Material Safety Data Sheet
Trichloroisocyanuric acid
ACC# 96400
Section 1 - Chemical Product and Company Identification |
MSDS Name: Trichloroisocyanuric acid
Catalog Numbers:
AC175030000, AC175030010, AC175032500, AC421540000, AC421540010, AC421542500
AC421542500, ACE1353283, ACE1353291
Synonyms:
Symclosene; 1,3,5-Trichloro-1-triazine-2,4,6(1H,3H,5H)-trione.
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
87-90-1 |
Trichloroisocyanuric Acid |
97+ | 201-782-8 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: white powder.
Danger! Strong oxidizer. Contact with other
material may cause a fire. Harmful if swallowed, inhaled, or
absorbed through the skin. Causes eye, skin, and respiratory tract
irritation. Contact with acids liberates toxic gas. Toxic to aquatic
organisms, may cause long-term adverse effects in the aquatic
environment. Hygroscopic (absorbs moisture from the air).
Target Organs: Kidneys, liver, respiratory
system, eyes, skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation.
Chronic:
May cause liver and kidney damage.
Section 4 - First Aid Measures
|
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately. Call a poison
control center.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with other material may
cause fire.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Contact professional fire-fighters immediately.
Flash Point: Not applicable.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 2; Flammability: 1; Instability: 2; Special Hazard: OX
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Wear a self contained breathing apparatus and appropriate
personal protection. (See Exposure Controls, Personal Protection
section). Avoid generating dusty conditions. Provide ventilation. Do
not use combustible materials such as paper towels to clean up
spill. Keep combustibles (wood, paper, oil, etc.,) away from spilled
material. Do not let this chemical enter the environment.
Section 7 - Handling and Storage
|
Handling:
Minimize dust generation and accumulation. Do not get in eyes, on
skin, or on clothing. Do not ingest or inhale. Use only in a
chemical fume hood. Keep from contact with clothing and other
combustible materials.
Storage:
Do not store near combustible materials. Store in a cool, dry place.
Store in a tightly closed container. Store under an inert atmosphere.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use only under a
chemical fume hood.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Trichloroisocyanuric Acid
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
Trichloroisocyanuric Acid:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
Section 9 - Physical and Chemical Properties
|
Physical State: Powder
Appearance: white
Odor: None reported.
pH: 3.0 (1% aq.sol.)
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:245 - 251 deg C
Decomposition Temperature:225 deg C
Solubility: 12 g/L (25°C)
Specific Gravity/Density:Not available.
Molecular Formula:C3Cl3N3O3
Molecular Weight:232.41
Section 10 - Stability and Reactivity
|
Chemical Stability:
Hygroscopic: absorbs moisture or water from the air.
Conditions to Avoid:
Incompatible materials, dust generation, combustible materials,
exposure to moist air or water.
Incompatibilities with Other Materials:
Strong bases, strong oxidizing agents, strong reducing agents.
Hazardous Decomposition Products:
Hydrogen chloride, nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 87-90-1:
XZ1925000
LD50/LC50:
CAS# 87-90-1:
Draize test, rabbit,
eye: 500 mg Severe;
Draize test,
rabbit, skin: 500 mg/24H Moderate;
Oral, rat: LD50 = 406 mg/kg;
.
Carcinogenicity:
CAS# 87-90-1:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information found
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
No information found
Neurotoxicity:
No information found
Other Studies:
Section 12 - Ecological Information
|
Ecotoxicity:
No data available.
No information available.
Environmental:
No information available.
Physical:
No information available.
Other:
Do not empty into drains.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
TRICHLOROISOCYANURIC ACID, DRY |
TRICHLOROISOCYANURIC ACID, DRY |
Hazard Class: |
5.1 |
5.1 |
UN Number: |
UN2468 |
UN2468 |
Packing Group: |
II |
II |
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 87-90-1 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 87-90-1: immediate, fire, reactive.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 87-90-1 can be found on the
following state right to know lists: New Jersey, Pennsylvania,
Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XN O N
Risk Phrases:
R 22 Harmful if swallowed.
R 31 Contact with acids liberates toxic gas.
R 36/37 Irritating to eyes and respiratory system.
R 8 Contact with combustible material may cause fire.
R 50/53 Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 41 In case of fire and/or explosion do not breathe fumes.
S 8 Keep container dry.
S 60 This material and its container must be disposed of as hazardou
s waste.
S 61 Avoid release to the environment. Refer to special instructions
/safety data sheets.
WGK (Water Danger/Protection)
CAS# 87-90-1: No information available.
Canada - DSL/NDSL
CAS# 87-90-1 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of C, D1B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 87-90-1 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 9/02/1997
Revision #8 Date: 1/14/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.