Material Safety Data Sheet
Boron trifluoride etherate, ca. 48% BF3
ACC# 18827
Section 1 - Chemical Product and Company Identification |
MSDS Name: Boron trifluoride etherate, ca. 48% BF3
Catalog Numbers:
AC174560000, AC174560010, AC174560025, AC174560250, AC174561000
Synonyms:
Boron trifluoride ethyl ether.
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
109-63-7 |
Boron trifluoride etherate |
100 | 203-689-8 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: clear straw colored liquid.
Danger! Causes eye and skin burns. Causes
digestive and respiratory tract burns. Water-reactive. Contact with
water liberates extremely flammable gases. Flammable liquid
and vapor. Harmful if swallowed.
Target Organs: Eyes, skin, mucous membranes.
Potential Health Effects
Eye:
Causes eye burns. May cause irreversible eye injury.
Skin:
Causes skin burns.
Ingestion:
Harmful if swallowed. Causes digestive tract burns with immediate
pain, swelling of the throat, convulsions, and possible coma.
Inhalation:
Causes severe irritation of upper respiratory tract with coughing,
burns, breathing difficulty, and possible coma.
Chronic:
No information found.
Section 4 - First Aid Measures
|
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. Can burn in a fire, releasing toxic vapors. Will burn if
involved in a fire.
Extinguishing Media:
Use carbon dioxide or dry chemical.
Flash Point: 110 deg C ( 230.00 deg F)
Autoignition Temperature: 185 deg C ( 365.00 deg F)
Explosion Limits, Lower:5.10 vol %
Upper: 18.20 vol %
NFPA Rating:
(estimated) Health: ; Flammability: ; Instability:
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Wash thoroughly after handling.
Remove contaminated clothing and wash before reuse. Use with
adequate ventilation. Do not breathe dust, mist, or vapor. Do not get
in eyes, on skin, or on clothing. Take precautionary measures against
static discharges. Do not ingest or inhale.
Storage:
Keep away from heat and flame. Store in a cool, dry place. Store in
a tightly closed container. Flammables-area.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits. Facilities storing or utilizing this material should
be equipped with an eyewash facility and a safety shower.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Boron trifluoride etherate
|
none listed
|
none listed
|
2.5 mg/m3 TWA (as dust) (listed under Fluorides).
|
OSHA Vacated PELs:
Boron trifluoride etherate:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Liquid
Appearance: clear straw colored
Odor: Not available.
pH: Not available.
Vapor Pressure: 60 mbar @ 20 C
Vapor Density: 4.9
Evaporation Rate:Not available.
Viscosity: 10.5 deg C
Boiling Point: 126 deg C @ 760 mm Hg
Freezing/Melting Point:-60 deg C
Decomposition Temperature:110 deg C
Solubility: reacts with water
Specific Gravity/Density:1.1280g/cm3
Molecular Formula:C4H10BF3O
Molecular Weight:141.93
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Mechanical shock, ignition sources, temperatures above 50°C (122°F),
exposure to moist air or water.
Incompatibilities with Other Materials:
Acids, bases, alcohols, alkali metals, steel, water, and metals.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, boron trifluoride, diethyl ether,
hydrogen fluoride gas, oxides of boron.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 109-63-7
unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
CAS# 109-63-7:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No data available.
Teratogenicity:
No data available.
Reproductive Effects:
No data available.
Mutagenicity:
No data available.
Neurotoxicity:
No data available.
Other Studies:
Section 12 - Ecological Information
|
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
BORON TRIFLUORIDE DIETHYL ETHERATE |
BORON TRIFLUORIDE DIETHYL ETHERAT |
Hazard Class: |
8 |
8(3) |
UN Number: |
UN2604 |
UN2604 |
Packing Group: |
I |
I |
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 109-63-7 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 109-63-7: immediate, delayed, fire, reactive.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 109-63-7 can be found on the
following state right to know lists: California, (listed as
Fluorides), New Jersey, Pennsylvania, Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
F C
Risk Phrases:
R 15 Contact with water liberates extremely flammable gases.
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face pr
otection.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S 7/8 Keep container tightly closed and dry.
WGK (Water Danger/Protection)
CAS# 109-63-7: No information available.
Canada - DSL/NDSL
CAS# 109-63-7 is listed on Canada's DSL List.
Canada - WHMIS
not available.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 109-63-7 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 9/02/1997
Revision #5 Date: 11/20/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.