Material Safety Data Sheet
Mercury (II) Iodide, Red, P.A.

ACC# 00948
Section 1 - Chemical Product and Company Identification
MSDS Name: Mercury (II) Iodide, Red, P.A.
Catalog Numbers: AC205740000, AC205740050, AC205741000, AC205745000
Synonyms:
Mercuric Iodide; Mercury Diiodide; Red Mercuric Iodide.
Company Identification:

              Acros Organics N.V.
              One Reagent Lane
              Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
7774-29-0 MERCURIC IODIDE ca 100 231-873-8

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: red solid.
Danger! Highly toxic. Poison! Causes digestive and respiratory tract burns. Causes eye and skin burns. Light sensitive. This substance has caused adverse reproductive and fetal effects in animals. May cause kidney damage. May cause central nervous system effects.
Target Organs: Kidneys, central nervous system.


Potential Health Effects
Eye: Contact may cause severe eye irritation and possible eye damage.
Skin: May cause severe skin irritation. May be absorbed through the skin.
Ingestion: May be fatal if swallowed. Poison by ingestion. May cause kidney damage. May cause severe digestive tract irritation with abdominal pain, nausea, vomiting and diarrhea. May cause corrosion and permanent tissue destruction of the esophagus and digestive tract. Can cause nervous system damage.
Inhalation: May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. May cause effects similar to those described for ingestion.
Chronic: Chronic inhalation and ingestion may cause effects similar to those of acute inhalation and ingestion. Prolonged or repeated exposure may cause adverse reproductive effects. May cause fetal effects.

Section 4 - First Aid Measures


Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid imme diately.
Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation.
Notes to Physician: Treat symptomatically and supportively.
Antidote: The use of Dimercaprol or BAL (British Anti-Lewisite) as a chelating agent should be determined by qualified medical personnel.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Combustion generates toxic fumes.
Extinguishing Media: For small fires, use water spray, dry chemical, carbon dioxide or chemical foam.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 3; Flammability: 0; Instability: 0

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Clean up spills immediately, observing precautions in the Protective Equipment section. Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale. Store protected from light.
Storage: Do not store in direct sunlight. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances. Poison room locked.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
MERCURIC IODIDE 0.025 mg/m3 TWA (as Hg) (listed under Mercury inorganic compounds).Skin - potential significant contribution to overall exposure by the cutaneous r oute (listed under Mercury inorganic compounds). 0.05 mg/m3 TWA (vapor, except organo alkyls, as Hg) (listed under Mercury compounds).10 mg/m3 IDLH (as Hg, except organo(alkyl) compounds) (listed under Mercury compounds). none listed

OSHA Vacated PELs: MERCURIC IODIDE: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties


Physical State: Solid
Appearance: red
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 350 deg C
Freezing/Melting Point:259 deg C
Decomposition Temperature:Not available.
Solubility: Insoluble in water.
Specific Gravity/Density: 6.3600
Molecular Formula:HgI2
Molecular Weight:454.399

Section 10 - Stability and Reactivity


Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: High temperatures, incompatible materials, light, dust generation, excess heat.
Incompatibilities with Other Materials: Strong oxidizing agents, chlorine trifluoride, potassium, sodium, light.
Hazardous Decomposition Products: Hydrogen iodide, mercury/mercury oxides.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information


RTECS#:      
CAS# 7774-29-0: OW5250000
LD50/LC50:
CAS# 7774-29-0:
     Oral, mouse: LD50 = 17 mg/kg;
     Oral, rat: LD50 = 18 mg/kg;
     Skin, rat: LD50 = 75 mg/kg;
.

Carcinogenicity:
CAS# 7774-29-0: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information available.
Teratogenicity: Embryo or Fetus: Death, inhalation-rat TCLo=4870ng/m3/24H; Extra-embryonic structures, inhalation-rat TCLo=450 ng/m3/24H; Fetotoxicity, inhalation-rat TCLo=450ng/m3/24H.
Reproductive Effects: Fertility: Post-implantation mortality, inhalation-rat TCLo=4870ng/m3/24H.
Mutagenicity: Please refer to RTCES# OW5250000 for specific information.
Neurotoxicity: No information available.
Other Studies:

Section 12 - Ecological Information


Ecotoxicity: No data available. No information available.
Environmental: No information reported.
Physical: No information available.
Other: None.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: MERCURY IODIDE MERCURY IODIDE, SOLID
Hazard Class: 6.1 6.1
UN Number: UN1638 UN1638
Packing Group: II II

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 7774-29-0 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 7774-29-0: immediate, delayed.
Section 313
     This material contains MERCURIC IODIDE (listed as Mercury compounds), ca 100%, (CAS# 7774-29-0) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
     CAS# 7774-29-0 (listed as Mercury compounds) is listed as a hazardous      air pollutant (HAP).
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA. CAS# 7774-29-0 is listed as a Toxic Pollutant under the Clean Water Act.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 7774-29-0 can be found on the following state right to know lists: California, (listed as Mercury compounds), New Jersey, Pennsylvania, (listed as Mercury compounds).

California Prop 65
WARNING: This product contains MERCURIC IODIDE, listed as `Mercury compounds', a chemical known to the state of California to cause developmental reproductive toxicity.
California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
     T+
Risk Phrases:

     R 26/27/28 Very toxic by inhalation, in contact with skin and if
     swallowed.
     R 33 Danger of cumulative effects.

Safety Phrases:

     S 13 Keep away from food, drink and animal feeding stuffs.
     S 28 After contact with skin, wash immediately with...
     S 45 In case of accident or if you feel unwell, seek medical advice
     immediately (show the label where possible).

WGK (Water Danger/Protection)

     CAS# 7774-29-0: 3
Canada - DSL/NDSL
     CAS# 7774-29-0 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of D1A, D2A.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 7774-29-0 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 9/02/1997
Revision #6 Date: 11/06/2007

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.