Section 2 - Composition, Information on Ingredients

CAS#	Chemical Name	Percent	EINECS/ELINCS
110-83-8	Cyclohexene	99.99	203-807-8
128-37-0	2,6-di-tert-butyl-p-cresol	0.01	204-881-4

Section 3 - Hazards Identification

Appearance: clear, colorless liquid. Flash Point: -20 deg C.
Danger! Extremely flammable liquid and vapor. Vapor may cause flash fire. Causes eye, skin, and respiratory tract irritation. May cause central nervous system depression. May form explosive peroxides. This material has been reported to be susceptible to autoxidation and therefore should be classified as peroxidizable.
Target Organs: Central nervous system.


Potential Health Effects
Eye: Causes eye irritation.
Skin: Causes skin irritation.
Ingestion: May cause irritation of the digestive tract. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure.
Inhalation: Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. Causes respiratory tract irritation.
Chronic: Prolonged or repeated skin contact may cause defatting and dermatitis.

Section 4 - First Aid Measures

Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin: Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors can travel to a source of ignition and flash back. Use water spray to keep fire-exposed containers cool. Water may be ineffective. Material is lighter than water and a fire may be spread by the use of water. May form explosive peroxides. Vapors may be heavier than air. They can spread along the ground and collect in low or confined areas. Containers may explode if exposed to fire. Extremely flammable liquid and vapor. Vapor may cause flash fire.
Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. This material is lighter than water and insoluble in water. The fire could easily be spread by the use of water in an area where the water cannot be contained. Do NOT use straight streams of water. For large fires, use dry chemical, carbon dioxide, alcohol-resistant foam, or water spray. Cool containers with flooding quantities of water until well after fire is out.
Flash Point: -20 deg C ( -4.00 deg F)
Autoignition Temperature: 250 deg C ( 482.00 deg F)
Explosion Limits, Lower:1.30 vol %
Upper: 7.70 vol %
NFPA Rating: (estimated) Health: 1; Flammability: 4; Instability: 1

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors. Water spray may reduce vapor but may not prevent ignition in closed spaces.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. If peroxide formation is suspected, do not open or move container. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage: Keep away from heat, sparks, and flame. Keep away from sources of ignition. Do not store in direct sunlight. Store in a tightly closed container. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances. Containers should be dated when opened and tested periodically for the presence of peroxides. Should crystals form in a peroxidizable liquid, peroxidation may have occurred and the product should be considered extremely dangerous. In this instance, the container should only be opened remotely by professionals. All peroxidizable substances should be stored away from heat and light and be protected from ignition sources.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Use explosion-proof ventilation equipment. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits

Chemical Name	ACGIH	NIOSH	OSHA - Final PELs
Cyclohexene	300 ppm TWA	300 ppm TWA; 1015 mg/m3 TWA 2000 ppm IDLH	300 ppm TWA; 1015 mg/m3 TWA
2,6-di-tert-butyl-p-cresol	2 mg/m3 TWA (inhalable fraction and vapor)	10 mg/m3 TWA	none listed

OSHA Vacated PELs: Cyclohexene: 300 ppm TWA; 1015 mg/m3 TWA 2,6-di-tert-butyl-p-cresol: 10 mg/m3 TWA
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties

Physical State: Liquid
Appearance: clear, colorless
Odor: sweetish odor
pH: Not available.
Vapor Pressure: 75 mm Hg @ 20C
Vapor Density: 2.8 (air=1)
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 83 deg C @ 760 mmHg
Freezing/Melting Point:-104 - 0 deg C
Decomposition Temperature:Not available.
Solubility: insoluble
Specific Gravity/Density:.8110g/cm3
Molecular Formula:C6H10
Molecular Weight:82.13

Section 10 - Stability and Reactivity

Chemical Stability: Under normal storage conditions, peroxidizable compounds can form and accumulate peroxides which may explode when subjected to heat or shock. This material is most hazardous when peroxide levels are concentrated by distillation or evaporation.
Conditions to Avoid: Incompatible materials, light, ignition sources, oxidizers.
Incompatibilities with Other Materials: Oxidizing agents and acids..
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information

RTECS#:      
CAS# 110-83-8: GW2500000      
CAS# 128-37-0: GO7875000
LD50/LC50:
CAS# 110-83-8:
     Dermal, guinea pig: LD50 = >20 mL/kg;
     Inhalation, mouse: LC50 = 50000 mg/m3;
     Oral, mouse: LD50 = >3200 uL/kg;
     Oral, mouse: LD50 = 2300 mg/kg;
     Oral, rat: LD50 = 2400 uL/kg;
     Oral, rat: LD50 = 1300 mg/kg;
.

CAS# 128-37-0:
     Draize test, rabbit, eye: 100 mg/24H Moderate;
     Draize test, rabbit, skin: 500 mg/48H Moderate;
     Oral, mouse: LD50 = 650 mg/kg;
     Oral, mouse: LD50 = 1040 mg/kg;
     Oral, rabbit: LD50 = 2100 mg/kg;
     Oral, rat: LD50 = 890 mg/kg;
.
Oral, mice: LD50 = >3.2 mL/kg, Oral, rats: LD50 = 2.40 mL/kg
Carcinogenicity:
CAS# 110-83-8: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 128-37-0: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Mutagenicity: No information available.
Neurotoxicity: No information available.
Other Studies:

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

	US DOT	Canada TDG
Shipping Name:	CYCLOHEXENE	CYCLOHEXENE
Hazard Class:	3	3
UN Number:	UN2256	UN2256
Packing Group:	II	II
Additional Info:		FLASHPOINT -7C

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 110-83-8 is listed on the TSCA inventory.
     CAS# 128-37-0 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 110-83-8: immediate, fire, reactive.
     CAS # 128-37-0: immediate.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 110-83-8 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts.
     CAS# 128-37-0 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
     F
Risk Phrases:
     R 11 Highly flammable.
     R 19 May form explosive peroxides.
     R 21/22 Harmful in contact with skin and if swallowed.
     R 65 Harmful: may cause lung damage if swallowed.

Safety Phrases:
     S 16 Keep away from sources of ignition - No smoking.
     S 36/37 Wear suitable protective clothing and gloves.

WGK (Water Danger/Protection)
     CAS# 110-83-8: 1
     CAS# 128-37-0: 1
Canada - DSL/NDSL
     CAS# 110-83-8 is listed on Canada's DSL List.
     CAS# 128-37-0 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of B2, D2B.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 110-83-8 is listed on the Canadian Ingredient Disclosure List.
     CAS# 128-37-0 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 6/04/1998
Revision #9 Date: 1/22/2009

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.