Material Safety Data Sheet
Octane
ACC# 17260
Section 1 - Chemical Product and Company Identification |
MSDS Name: Octane
Catalog Numbers:
AC129370020, AC129370250, AC129375000, AC325950010, AC325950020,
AC325950025, AC325950250, O3980-1
Synonyms:
n-Octane.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
111-65-9 |
Octane |
>95 | 203-892-1 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: clear, colorless liquid. Flash Point: 13 deg C.
Warning! Flammable liquid and
vapor. Causes eye, skin, and respiratory tract
irritation. Breathing vapors may cause drowsiness and dizziness.
Aspiration hazard if swallowed. Can enter lungs and cause damage.
Target Organs: Central nervous system.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be absorbed through the skin in harmful
amounts. Prolonged and/or repeated contact may cause defatting of
the skin and dermatitis.
Ingestion:
Aspiration hazard. May cause central nervous system depression,
characterized by excitement, followed by headache, dizziness,
drowsiness, and nausea. Advanced stages may cause collapse,
unconsciousness, coma and possible death due to respiratory failure.
Aspiration of material into the lungs may cause chemical
pneumonitis, which may be fatal.
Inhalation:
Causes respiratory tract irritation. May cause narcotic effects in
high concentration.
Chronic:
Prolonged or repeated skin contact may cause defatting and
dermatitis.
Section 4 - First Aid Measures
|
Eyes:
In case of contact, immediately flush eyes with plenty of water for a
t least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
Potential for aspiration if swallowed. Get medical aid immediately.
Do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person. If
vomiting occurs naturally, have victim lean forward.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Use water spray to keep fire-exposed containers
cool. Flammable liquid and vapor. May accumulate static electrical
charges, and may cause ignition of its own vapors. Vapors are
heavier than air and may travel to a source of ignition and flash
back. Vapors can spread along the ground and collect in low or
confined areas. This liquid floats on water and may travel to a
source of ignition and spread fire.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide. Water may be ineffective.
Water may spread fire.
Flash Point: 13 deg C ( 55.40 deg F)
Autoignition Temperature: 206 deg C ( 402.80 deg F)
Explosion Limits, Lower:1.0
Upper: 6.5
NFPA Rating:
(estimated) Health: 1; Flammability: 3; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Provide ventilation.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Ground and bond
containers when transferring material. Use spark-proof tools and
explosion proof equipment. Avoid contact with eyes, skin, and
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep away from heat, sparks and flame.
Do not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or
utilizing this material should be equipped with an eyewash facility
and a safety shower. Use adequate general or local exhaust
ventilation to keep airborne concentrations below the permissible
exposure limits.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Octane
|
300 ppm TWA
|
75 ppm TWA; 350 mg/m3 TWA 1000 ppm IDLH
|
500 ppm TWA; 2350 mg/m3 TWA
|
OSHA Vacated PELs:
Octane:
300 ppm TWA; 1450 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Liquid
Appearance: clear, colorless
Odor: mild odor - gasoline-like
pH: Not available.
Vapor Pressure: 11 mm Hg @ 20 deg C
Vapor Density: 3.9 (air=1)
Evaporation Rate:0.6 (butyl acetate=1)
Viscosity: Not available.
Boiling Point: 124-127 deg C
Freezing/Melting Point:-57 deg C
Decomposition Temperature:Not available.
Solubility: Insoluble.
Specific Gravity/Density:0.708
Molecular Formula:C8H18
Molecular Weight:114.23
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 111-65-9:
RG8400000
LD50/LC50:
CAS# 111-65-9:
Inhalation, rat:
LC50 = 118 gm/m3/4H;
.
Carcinogenicity:
CAS# 111-65-9:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information available.
Teratogenicity:
No information available.
Reproductive Effects:
No information available.
Mutagenicity:
No information available.
Neurotoxicity:
No information available.
Other Studies:
Section 12 - Ecological Information
|
Ecotoxicity:
Water flea EC50 = 0.38 mg/L; 48 Hr.; Unspecified
ConditionsBacteria: Phytobacterium phosphoreum: EC50 = 890 mg/L;
30 minutes; Microtox test
No data available.
Environmental:
No information available.
Physical:
No information available.
Other:
AQUATIC FATE: Photolysis or hydrolysis of n-octane in aquatic systems
is not expected to be important. The biodegradation of n-octane may
occur in aquatic environments, however volatilization and adsorption
are expected to be far more important fate processes. The log
bioconcentration factor (log BCF) for n-octane has been estimated to
range from 2.89 to 3.71suggesting bioconcentration may be an
important factor in aquatic systems. An estimated range for Koc from
5500 to 15,600 indicates n-octane will strongly absorb to carbon.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
OCTANES |
OCTANES |
Hazard Class: |
3 |
3 |
UN Number: |
UN1262 |
UN1262 |
Packing Group: |
II |
II |
Additional Info: | | FLASHPOINT 13C |
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 111-65-9 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 111-65-9: immediate, fire.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 111-65-9 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XN F N
Risk Phrases:
R 11 Highly flammable.
R 38 Irritating to skin.
R 50/53 Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
R 65 Harmful: may cause lung damage if swallowed.
R 67 Vapours may cause drowsiness and dizziness.
Safety Phrases:
S 16 Keep away from sources of ignition - No smoking.
S 29 Do not empty into drains.
S 33 Take precautionary measures against static discharges.
S 9 Keep container in a well-ventilated place.
S 60 This material and its container must be disposed of as hazardou
s waste.
S 61 Avoid release to the environment. Refer to special instructions
/safety data sheets.
S 62 If swallowed, do not induce vomiting: seek medical advice immed
iately and show this container or label.
WGK (Water Danger/Protection)
CAS# 111-65-9: 1
Canada - DSL/NDSL
CAS# 111-65-9 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of B2, D2B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 111-65-9 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 6/08/1999
Revision #6 Date: 5/24/2006
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.