Material Safety Data Sheet
Lead(II) oxide, 99.7%
MSDS Name: Lead(II) oxide, 99.7%
Section 1 - Chemical Product and Company Identification
AC199340000, AC199340010, AC199340050, AC199345000
Lead monooxide, Lead protoxide, Litharge; Lead(II) oxide; C.I. 77577;
C.I. Pigment Yellow 46; Lead oxide yellow; Plumbous oxide.
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
|| 99.7 ||215-267-0
Section 3 - Hazards Identification
Appearance: red or yellow.
Caution! May be harmful if inhaled. May cause eye
and skin irritation. May be harmful if swallowed. May cause
respiratory tract irritation. May cause kidney damage. May cause
central nervous system effects. This product contains lead, a
chemical known to the state of California to cause male reproductive
Target Organs: Blood, kidneys, central nervous
system, reproductive system.
Potential Health Effects
May cause eye irritation.
May cause skin irritation.
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. May cause kidney damage. Ingestion of large amounts may
cause CNS depression. Ingestion of large quantities may cause severe
hemolytic anemia and hemoglobinuria.
May cause respiratory tract irritation. May cause effects similar to
those described for ingestion. May be harmful if inhaled.
Prolonged or repeated exposure may cause adverse reproductive
effects. Chronic exposure may cause visual disturbances.
Section 4 - First Aid Measures
Flush eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid.
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
The use of a metal chelator should be determined only by qualified
Section 5 - Fire Fighting Measures
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Flash Point: Not applicable.
Autoignition Temperature: Not available.
Explosion Limits, Lower:N/A
(estimated) Health: ; Flammability: 0; Instability: 0
Section 6 - Accidental Release Measures
General Information: Use proper personal protective equipment as indicated
in Section 8.
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Section 7 - Handling and Storage
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Use only with
adequate ventilation. Avoid breathing dust.
Store in a cool, dry, well-ventilated area away from incompatible
substances. Keep containers tightly closed.
Section 8 - Exposure Controls, Personal Protection
Local exhaust ventilation may be necessary to control any air
contaminants to within their TLVs during the use of this product.
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower.
||OSHA - Final PELs|
0.05 mg/m3 TWA (as Pb) (listed under Lead, inorganic compounds).
0.050 mg/m3 TWA (as Pb) (listed under Lead compounds).
50 ęg/m3 TWA (as Pb) (listed under Lead, inorganic compounds).50 ęg/m3 TWA (as Pb); 30 ęg/m3 Action Level (as Pb. Poison - see 29 CFR 1910.10 25) (listed under Lead, inorganic compounds).
OSHA Vacated PELs:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Wear appropriate gloves to prevent skin exposure.
Wear appropriate protective clothing to minimize
contact with skin.
Refer to 29 CFR1910.1025 for regulations on
respiratory protection required during exposure to
lead and lead compounds.
Section 9 - Physical and Chemical Properties
Physical State: Crystals
Appearance: red or yellow
Odor: None reported
pH: Strong base
Vapor Pressure: 10 mm Hg @ 1085C
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 1470 deg C
Freezing/Melting Point:886 deg C
Decomposition Temperature:Not available.
Section 10 - Stability and Reactivity
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Dust generation, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, hydrogen peroxide, lithium carbide,
perchloric acid, powdered aluminum, hydrogen trisulfide.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, lead/lead oxides.
Hazardous Polymerization: Has not been reported
Section 11 - Toxicological Information
rabbit, skin: 100 mg/24H Mild;
- ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to humans (listed as 'Lead, inorganic compounds').
- California: carcinogen, initial date 10/1/92 (listed as Lead compounds).
- NTP: Suspect carcinogen (listed as Lead compounds).
- IARC: Group 2A carcinogen (listed as Lead, inorganic compounds).
No information available.
Lead has been shown to cause teratogenic effects.
Lead has been shown to cause reproductive effects.
No information available.
Lead has been shown to cause neurotoxic effects.
Section 12 - Ecological Information
No information available.
Section 13 - Disposal Considerations
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
||LEAD COMPOUNDS, SOLUBLE, N.O.S.
||LEAD COMPOUND SOLUBLE NOS (LEAD III OXIDE)
Section 15 - Regulatory Information
CAS# 1317-36-8 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
CAS # 1317-36-8: immediate, delayed.
This material contains Lead
monooxide (listed as Lead, inorganic compounds), 99.7%, (CAS#
1317-36-8) which is subject to the reporting requirements of Section
313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
CAS# 1317-36-8 (listed as Lead compounds) is listed as a hazardous air
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
CAS# 1317-36-8 is listed as a Toxic Pollutant under the Clean Water
None of the chemicals in this product
are considered highly hazardous by OSHA.
CAS# 1317-36-8 can be found on the
following state right to know lists: California, (listed as Lead
compounds), New Jersey, (listed as Lead, inorganic compounds), New
Jersey, (listed as Lead compounds), Pennsylvania, (listed as Lead
compounds), Minnesota, (listed as Lead, inorganic compounds),
California Prop 65
The following statement(s) is(are) made in order to comply with
the California Safe Drinking Water Act:
WARNING: This product contains Lead monooxide, listed as `Lead
compounds', a chemical known to the state of California to cause
WARNING: This product contains Lead monooxide, listed as `Lead,
inorganic compounds', a chemical known to the state of California to
cause developmental reproductive toxicity.
California No Significant Risk Level:
None of the chemicals in this product are listed.
European Labeling in Accordance with EC Directives
R 20/22 Harmful by inhalation and if swallowed.
R 33 Danger of cumulative effects.
R 61 May cause harm to the unborn child.
R 62 Possible risk of impaired fertility.
R 50/53 Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S 53 Avoid exposure - obtain special instructions before use.
S 60 This material and its container must be disposed of as hazardou
S 61 Avoid release to the environment. Refer to special instructions
/safety data sheets.
WGK (Water Danger/Protection)
CAS# 1317-36-8: 1
Canada - DSL/NDSL
CAS# 1317-36-8 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D2A.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 1317-36-8 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
MSDS Creation Date: 4/17/1998
Revision #4 Date: 9/26/2007
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.