Material Safety Data Sheet
Zinc Nitrate Hexahydrate, 98%
ACC# 01726
Section 1 - Chemical Product and Company Identification |
MSDS Name: Zinc Nitrate Hexahydrate, 98%
Catalog Numbers:
AC211660000, AC211660010, AC211660050
Synonyms:
Nitric Acid, Zinc Salt, Hexahydrate
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
10196-18-6 |
Zinc Nitrate Hexahydrate |
98 | unlisted |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: white.
Danger! Strong oxidizer. Contact with other
material may cause a fire. May be harmful if swallowed. May cause
eye and skin irritation. May cause respiratory and digestive tract
irritation.
Target Organs: None.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause severe skin irritation.
Ingestion:
May cause severe digestive tract irritation with abdominal pain,
nausea, vomiting and diarrhea. May be harmful if swallowed.
Inhalation:
May cause respiratory tract irritation. May cause methemoglobinemia,
cyanosis (bluish discoloration of skin due to deficient oxygenation
of the blood), convulsions, tachycardia, dyspnea (labored breathing),
and death.
Chronic:
No information found.
Section 4 - First Aid Measures
|
Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid if irritation develops or persists. Wash clothing
before reuse. Flush skin with plenty of soap and water.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid if irritation or symptoms occur.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician:
Treat symptomatically.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Strong oxidizer. Contact with other material may
cause fire. During a fire, irritating and highly toxic gases may be
generated by thermal decomposition or combustion. Use water spray to
keep fire-exposed containers cool. Use water with caution and in
flooding amounts. Vapors may be heavier than air. They can spread
along the ground and collect in low or confined areas. Containers may
explode when heated.
Extinguishing Media:
Use water only! Do NOT get water inside containers. Contact
professional fire-fighters immediately. Cool containers with
flooding quantities of water until well after fire is out. For small
fires, do NOT use dry chemicals, carbon dioxide, halon or foams.
USE WATER ONLY. For large fires, flood fire area with water from a
distance.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: ; Flammability: ; Instability:
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Avoid runoff into storm sewers and ditches which lead to waterways.
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Remove all sources of
ignition. Use a spark-proof tool. Provide ventilation. Do not get
water inside containers.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with clothing and other
combustible materials. Do not get on skin or in eyes. Avoid
ingestion and inhalation. Keep from contact with clothing and other
combustible materials. Discard contaminated shoes.
Storage:
Keep away from heat, sparks, and flame. Do not store near
combustible materials. Store in a cool, dry place. Keep containers
tightly closed. Keep away from strong bases.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Zinc Nitrate Hexahydrate
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
Zinc Nitrate Hexahydrate:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear a chemical apron. Wear appropriate clothing to
prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
Section 9 - Physical and Chemical Properties
|
Physical State: Solid
Appearance: white
Odor: odorless
pH: 5.1 in 5% solution.
Vapor Pressure: Not available.
Vapor Density: 10.3
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not applicable.
Freezing/Melting Point:36.4 deg C
Decomposition Temperature:105-131 deg C -
Solubility: Soluble in water.
Specific Gravity/Density: 2.065
Molecular Formula:Zn(NO3)2 .6H2O
Molecular Weight:297.4702
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, dust generation,
combustible materials, reducing agents.
Incompatibilities with Other Materials:
Reducing agents.
Hazardous Decomposition Products:
Nitrogen oxides, nitrogen gas, toxic fumes of zinc oxide.
Hazardous Polymerization: Will not occur.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 10196-18-6:
ZH4775000
LD50/LC50:
CAS# 10196-18-6:
Draize test,
rabbit, eye: 20 mg/24H Moderate;
Draize test, rabbit, skin: 500 mg/24H
Severe;
Oral, mouse: LD50 = 926
mg/kg;
Oral, rat: LD50 = 1190
mg/kg;
.
Carcinogenicity:
CAS# 10196-18-6:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information available.
Teratogenicity:
No information available.
Reproductive Effects:
No information available.
Mutagenicity:
No information available.
Neurotoxicity:
No information available.
Other Studies:
Section 12 - Ecological Information
|
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
ZINC NITRATE |
ZINC NITRATE |
Hazard Class: |
5.1 |
5.1 |
UN Number: |
UN1514 |
UN1514 |
Packing Group: |
II |
II |
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 10196-18-6 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 10196-18-6: immediate, fire.
Section 313
This material contains Zinc Nitrate
Hexahydrate (listed as Zinc compounds), 98%, (CAS# 10196-18-6) which
is subject to the reporting requirements of Section 313 of SARA
Title III and 40 CFR Part 373.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
CAS# 10196-18-6 is listed as a Toxic Pollutant under the Clean Water
Act.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 10196-18-6 can be found on the
following state right to know lists: California, (listed as Zinc
compounds), New Jersey, (listed as Zinc compounds), Pennsylvania,
(listed as Zinc compounds).
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
O
Risk Phrases:
R 8 Contact with combustible material may cause fire.
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 10196-18-6: 1
Canada - DSL/NDSL
None of the chemicals in this product are listed on the DSL or NDSL list.
Canada - WHMIS
This product has a WHMIS classification of C, D2B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 10196-18-6 is not listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 8/21/1998
Revision #4 Date: 11/20/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.