, rat: LD50 = 7500 mg/kg;
     Skin, rabbit: LD50 = 4200 uL/kg;
     Skin, rabbit: LD50 = 8.5 ml/kg/2H;
     Skin, rat: LD50 = 6 mL/kg;
.

Carcinogenicity:
CAS# 111-90-0: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: No information found
Neurotoxicity: No information found
Other Studies:

Section 12 - Ecological Information

Ecotoxicity: Fish: Bluegill/Sunfish: >10000 mg/l; 96h; LC50 No data available.
Environmental: Readily biodegradable. No bioaccumulation is to be expoected.
Physical: No information available.
Other: The Koc of diethylene glycol monoethyl ether is estimated as approximately 12, using a measured log Kow of -0.54 and a regression-derived equation. According to a recommended classification scheme, this estimated Koc value suggests that diethylene glycol monoethyl ether has very high mobility in soil.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

	US DOT	Canada TDG
Shipping Name:	Not Regulated	Not Regulated
Hazard Class:
UN Number:
Packing Group:

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 111-90-0 is listed on the TSCA inventory.
Health & Safety Reporting List
     CAS# 111-90-0: Effective 4/13/89, Sunset 12/19/95
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 111-90-0: immediate, fire.
Section 313
     This material contains Diethylene glycol monoethyl ether (listed as Glycol ethers), > 98%, (CAS# 111-90-0) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
     CAS# 111-90-0 (listed as Glycol ethers (except for EGBE)) is listed as      a hazardous air pollutant (HAP).
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 111-90-0 can be found on the following state right to know lists: New Jersey, (listed as Glycol ethers), Pennsylvania, (listed as Glycol ethers), Minnesota.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
     XI
Risk Phrases:
     R 36 Irritating to eyes.

Safety Phrases:
     S 23 Do not inhale gas/fumes/vapour/spray.
     S 26 In case of contact with eyes, rinse immediately with plenty of
     water and seek medical advice.
     S 39 Wear eye/face protection.

WGK (Water Danger/Protection)
     CAS# 111-90-0: 1
Canada - DSL/NDSL
     CAS# 111-90-0 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of D2A, D2B, B3.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 111-90-0 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 6/09/1999
Revision #5 Date: 11/22/2006

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.