Section 2 - Composition, Information on Ingredients

CAS#	Chemical Name	Percent	EINECS/ELINCS
110-75-8	2-Chloroethyl vinyl ether	95	203-799-6

Section 3 - Hazards Identification

Appearance: clear slightly yellow liquid. Flash Point: 16 deg C.
Danger! Harmful if swallowed. Flammable liquid and vapor. Causes eye, skin, and respiratory tract irritation. May form explosive peroxides. This material has been reported to be susceptible to autoxidation and therefore should be classified as peroxidizable.
Target Organs: Respiratory system, eyes, skin.


Potential Health Effects
Eye: Causes eye irritation.
Skin: Causes skin irritation.
Ingestion: Harmful if swallowed. Causes gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation: Causes respiratory tract irritation. Vapors may cause dizziness or suffocation.
Chronic: No information found.

Section 4 - First Aid Measures

Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Flammable liquid and vapor. May form explosive peroxides. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Flash Point: 16 deg C ( 60.80 deg F)
Autoignition Temperature: Not available.
Explosion Limits, Lower:N/A
Upper: N/A
NFPA Rating: (estimated) Health: 2; Flammability: 3; Instability: 2

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Avoid ingestion and inhalation. Wash clothing before reuse. If peroxide formation is suspected, do not open or move container. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Use only with adequate ventilation. Keep away from heat, sparks and flame.
Storage: Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area. After opening, purge container with nitrogen before reclosing. Periodically test for peroxide formation on long-term storage. Addition of water or appropriate reducing materials will lessen peroxide formation. Containers should be dated when opened and tested periodically for the presence of peroxides. Should crystals form in a peroxidizable liquid, peroxidation may have occurred and the product should be considered extremely dangerous. In this instance, the container should only be opened remotely by professionals. All peroxidizable substances should be stored away from heat and light and be protected from ignition sources.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits

Chemical Name	ACGIH	NIOSH	OSHA - Final PELs
2-Chloroethyl vinyl ether	none listed	none listed	none listed
Triethanolamine	5 mg/m3 TWA	none listed	none listed
MEHQ	5 mg/m3 TWA	5 mg/m3 TWA	none listed

OSHA Vacated PELs: 2-Chloroethyl vinyl ether: No OSHA Vacated PELs are listed for this chemical. Triethanolamine: No OSHA Vacated PELs are listed for this chemical. MEHQ: 5 mg/m3 TWA
Personal Protective Equipment
Eyes: Wear chemical splash goggles.
Skin: Wear appropriate gloves to prevent skin exposure.
Clothing: Wear appropriate clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties

Physical State: Liquid
Appearance: clear slightly yellow
Odor: Not available.
pH: Not available.
Vapor Pressure: 27 mm Hg @ 20 deg C
Vapor Density: 3.7 (air=1)
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 109 deg C @ 760 mm Hg
Freezing/Melting Point:-70 deg C
Decomposition Temperature:Not available.
Solubility: Slightly soluble.
Specific Gravity/Density:1.04 g/cm3
Molecular Formula:C4H7ClO
Molecular Weight:106.55

Section 10 - Stability and Reactivity

Chemical Stability: Under normal storage conditions, peroxidizable compounds can form and accumulate peroxides which may explode when subjected to heat or shock. This material is most hazardous when peroxide levels are concentrated by distillation or evaporation.
Conditions to Avoid: Light, ignition sources, excess heat, mechanical shock.
Incompatibilities with Other Materials: Strong oxidizing agents.
Hazardous Decomposition Products: Hydrogen chloride, carbon monoxide, irritating and toxic fumes and gases, carbon dioxide, phosgene gas.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information

RTECS#:      
CAS# 110-75-8: KN6300000      
CAS# 102-71-6: KL9275000      
CAS# 150-76-5: SL7700000
LD50/LC50:
CAS# 110-75-8:
     Oral, rat: LD50 = 210 mg/kg;
     Skin, rabbit: LD50 = 2400 mg/kg;
.

CAS# 102-71-6:
     Draize test, rabbit, eye: 20 mg Severe;
     Draize test, rabbit, eye: 10 mg Mild;
     Draize test, rabbit, skin: 560 mg/24H Mild;
     Oral, mouse: LD50 = 5846 mg/kg;
     Oral, rabbit: LD50 = 2200 mg/kg;
     Oral, rat: LD50 = 4920 uL/kg;
     Skin, rabbit: LD50 = >20 mL/kg;
     Skin, rat: LD50 = >16 mL/kg;
.

CAS# 150-76-5:
     Draize test, rabbit, skin: 6 gm/12D (Intermittent) Mild;
     Draize test, rabbit, skin: 10%;
     Oral, rat: LD50 = 1600 mg/kg;
.

Carcinogenicity:
CAS# 110-75-8: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 102-71-6: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 150-76-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Mutagenicity: No information available.
Neurotoxicity: No information available.
Other Studies:

Section 12 - Ecological Information

Ecotoxicity: No data available. Fish toxicity: LC50 (24-96 hr) bluegill sunfish 452-350 mg/lInvertebrate toxicity: LC50 (48 hr) contact Eisenia foetida 33 µg/cm2LC50 (14 days) absorbed in soil Eisenia foetida 740 mg/kg
Environmental: Terrestrial: Readily leaches through soil and undergoes hydrolysis. Aquatic: Volatilization important fate process. Atmospheric: Undergoes rapid degradation by photochemically-produced hydroxy radicals. Half-life seven hours. Not expected to bioconcentrate but will biodegrade.
Physical: No information available.
Other: No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series:
CAS# 110-75-8: waste number U042.

Section 14 - Transport Information

	US DOT	Canada TDG
Shipping Name:	FLAMMABLE LIQUIDS, TOXIC, N.O.S.	Flammable Liquid, Toxic, N.O.S.
Hazard Class:	3	3
UN Number:	UN1992	UN1992
Packing Group:	II	II

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 110-75-8 is listed on the TSCA inventory.
     CAS# 102-71-6 is listed on the TSCA inventory.
     CAS# 150-76-5 is listed on the TSCA inventory.
Health & Safety Reporting List
     CAS# 110-75-8: Effective 3/7/86, Sunset 12/19/95      CAS# 102-71-6: Effective 4/13/89, Sunset 12/19/95
Chemical Test Rules
     CAS# 150-76-5: 40 CFR 799.5115
Section 12b
     CAS# 150-76-5: Section 4
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     CAS# 110-75-8: 1000 lb final RQ; 454 kg final RQ
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 102-71-6: immediate.
     CAS # 150-76-5: immediate.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.      CAS# 110-75-8 is listed as a Priority Pollutant under the Clean Water      Act.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 110-75-8 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Massachusetts.
     CAS# 102-71-6 can be found on the following state right to know lists: Pennsylvania, Minnesota, Massachusetts.
     CAS# 150-76-5 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
     XN F
Risk Phrases:
     R 11 Highly flammable.
     R 22 Harmful if swallowed.
     R 36/37/38 Irritating to eyes, respiratory system and skin.

Safety Phrases:
     S 16 Keep away from sources of ignition - No smoking.
     S 26 In case of contact with eyes, rinse immediately with plenty of
     water and seek medical advice.
     S 37/39 Wear suitable gloves and eye/face protection.

WGK (Water Danger/Protection)
     CAS# 110-75-8: No information available.
     CAS# 102-71-6: 1
     CAS# 150-76-5: 1
Canada - DSL/NDSL
     CAS# 102-71-6 is listed on Canada's DSL List.
     CAS# 150-76-5 is listed on Canada's DSL List.
     CAS# 110-75-8 is listed on Canada's NDSL List.
Canada - WHMIS
     This product has a WHMIS classification of B2, D1B.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 110-75-8 is listed on the Canadian Ingredient Disclosure List.
     CAS# 102-71-6 is listed on the Canadian Ingredient Disclosure List.
     CAS# 150-76-5 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 9/25/1998
Revision #4 Date: 3/16/2007

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.