Material Safety Data Sheet
Potassium antimonyl-tartrate hemihydrate 99+%
ACC# 00249
Section 1 - Chemical Product and Company Identification |
MSDS Name: Potassium antimonyl-tartrate hemihydrate 99+%
Catalog Numbers:
AC223800000, AC223800050, AC223801000, AC223805000
Synonyms:
Antimony potassium tartrate; Potassium antimonyl d-tartrate
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
28300-74-5 |
ANTIMONY POTASSIUM TARTRATE |
99+% | unlisted |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: fine crystalline powder.
Warning! Harmful if inhaled or swallowed. Toxic to
aquatic organisms, may cause long-term adverse effects in the aquatic
environment. May cause liver damage.
Target Organs: Liver.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea. May cause liver damage. May cause
headache.
Inhalation:
Harmful if inhaled. May cause respiratory tract irritation.
Inhalation of fumes may cause metal fume fever, which is
characterized by flu-like symptoms with metallic taste, fever,
chills, cough, weakness, chest pain, muscle pain and increased white
blood cell count. The toxicological properties of this substance have
not been fully investigated.
Chronic:
No information found.
Section 4 - First Aid Measures
|
Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
Call a poison control center. If swallowed, do not induce vomiting
unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Substance is noncombustible.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam.
Flash Point: 100 deg C ( 212.00 deg F)
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 2; Flammability: 1; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid generating dusty conditions. Do not let this
chemical enter the environment.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Minimize dust generation and
accumulation. Avoid contact with skin and eyes. Avoid ingestion and
inhalation. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
ANTIMONY POTASSIUM TARTRATE
|
0.5 mg/m3 TWA (listed under Antimony).
|
0.5 mg/m3 TWA (listed under Antimony).50 mg/m3 IDLH (listed under Antimony).
|
0.5 mg/m3 TWA (listed under Antimony).
|
OSHA Vacated PELs:
ANTIMONY POTASSIUM TARTRATE:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Crystalline powder
Appearance: white - fine
Odor: Odorless.
pH: 3 - 5 (5% aq.sol.)
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:100 deg C
Decomposition Temperature:100 deg C
Solubility: 8.3%
Specific Gravity/Density:Not available.
Molecular Formula:C4H4O7SbK.0.5H2O
Molecular Weight:333.92
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, bases, carbonates.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, antimony/antimony oxides, oxides of
potassium.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 28300-74-5:
CC6825000
LD50/LC50:
CAS# 28300-74-5:
Oral, mouse: LD50
= 600 mg/kg;
Oral, rabbit: LD50 =
115 mg/kg;
Oral, rat: LD50 = 115
mg/kg;
.
Carcinogenicity:
CAS# 28300-74-5:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
Present evidence in humans is inconclusive concerning
increased risk of lung cancer and reproductive disorders
from antimony exposure.
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
Mutation:cyt-hmn-fbr 100 µmol/Lcyt-rat-ipr 2 mg/kg
Neurotoxicity:
No information found
Other Studies:
Section 12 - Ecological Information
|
Ecotoxicity:
No data available.
Water Danger/Protection: WGK 2
Environmental:
No information available.
Physical:
No information available.
Other:
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
ANTIMONY POTASSIUM TARTRATE |
ANTIMONY POTASSIUM TARTRATE |
Hazard Class: |
6.1 |
6.1 |
UN Number: |
UN1551 |
UN1551 |
Packing Group: |
III |
III |
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 28300-74-5 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 28300-74-5: 100 lb final RQ; 45.4 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 28300-74-5: immediate, delayed.
Section 313
This material contains ANTIMONY
POTASSIUM TARTRATE (listed as Antimony), 99+%, (CAS# 28300-74-5)
which is subject to the reporting requirements of Section 313 of
SARA Title III and 40 CFR Part 373.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 28300-74-5 is listed as a Hazardous Substance under the CWA.
CAS# 28300-74-5 is listed as a Priority Pollutant under the Clean
Water Act.
CAS# 28300-74-5 is listed as a Toxic Pollutant under the Clean Water
Act.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 28300-74-5 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, (listed as Antimony), Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XN N
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
R 51/53 Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
Safety Phrases:
S 61 Avoid release to the environment. Refer to special instructions
/safety data sheets.
WGK (Water Danger/Protection)
CAS# 28300-74-5: 3
Canada - DSL/NDSL
CAS# 28300-74-5 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D1B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 28300-74-5 (listed as Antimony) is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 8/24/1997
Revision #5 Date: 8/09/2006
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.