Material Safety Data Sheet
Triphenyl phosphate

ACC# 96571
Section 1 - Chemical Product and Company Identification
MSDS Name: Triphenyl phosphate
Catalog Numbers: AC147670000, AC147670010, AC147670025, AC147670030, AC147672500, AC220920000 AC220920000, AC220920050, AC220920500
Synonyms:
TPP.
Company Identification:

              Acros Organics N.V.
              One Reagent Lane
              Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
115-86-6 Triphenyl phosphate 99+ 204-112-2

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: white flakes.
Warning! Causes eye and respiratory tract irritation. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. May cause skin irritation. May cause central nervous system depression.
Target Organs: Central nervous system, liver, respiratory system, eyes.


Potential Health Effects
Eye: Causes eye irritation.
Skin: May cause skin irritation. May be harmful if absorbed through the skin.
Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May be harmful if swallowed. May cause central nervous system depression.
Inhalation: Causes respiratory tract irritation. May be harmful if inhaled. May cause central nervous system effects.
Chronic: Chronic exposure may cause liver damage. High or repeated exposure may damage the nerves causing weakness, "pins and needles," and poor coordination in the arms and

Section 4 - First Aid Measures


Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: Do not induce vomiting. Get medical aid.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam.
Flash Point: 220 deg C ( 428.00 deg F)
Autoignition Temperature: 500 deg C ( 932.00 deg F)
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 2; Flammability: 1; Instability: 0

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Avoid generating dusty conditions. Provide ventilation. Do not let this chemical enter the environment.

Section 7 - Handling and Storage


Handling: Use with adequate ventilation. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale.
Storage: Store in a cool, dry place. Store in a tightly closed container.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Triphenyl phosphate 3 mg/m3 TWA 3 mg/m3 TWA 1000 mg/m3 IDLH 3 mg/m3 TWA

OSHA Vacated PELs: Triphenyl phosphate: 3 mg/m3 TWA
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties


Physical State: Flakes
Appearance: white
Odor: odorless
pH: Not available.
Vapor Pressure: 1.3 hPa @ 193 deg C
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 370 deg C @ 760 mmHg
Freezing/Melting Point:47 - 53 deg C
Decomposition Temperature:Not available.
Solubility: Insoluble.
Specific Gravity/Density:Not available.
Molecular Formula:C18H15O4P
Molecular Weight:326.28

Section 10 - Stability and Reactivity


Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials, dust generation, excess heat.
Incompatibilities with Other Materials: Oxidizing agents.
Hazardous Decomposition Products: Phosphine, carbon monoxide, oxides of phosphorus, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information


RTECS#:      
CAS# 115-86-6: TC8400000
LD50/LC50:
CAS# 115-86-6:
     Dermal, guinea pig: LD50 = >4 gm/kg;
     Oral, mouse: LD50 = 1320 mg/kg;
     Oral, rat: LD50 = 3500 mg/kg;
     Skin, rabbit: LD50 = >7900 mg/kg;
.

Carcinogenicity:
CAS# 115-86-6: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: No information found
Neurotoxicity: No information found
Other Studies:

Section 12 - Ecological Information


Ecotoxicity: Fish: Rainbow trout: LC50 = 0.3 mg/L; 96 Hr.; UnspecifiedFish: Fathead Minnow: LC50 = 0.87 mg/L; 96 Hr.; Flow-throughFish: Bluegill/Sunfish: LC50 = 290.0 mg/L; 96 Hr.; Static ConditionWater flea Daphnia: EC50 = 1.0 mg/L; 48 Hr.; Unspecified No data available.
Environmental: TERRESTRIAL FATE: Biodegradation is expected to be the dominant fate process of triphenyl phosphate (TPP) in soil; screening tests exhibited aerobic half-lives of about 4 days or less in natural waters. Aqueous hydrolysis is expected to aid in soil degradation especially under alkaline conditions (half-lives of 0.23 to 7.5 days at pH 9.5 to pH 8.2). Based on an estimated Koc range of 3,066 to 7,481, TPP should be slightly mobile to immobile in soil. Biodegradation is an important removal process in aerobic waters with aerobic half-lives of about 4 days or less.
Physical: Vapor phase triphenyl phosphate is degraded in the ambient atmosphere by reaction with photochemically formed hydroxyl radicals; the half-life for this reaction in air can be estimated to be about 1.4 days. Particulate phase triphenyl phosphate may be susceptible to dry deposition and wet deposition (rainfall).
Other: Do not empty into drains.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: ENVIRONMENTALLY HAZARDOUS SUBSTANCE (Triphenyl phosphate) ENVIRONMENTALLY HAZARDOUS SUBSTANCE (Triphenyl phosphate)
Hazard Class: 9 9
UN Number: UN3077 UN3077
Packing Group: III III

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 115-86-6 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 115-86-6 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
     N
Risk Phrases:

     R 50/53 Very toxic to aquatic organisms, may cause long-term
     adverse effects in the aquatic environment.

Safety Phrases:

     S 24/25 Avoid contact with skin and eyes.
     S 29 Do not empty into drains.
     S 61 Avoid release to the environment. Refer to special instructions
     /safety data sheets.

WGK (Water Danger/Protection)

     CAS# 115-86-6: 2
Canada - DSL/NDSL
     CAS# 115-86-6 is listed on Canada's DSL List.
Canada - WHMIS
     not available.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 115-86-6 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 6/10/1999
Revision #7 Date: 6/24/2008

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.