Material Safety Data Sheet
Diethyl Phthalate,99%
ACC# 00534
Section 1 - Chemical Product and Company Identification |
MSDS Name: Diethyl Phthalate,99%
Catalog Numbers:
AC114520000, AC114520010, AC114520025, AC114520200, AC114520250
Synonyms:
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
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CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
84-66-2 | Diethyl Phthalate |
99 | 201-550-6 |
Hazard Symbols: XI
Risk Phrases: 36/37/38
Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: colorless liquid.
Caution! Causes respiratory tract irritation. May
cause central nervous system depression. May cause fetal effects
based upon animal studies. Causes eye and skin irritation. May cause
digestive tract irritation.
Target Organs: Central nervous system.
Potential Health Effects
Eye:
Contact produces irritation, tearing, and burning pain.
Skin:
Causes skin irritation.
Ingestion:
Ingestion of large amounts may cause gastrointestinal irritation.
Inhalation:
Causes respiratory tract irritation. May cause narcotic effects in
high concentration.
Chronic:
May cause fetal effects.
Section 4 - First Aid Measures
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Eyes:
Flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers.
Flash Point: 160 deg C ( 320.00 deg F)
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
1 - health, 1 - flammability, 0 - instability
Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry,
closed container for disposal.
Section 7 - Handling and Storage
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Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Avoid contact with eyes, skin, and clothing. Avoid ingestion and
inhalation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Diethyl Phthalate | 5 mg/m3 TWA |
5 mg/m3 TWA | none listed |
OSHA Vacated PELs:
Diethyl Phthalate:
5 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Always use
a NIOSH or European Standard EN 149 approved
respirator when necessary.
Section 9 - Physical and Chemical Properties
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Physical State: Liquid
Appearance: colorless
Odor: Odorless.
pH: Not available.
Vapor Pressure: 14 mm Hg @163C
Vapor Density: 7.66
Evaporation Rate:Not available.
Viscosity: 12 cPs 20 deg C
Boiling Point: 298 - 299 deg C @ 760.00mm Hg
Freezing/Melting Point:-3 deg C
Decomposition Temperature:Not available.
Solubility: IN WATER: 0.15% (25°C)
Specific Gravity/Density:1.1180g/cm3
Molecular Formula:C12H14O4
Molecular Weight:222.24
Section 10 - Stability and Reactivity
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Chemical Stability:
Stable.
Conditions to Avoid:
Not available.
Incompatibilities with Other Materials:
Strong acids such as nitric acid, strong oxidizing agents, and
permanganates.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
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RTECS#:
CAS# 84-66-2: TI1050000
LD50/LC50:
CAS# 84-66-2:
Draize test, rabbit, eye: 112 mg;
Oral, mouse:
LD50 = 6172 mg/kg;
Oral, rabbit: LD50 = 1 gm/kg;
Oral, rat:
LD50 = 8600 mg/kg;
Carcinogenicity:
CAS# 84-66-2:
ACGIH: A4 - Not Classifiable as a Human Carcinogen
Epidemiology:
No data available.
Teratogenicity:
No data available.
Reproductive Effects:
No data available.
Neurotoxicity:
No data available.
Mutagenicity:
No data available.
Other Studies:
No data available.
Section 12 - Ecological Information
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No information available.
Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: CAS# 84-66-2: waste number
U088.
Section 14 - Transport Information
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US DOT |
IATA |
RID/ADR |
IMO |
Canada TDG |
Shipping Name: |
No information available. |
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No information available. |
Hazard Class: |
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UN Number: |
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Packing Group: |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 84-66-2 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA
CERCLA Hazardous Substances and corresponding RQs
CAS# 84-66-2: 1000 lb final RQ; 454 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product are listed as Hazardous
Substances under the CWA.
CAS# 84-66-2 is listed as a Priority Pollutant under the Clean Water
Act.
None of the chemicals in this product are listed as Toxic Pollutants
under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous
by OSHA.
STATE
CAS# 84-66-2 can be found on the following state right to know
lists: California, New Jersey, Pennsylvania, Minnesota,
Massachusetts.
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 84-66-2: 2
Canada - DSL/NDSL
CAS# 84-66-2 is listed on Canada's DSL List.
Canada - WHMIS
WHMIS: Not available.
Canadian Ingredient Disclosure List
CAS# 84-66-2 is listed on the Canadian Ingredient Disclosure List.
Exposure Limits
CAS# 84-66-2: OEL-AUSTRALIA:TWA 5 mg/m3 OEL-BELGIUM:TWA 5 mg/m3 OE
L-DENMARK:TWA 5 mg/m3 OEL-FINLAND:TWA 5 mg/m3;STEL 10 mg/m3;Skin OEL
-FRANCE:TWA 5 mg/m3 OEL-THE NETHERLANDS:TWA 5 mg/m3 OEL-RUSSIA:STEL
0.5 mg/m3 OEL-SWEDEN:TWA 3 mg/m3;STEL 5 mg/m3 OEL-SWITZERLAND:TWA 5
mg/m3 OEL-UNITED KINGDOM:TWA 5 mg/m3;STEL 10 mg/m3 JAN9 OEL IN BULGA
RIA, COLOMBIA, JORDAN, KOREA check ACGIH TLV OEL IN NEW ZEALAND, SING
APORE, VIETNAM check ACGI TLV
Section 16 - Additional Information
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MSDS Creation Date: 3/05/1998
Revision #3 Date: 3/18/2003
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.