Material Safety Data Sheet
Antimony potassium tartrate trihydrate
ACC# 01690
Section 1 - Chemical Product and Company Identification |
MSDS Name: Antimony potassium tartrate trihydrate
Catalog Numbers:
S75046, A867-250, A867-500, NC9453800
Synonyms:
Antimonate(2)-, bis(mu-tartrato(4-))di-, dipotassium, trihydrate;
Antimonyl potassium tartrate; Potassium antimonyl tartrate; Tartaric
acid, antimony potassium salt.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
28300-74-5 |
Antimony potassium tartrate trihydrate |
100 | unlisted |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: colorless or white crystals.
Warning! Harmful if swallowed. Causes eye, skin,
and respiratory tract irritation. May cause liver, kidney and heart
damage.
Target Organs: Kidneys, heart, liver.
Potential Health Effects
Eye:
Causes eye irritation. May cause chemical conjunctivitis.
Skin:
Causes skin irritation.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea.
Inhalation:
May cause nausea, vomiting, abdominal pain, diarrhea, chest
tightness, weakness, and delayed pulmonary edema. Antimony compounds
may enter the body through the lungs. Causes irritation of the mucous
membrane and upper respiratory tract.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Effects may
be delayed. Laboratory experiments have resulted in mutagenic
effects. Prolonged exposure may cause liver, kidney, and heart
damage.
Section 4 - First Aid Measures
|
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. Get medical aid. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
Antidote:
The use of Dimercaprol or BAL (British Anti-Lewisite) as a chelating
agent should be determined by qualified medical personnel.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 2; Flammability: 0; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
Section 7 - Handling and Storage
|
Handling:
Remove contaminated clothing and wash before reuse. Use only in a
well-ventilated area. Minimize dust generation and accumulation.
Avoid breathing dust, mist, or vapor. Avoid contact with eyes, skin,
and clothing. Keep container tightly closed. Do not ingest or
inhale. Wash clothing before reuse.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Antimony potassium tartrate trihydrate
|
0.5 mg/m3 TWA (listed under Antimony).
|
0.5 mg/m3 TWA (listed under Antimony).50 mg/m3 IDLH (listed under Antimony).
|
0.5 mg/m3 TWA (listed under Antimony).
|
OSHA Vacated PELs:
Antimony potassium tartrate trihydrate:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
Section 9 - Physical and Chemical Properties
|
Physical State: Crystals
Appearance: colorless or white
Odor: odorless
pH: slightly acidic
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:100 deg C
Decomposition Temperature:100 deg C
Solubility: 8.3% in water.
Specific Gravity/Density:2.6 @20C
Molecular Formula:C8H4K2O12Sb2.3H2O
Molecular Weight:667.6776
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Mineral acids, tannic acid, gallic acid, alkali hydroxides,
carbonates, lead salts, silver salts, mercury bichloride, lime water,
albumin, alkali carbonates, perchloric acid, soap, strong oxidizing
agents.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, antimony/antimony oxides, oxides of potassium.
Hazardous Polymerization: Will not occur.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 28300-74-5:
CC6825000
LD50/LC50:
CAS# 28300-74-5:
Oral, mouse: LD50
= 600 mg/kg;
Oral, rabbit: LD50 =
115 mg/kg;
Oral, rat: LD50 = 115
mg/kg;
.
Carcinogenicity:
CAS# 28300-74-5:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information available.
Teratogenicity:
No information available.
Reproductive Effects:
No information available.
Mutagenicity:
Cytogenetic Analysis: Human, Fibroblast = 100 umol/L.;
Cytogenetic Analysis: Intraperitoneal, rat = 2 mg/kg.
Neurotoxicity:
No information available.
Other Studies:
Section 12 - Ecological Information
|
Ecotoxicity:
Fish: Fathead Minnow: TLm = 200 ppm; 96 Hr; Antimony (soft
water)
Fish: Fathead Minnow: TLm =12 ppm; 96 Hr; Antimony (hard
water)
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
ANTIMONY POTASSIUM TARTRATE |
No information available. |
Hazard Class: |
6.1 |
|
UN Number: |
UN1551 |
|
Packing Group: |
III |
|
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 28300-74-5 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 28300-74-5: 100 lb final RQ; 45.4 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 28300-74-5: immediate, delayed.
Section 313
This material contains Antimony
potassium tartrate trihydrate (listed as Antimony), 100%, (CAS#
28300-74-5) which is subject to the reporting requirements of Section
313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 28300-74-5 is listed as a Hazardous Substance under the CWA.
CAS# 28300-74-5 is listed as a Priority Pollutant under the Clean
Water Act.
CAS# 28300-74-5 is listed as a Toxic Pollutant under the Clean Water
Act.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 28300-74-5 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, (listed as Antimony), Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
T
Risk Phrases:
R 25 Toxic if swallowed.
Safety Phrases:
S 22 Do not breathe dust.
WGK (Water Danger/Protection)
CAS# 28300-74-5: 3
Canada - DSL/NDSL
CAS# 28300-74-5 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D1B, D2B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 28300-74-5 (listed as Antimony) is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 6/28/1999
Revision #4 Date: 8/23/2006
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.