Section 2 - Composition, Information on Ingredients

CAS#	Chemical Name	Percent	EINECS/ELINCS
10031-43-3	Copper(II) nitrate, trihydrate	95+	unlisted

Section 3 - Hazards Identification

Appearance: blue crystals.
Danger! Strong oxidizer. Contact with other material may cause a fire. Harmful if swallowed. Causes eye and skin irritation. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. May cause respiratory tract irritation.
Target Organs: Central nervous system, eyes, skin.


Potential Health Effects
Eye: Causes eye irritation.
Skin: Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion: Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation: May cause respiratory tract irritation. May be harmful if inhaled.
Chronic: Laboratory experiments have resulted in mutagenic effects. Exposure to high concentrations may cause central nervous system depression. Animal studies have reported the development of tumors.

Section 4 - First Aid Measures

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: Do not induce vomiting. Get medical aid immediately. Call a poison control center.
Inhalation: Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Get medical aid. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Strong oxidizer. Contact with other material may cause fire.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or chemical foam.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 2; Flammability: 1; Instability: 2; Special Hazard: OX

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Wear a self contained breathing apparatus and appropriate personal protection. (See Exposure Controls, Personal Protection section). Avoid generating dusty conditions. Provide ventilation. Do not use combustible materials such as paper towels to clean up spill. Keep combustibles (wood, paper, oil, etc.,) away from spilled material. Do not let this chemical enter the environment.

Section 7 - Handling and Storage

Handling: Minimize dust generation and accumulation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Use only in a chemical fume hood. Keep from contact with clothing and other combustible materials.
Storage: Do not store near combustible materials. Store in a cool, dry place. Store in a tightly closed container.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use only under a chemical fume hood.
Exposure Limits

Chemical Name	ACGIH	NIOSH	OSHA - Final PELs
Copper(II) nitrate, trihydrate	none listed	1 mg/m3 TWA (as Cu, except Copper fume) (listed under Copper compounds, n.o.s.).100 mg/m3 IDLH (dust and mist, as Cu) (listed under Copper compounds, n.o.s.).	none listed
Copper(II) nitrate	none listed	none listed	none listed

OSHA Vacated PELs: Copper(II) nitrate, trihydrate: No OSHA Vacated PELs are listed for this chemical. Copper(II) nitrate: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - Physical and Chemical Properties

Physical State: Crystals
Appearance: blue
Odor: characteristic odor
pH: 4.0 (2M aq.sol.).
Vapor Pressure: Not available.
Vapor Density: 8.33
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:114 deg C
Decomposition Temperature:170 deg C
Solubility: Soluble.
Specific Gravity/Density:Not available.
Molecular Formula:CuN2O6.3H2O
Molecular Weight:241.6

Section 10 - Stability and Reactivity

Chemical Stability: Moisture sensitive. Heat sensitive
Conditions to Avoid: Incompatible materials, dust generation, excess heat, exposure to moist air or water.
Incompatibilities with Other Materials: Strong oxidizing agents, ammonia, anhydrides, amides, cyanides (e.g. potassium cyanide, sodium cyanide).
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information

RTECS#:      
CAS# 10031-43-3: GL7875000      
CAS# 3251-23-8: QU7400000
LD50/LC50:
CAS# 10031-43-3:
     Oral, rat: LD50 = 940 mg/kg;
.

CAS# 3251-23-8:
     Draize test, rabbit, eye: 100 mg Severe;
     Draize test, rabbit, skin: 500 mg Severe;
     Oral, mouse: LD50 = 430 mg/kg;
     Oral, rat: LD50 = 794 mg/kg;
     Oral, rat: LD50 = 940 mg/kg;
.

Carcinogenicity:
CAS# 10031-43-3: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 3251-23-8: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: Tumorigenic effects have been reported in experimental animals.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Mutagenicity: Mutagenic effects have occurred in experimental animals.
Neurotoxicity: No information available.
Other Studies:

Section 12 - Ecological Information

Ecotoxicity: No data available. No information available.
Environmental: No information available.
Physical: No information available.
Other: Do not empty into drains.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

	US DOT	Canada TDG
Shipping Name:	NITRATES, INORGANIC, N.O.S.	NITRATES INORGANIC NOS (COPPER NITRATE TRIHYDRATE)
Hazard Class:	5.1	5.1
UN Number:	UN1477	UN1477
Packing Group:	II	II

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 10031-43-3 is not on the TSCA Inventory because it is a hydrate. It is considered to be listed if the CAS number for the anhydrous form is on the inventory (40CFR720.3(u)(2)).
     CAS# 3251-23-8 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     CAS# 3251-23-8: 100 lb final RQ; 45.4 kg final RQ
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 10031-43-3: immediate, delayed, fire.
     CAS # 3251-23-8: immediate, delayed, fire.
Section 313
     This material contains Copper(II) nitrate, trihydrate (listed as Copper compounds, n.o.s.), 95+%, (CAS# 10031-43-3) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
     This material contains Copper(II) nitrate (listed as Water Dissociable Nitrate Compounds), -%, (CAS# 3251-23-8) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 3251-23-8 is listed as a Hazardous Substance under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA. CAS# 10031-43-3 is listed as a Toxic Pollutant under the Clean Water Act.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 10031-43-3 can be found on the following state right to know lists: California, (listed as Copper compounds, n.o.s.), New Jersey, (listed as Copper compounds, n.o.s.), Pennsylvania, (listed as Copper compounds, n.o.s.).
     CAS# 3251-23-8 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Massachusetts.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
     XN O N
Risk Phrases:
     R 22 Harmful if swallowed.
     R 36/38 Irritating to eyes and skin.
     R 8 Contact with combustible material may cause fire.
     R 50/53 Very toxic to aquatic organisms, may cause long-term
     adverse effects in the aquatic environment.

Safety Phrases:
     S 26 In case of contact with eyes, rinse immediately with plenty of
     water and seek medical advice.
     S 37/39 Wear suitable gloves and eye/face protection.
     S 60 This material and its container must be disposed of as hazardou
     s waste.
     S 61 Avoid release to the environment. Refer to special instructions
     /safety data sheets.

WGK (Water Danger/Protection)
     CAS# 10031-43-3: 2
     CAS# 3251-23-8: No information available.
Canada - DSL/NDSL
     CAS# 3251-23-8 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of C, D1B, D2B.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 10031-43-3 (listed as Copper compounds, n.o.s.) is listed on the Canadian Ingredient Disclosure List.
     CAS# 3251-23-8 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 5/07/1998
Revision #6 Date: 4/02/2008

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.