Section 2 - Composition, Information on Ingredients

CAS#	Chemical Name	Percent	EINECS/ELINCS
7789-00-6	Potassium chromate		232-140-5

Hazard Symbols: T N
Risk Phrases: 36/37/38 43 46 49 50/53

Section 3 - Hazards Identification

Not available. Appearance: yellow crystals. Not available.
Target Organs: Blood, kidneys, liver, lungs, respiratory system, eyes, skin.


Potential Health Effects
Eye: Contact with eyes may cause severe irritation, and possible eye burns. Exposure to particulates or solution may cause conjunctivitis, ulceration, and corneal abnormalities.
Skin: May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. Contact with skin causes irritation and possible burns, especially if the skin is wet or moist. May cause deep, penetrating ulcers of the skin. May cause dermatitis.
Ingestion: May cause liver and kidney damage. May cause severe digestive tract irritation with abdominal pain, nausea, vomiting and diarrhea. Ingestion may cause violent gastroenteritis, circulatory collapse and kidney damage.
Inhalation: May cause asthmatic attacks due to allergic sensitization of the respiratory tract. May cause ulceration and perforation of the nasal septum if inhaled in excessive quantities. May cause severe irritation of the upper respiratory tract with pain, burns, and inflammation. May cause chemical bronchitis with coughing and difficulty in breathing.
Chronic: Chronic inhalation and ingestion may cause effects similar to those of acute inhalation and ingestion. Prolonged or repeated exposure may lead to asthma and perforation of the nasal septum. Repeated inhalation may cause chronic bronchitis. May cause liver and kidney damage. May cause cancer according to animal studies.

Section 4 - First Aid Measures

Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin: Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: Do NOT induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician: Monitor renal, hepatic, cardiovascular, and pulmonary function. Hemodialysis may be indicated if renal failure develops. (Genium MSDS No. 744, Issued: 7/91)

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with combustible materials may cause a fire.
Extinguishing Media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: ; Flammability: ; Instability:; Special Hazard: OX

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container.

Section 7 - Handling and Storage

Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage: Do not store near combustible materials. Store in a cool, dry place. Store in a tightly closed container.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits

Chemical Name	ACGIH	NIOSH	OSHA - Final PELs
Potassium chromate	none listed	none listed	none listed

OSHA Vacated PELs: Potassium chromate: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Not available.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to minimize contact with skin.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Always use a NIOSH or European Standard EN 149 approved respirator when necessary.

Section 9 - Physical and Chemical Properties

Physical State: Crystals
Appearance: yellow
Odor: odorless
pH: 8.6-9.8 @ 50 g/l aq.sol.
Vapor Pressure: Not applicable.
Vapor Density: 6.7
Evaporation Rate:Not applicable.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:975 deg C
Decomposition Temperature:Not available.
Solubility: 64gr/100ml water (20°C)
Specific Gravity/Density:2.7320g/cm3
Molecular Formula:K2CrO4
Molecular Weight:194.20

Section 10 - Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials, combustible materials.
Incompatibilities with Other Materials: Strong oxidizing agents, reducing agents, hydrazine.
Hazardous Decomposition Products: Oxides of potassium.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information

RTECS#:
CAS# 7789-00-6: GB2940000
LD50/LC50:
CAS# 7789-00-6:
Oral, mouse: LD50 = 180 mg/kg;
Carcinogenicity:
CAS# 7789-00-6:
ACGIH: A1 - Confirmed Human Carcinogen (listed as Chromium (VI) compounds- water solubl
California: carcinogen; initial date 2/27/87 (listed as Chromium (VI) compounds).
NTP: Known carcinogen (listed as Chromium (VI) compounds).
OSHA: Select carcinogen (listed as Chromium (VI) compounds).
IARC: IARC Group 3 - not classifiable (listed as Chromium).
Epidemiology: According to IARC sufficient evidence exists for potassium c hromate to be considered a carcinogen in humans. (RTECS Oc tober, 1994)
Teratogenicity: No data available.
Reproductive Effects: Potassium chromate has been shown to cause reproductive effects in animal studies.
Neurotoxicity: No data available.
Mutagenicity: Potassium chromate has been shown to cause mutagenic effects in animal studies.
Other Studies: May cause reproductive effects. Mutagen. The toxicological properties have not been fully investigated.

Section 12 - Ecological Information

Ecotoxicity: Fish: Fathead Minnow: LC50 = 75 mg/L; 96H; . ia: LC50 = 75 mg/L; 48H; . No data available.
Environmental: No information available.
Physical: No information available.
Other: Do not empty into drains.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

	US DOT	IATA	RID/ADR	IMO	Canada TDG
Shipping Name:	Oxidizing Solid, Toxic, N.O.S.*				No information available.
Hazard Class:	5.1
UN Number:	UN3087
Packing Group:	III

Section 15 - Regulatory Information

US FEDERAL

TSCA
CAS# 7789-00-6 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
CAS# 7789-00-6: 6/12b
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
SARA

CERCLA Hazardous Substances and corresponding RQs
CAS# 7789-00-6: 10 lb final RQ; 4.54 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 7789-00-6: acute, chronic.
Section 313
This chemical is not at a high enough concentration to be reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants. This material does not contain any Class 1 Ozone depletors. This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 7789-00-6 is listed as a Hazardous Substance under the CWA. None of the chemicals in this product are listed as Priority Pollutants under the CWA. None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
CAS# 7789-00-6 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Massachusetts.
California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
T N
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
R 43 May cause sensitization by skin contact.
R 46 May cause heritable genetic damage.
R 49 May cause cancer by inhalation.
R 50/53 Very toxic to aquatic organisms; may cause
long-term adverse effects in the aquatic environment.

Safety Phrases:
S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
S 53 Avoid exposure - obtain special instructions
before use.
S 60 This material and/or its container must be
disposed of as hazardous waste.
S 61 Avoid release to the environment. Refer to
special instructions/Safety data sheets.

WGK (Water Danger/Protection)
CAS# 7789-00-6: 2
Canada - DSL/NDSL
CAS# 7789-00-6 is listed on Canada's DSL List.
Canada - WHMIS
This product does not have a WHMIS classification.
Canadian Ingredient Disclosure List
CAS# 7789-00-6 is listed on the Canadian Ingredient Disclosure List.
Exposure Limits
CAS# 7789-00-6 (listed as chromium): OEL-ARAB Republic of Egypt:TWA 0.
05 mg/m3 OEL-AUSTRALIA:TWA 0.05 mg/m3 OEL-BELGIUM:TWA 0.5 mg/m3 OEL
-DENMARK:TWA 0.5 mg/m3 OEL-FINLAND:TWA 0.01 mg/m3 OEL-FRANCE:TWA 0.5
mg/m3 OEL-JAPAN:TWA 0.5 mg/m3 OEL-THE NETHERLANDS:TWA 0.5 mg/m3 OE
L-THE PHILIPPINES:TWA 1 mg/m3 OEL-SWEDEN:TWA 0.5 mg/m3 OEL-UNITED KI
NGDOM:TWA 0.5 mg/m3 OEL IN BULGARIA, COLOMBIA, JORDAN, KOREA check AC
GIH TLV OEL IN NEW ZEALAND, SINGAPORE, VIETNAM check ACGI TLV

Section 16 - Additional Information

MSDS Creation Date: 9/02/1997
Revision #3 Date: 6/10/2003

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.