Material Safety Data Sheet
Potassium fluoride
ACC# 96771
Section 1 - Chemical Product and Company Identification |
MSDS Name: Potassium fluoride
Catalog Numbers:
AC201350000, AC201350010, AC201350250, AC201352500, AC201355000,
AC212600000, AC212600050, AC212602500, AC9656858, O6113-1, O6113-500
Synonyms:
None.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
7789-23-3 |
Potassium fluoride |
99 | 232-151-5 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: fine crystalline powder.
Warning! Causes irritation and possible burns by
all routes of exposure. Harmful if swallowed, inhaled, or absorbed
through the skin. Long-term exposure may cause bone and joint
changes. Hygroscopic (absorbs moisture from the air).
Target Organs: Respiratory system, skeletal
structures, eyes, skin.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns. Exposure to particulates or solution may cause
conjunctivitis, ulceration, and corneal abnormalities.
Skin:
Harmful if absorbed through the skin. Causes severe skin irritation
and possible burns.
Ingestion:
Harmful if swallowed. Ingestion of large amounts of fluoride may
cause salivation, nausea, vomiting, abdominal pain, fever, labored
breathing. Inorganic fluorides can be harmful. Acute exposure to
fluorine compounds can lead to digestive tract burns, and abdominal
pain. Exposure to fluoride compounds can result in systemic toxic
effects on the heart, liver, and kidneys. It may also deplete
calcium levels in the body leading to hypocalcemia and death.
Fluoride can reduce calcium levels leading to fatal hypocalcemia.
Inhalation:
Inhalation may be fatal as a result of spasm, inflammation, edema of
the larynx and bronchi, chemical pneumonitis and pulmonary edema.
Causes respiratory tract irritation with possible burns.
Chronic:
Chronic inhalation and ingestion may cause chronic fluoride
poisoning (fluorosis) characterized by weight loss, weakness,
anemia, brittle bones, and stiff joints. Chronic exposure to
fluoride compounds may cause systemic toxicity. Skeletal effects may
include bone brittleness, joint stiffness, teeth discoloration,
tendon calcification, and osterosclerosis.
Section 4 - First Aid Measures
|
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 3; Flammability: 0; Instability: 1
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Minimize dust generation and accumulation. Avoid
contact with eyes, skin, and clothing. Use only in a chemical fume
hood. Avoid breathing dust.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Keep containers tightly closed.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Potassium fluoride
|
2.5 mg/m3 TWA (as F) (listed under Fluorides).
|
2.5 mg/m3 TWA (inorganic solids, as F) (listed under Fluorides, inorganic).
|
2.5 mg/m3 TWA (as F) (listed under Fluorides).2.5 mg/m3 TWA (as F) (listed under Fluorides).
|
OSHA Vacated PELs:
Potassium fluoride:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Crystalline powder
Appearance: white - fine
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 1505 deg C @ 760 mmHg
Freezing/Melting Point:860 deg C
Decomposition Temperature:Not available.
Solubility: IN WATER: 92.3 G/100ML (18°C)
Specific Gravity/Density:2.4800 g/cm3
Molecular Formula:FK
Molecular Weight:58.09
Section 10 - Stability and Reactivity
|
Chemical Stability:
Hygroscopic: absorbs moisture or water from the air.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Strong acids.
Hazardous Decomposition Products:
Hydrogen fluoride gas, oxides of potassium.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 7789-23-3:
TT0700000
LD50/LC50:
CAS# 7789-23-3:
Oral, rat: LD50 =
245 mg/kg;
.
Carcinogenicity:
CAS# 7789-23-3:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
Experimental reproductive effects have been reported.
Teratogenicity:
No information found
Reproductive Effects:
Adverse reproductive effects have occurred in experimental
animals.
Mutagenicity:
Mutagenic effects have occurred in experimental animals.
Neurotoxicity:
No information found
Other Studies:
Section 12 - Ecological Information
|
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
POTASSIUM FLUORIDE, SOLID |
POTASSIUM FLUORIDE SOLID |
Hazard Class: |
6.1 |
6.1 |
UN Number: |
UN1812 |
UN1812 |
Packing Group: |
III |
III |
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 7789-23-3 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 7789-23-3: immediate, delayed.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 7789-23-3 can be found on the
following state right to know lists: California, (listed as
Fluorides), California, (listed as Fluorides, inorganic), New Jersey,
Pennsylvania, (listed as Fluorides), Minnesota, (listed as
Fluorides), Minnesota, (listed as Fluorides, inorganic).
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
T
Risk Phrases:
R 23/24/25 Toxic by inhalation, in contact with skin and if
swallowed.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
WGK (Water Danger/Protection)
CAS# 7789-23-3: 1
Canada - DSL/NDSL
CAS# 7789-23-3 is listed on Canada's DSL List.
Canada - WHMIS
not available.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 7789-23-3 (listed as Fluorides, inorganic) is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 9/02/1997
Revision #7 Date: 6/06/2006
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.