Section 2 - Composition, Information on Ingredients

CAS#	Chemical Name	Percent	EINECS/ELINCS
497-19-8	Sodium carbonate anhydrous	< 30	207-838-8
9016-45-9	Ethylene oxide-nonylphenol polymer	< 10	unlisted
25155-30-0	Sodium dodecylbenzenesulfonate	< 10	246-680-4
Not available	Non-hazardous ingredients	> 1	unlisted

Section 3 - Hazards Identification

Appearance: white solid.
Danger! Causes eye burns. Causes skin and respiratory tract irritation. May be harmful if swallowed.
Target Organs: Respiratory system, eyes, skin.


Potential Health Effects
Eye: Contact with eyes may cause severe irritation, and possible eye burns.
Skin: Contact with skin causes irritation and possible burns, especially if the skin is wet or moist.
Ingestion: May cause severe digestive tract irritation with abdominal pain, nausea, vomiting and diarrhea. May be harmful if swallowed.
Inhalation: Causes respiratory tract irritation.
Chronic: Repeated or prolonged exposure contact with concentrated solutions causes tissue damage and ulceration.

Section 4 - First Aid Measures

Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin: Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Material will not burn.
Extinguishing Media: Use extinguishing media most appropriate for the surrounding fire.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 3; Flammability: 1; Instability: 0

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Avoid generating dusty conditions. Provide ventilation.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Discard contaminated shoes.
Storage: Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits

Chemical Name	ACGIH	NIOSH	OSHA - Final PELs
Sodium carbonate anhydrous	none listed	none listed	none listed
Ethylene oxide-nonylphenol polymer	none listed	none listed	none listed
Sodium dodecylbenzenesulfonate	none listed	none listed	none listed
Non-hazardous ingredients	none listed	none listed	none listed

OSHA Vacated PELs: Sodium carbonate anhydrous: No OSHA Vacated PELs are listed for this chemical. Ethylene oxide-nonylphenol polymer: No OSHA Vacated PELs are listed for this chemical. Sodium dodecylbenzenesulfonate: No OSHA Vacated PELs are listed for this chemical. Non-hazardous ingredients: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear chemical splash goggles.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - Physical and Chemical Properties

Physical State: Solid
Appearance: white
Odor: odorless
pH: 9.5-10 in solution.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Moderately soluble in water.
Specific Gravity/Density:Not available.
Molecular Formula:Mixture
Molecular Weight:Not available.

Section 10 - Stability and Reactivity

Chemical Stability: Stable.
Conditions to Avoid: Dust generation.
Incompatibilities with Other Materials: Strong oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, sulfur oxides (SOx), including sulfur oxide and sulfur dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information

RTECS#:      
CAS# 497-19-8: VZ4050000      
CAS# 9016-45-9: AX0247000; AX0257000; MD0900000; MD0905000; OQ0248333; WZ4200000; WZ4375000; WZ4550000; WZ4725000; WZ4750000      
CAS# 25155-30-0: DB6825000
LD50/LC50:
CAS# 497-19-8:
     Draize test, rabbit, eye: 100 mg/24H Moderate;
     Draize test, rabbit, eye: 50 mg Severe;
     Draize test, rabbit, skin: 500 mg/24H Mild;
     Inhalation, mouse: LC50 = 1200 mg/m3/2H;
     Inhalation, rat: LC50 = 2300 mg/m3/2H;
     Oral, mouse: LD50 = 6600 mg/kg;
     Oral, mouse: LD50 = 6600 mg/kg;
     Oral, rat: LD50 = 4090 mg/kg;
.

CAS# 9016-45-9:
     Draize test, rabbit, eye: 5 mg Severe;
     Draize test, rabbit, eye: 5 mg Severe;
     Draize test, rabbit, eye: 20 mg Severe;
     Draize test, rabbit, eye: 100 mg Severe;
     Draize test, rabbit, eye: 15 mg Severe;
     Draize test, rabbit, eye: 5 mg Severe;
     Oral, mouse: LD50 = >50 gm/kg;
     Oral, rat: LD50 = 4 gm/kg;
     Oral, rat: LD50 = 1310 mg/kg;
     Oral, rat: LD50 = 2590 uL/kg;
     Oral, rat: LD50 = >3 gm/kg;
     Oral, rat: LD50 = 4290 uL/kg;
     Oral, rat: LD50 = 3670 uL/kg;

CAS# 25155-30-0:
     Draize test, rabbit, eye: 250 ug/24H Severe;
     Draize test, rabbit, eye: 1% Severe;
     Draize test, rabbit, skin: 20 mg/24H Moderate;
     Oral, mouse: LD50 = 1330 mg/kg;
     Oral, rat: LD50 = 438 mg/kg;
.

Carcinogenicity:
CAS# 497-19-8: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 9016-45-9: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 25155-30-0: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: No information found
Neurotoxicity: No information found
Other Studies:

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

	US DOT	Canada TDG
Shipping Name:	Not regulated as a hazardous material	No information available.
Hazard Class:
UN Number:
Packing Group:

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 497-19-8 is listed on the TSCA inventory.
     CAS# 9016-45-9 is listed on the TSCA inventory.
     CAS# 25155-30-0 is listed on the TSCA inventory.
     Non-hazardous ingredients is not listed on the TSCA inventory. It is for research and development use only.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     CAS# 25155-30-0: 1000 lb final RQ; 454 kg final RQ
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 497-19-8: immediate.
     CAS # 9016-45-9: immediate, delayed, fire.
     CAS # 25155-30-0: immediate.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 25155-30-0 is listed as a Hazardous Substance under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 497-19-8 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
     CAS# 9016-45-9 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
     CAS# 25155-30-0 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Massachusetts.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
      Not available.
Risk Phrases:

Safety Phrases:

WGK (Water Danger/Protection)
     CAS# 497-19-8: 1
     CAS# 9016-45-9: 2
     CAS# 25155-30-0: 2
Canada - DSL/NDSL
     CAS# 497-19-8 is listed on Canada's DSL List.
     CAS# 9016-45-9 is listed on Canada's DSL List.
     CAS# 25155-30-0 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of D2B.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 497-19-8 is listed on the Canadian Ingredient Disclosure List.
     CAS# 25155-30-0 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 7/12/1999
Revision #5 Date: 11/20/2008

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.