Material Safety Data Sheet
1,3-Dichloro-1,1,3,3-tetramethyldisiloxane, 96%
ACC# 02084
Section 1 - Chemical Product and Company Identification |
MSDS Name: 1,3-Dichloro-1,1,3,3-tetramethyldisiloxane, 96%
Catalog Numbers:
AC338550000, AC338550050, AC338550250
Synonyms:
None.
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
2401-73-2 |
1,3-Dichloro-1,1,3,3-tetramethyldisiloxane |
96 | 219-278-1 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: clear, colorless liquid. Flash Point: 15 deg C.
Danger! Causes eye and skin burns. Causes
digestive and respiratory tract burns. Flammable liquid and
vapor. May cause central nervous system depression.
May cause kidney damage. May cause cardiac disturbances. Moisture
sensitive.
Target Organs: Kidneys, central nervous system,
cardiovascular system.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Causes skin burns.
Ingestion:
Causes gastrointestinal tract burns. May cause kidney damage. May
cause central nervous system effects. Ingestion of large amounts may
cause CNS depression. May cause systemic effects. May cause cardiac
effects such as heart blocks, arrhythmias, shock and possible death
due to cardiovascular collapse.
Inhalation:
Causes chemical burns to the respiratory tract. Inhalation may be
fatal as a result of spasm, inflammation, edema of the larynx and
bronchi, chemical pneumonitis and pulmonary edema. May cause kidney
damage. Aspiration may lead to pulmonary edema. Vapors may cause
dizziness or suffocation. May cause systemic effects. May cause
burning sensation, coughing, wheezing, laryngitis, shortness of
breath, headache, nausea, and vomiting. Inhalation at high
concentrations may cause CNS depression and asphixiation. May cause
burning sensation in the chest. May cause cardiac effects such as
tachyardia and shock.
Chronic:
Effects may be delayed. May cause kidney damage.
Section 4 - First Aid Measures
|
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Combustion
generates toxic fumes. During a fire, irritating and highly toxic
gases may be generated by thermal decomposition or combustion. Will
burn if involved in a fire. Use water spray to keep fire-exposed
containers cool. Containers may explode in the heat of a fire.
Flammable liquid and vapor. Containers may explode if exposed to
fire.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT get water inside
containers. Do NOT use straight streams of water.
Flash Point: 15 deg C ( 59.00 deg F)
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 3; Flammability: 3; Instability: 1
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. Provide ventilation. Do
not get water inside containers. A vapor suppressing foam may be
used to reduce vapors.
Section 7 - Handling and Storage
|
Handling:
Ground and bond containers when transferring material. Use
spark-proof tools and explosion proof equipment. Do not breathe dust,
mist, or vapor. Do not get in eyes, on skin, or on clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Keep container tightly closed. Keep away from heat, sparks
and flame. Do not ingest or inhale. Do not allow contact with water.
Use only in a chemical fume hood. Discard contaminated shoes. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames. Keep from contact with
moist air and steam.
Storage:
Keep away from sources of ignition. Keep container closed when not
in use. Store in a tightly closed container. Flammables-area. Store
protected from moisture. Store under an inert atmosphere.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
1,3-Dichloro-1,1,3,3-tetramethyldisiloxane
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
1,3-Dichloro-1,1,3,3-tetramethyldisiloxane:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Liquid
Appearance: clear, colorless
Odor: acrid odor
pH: Not available.
Vapor Pressure: 8 mm Hg @ 25 deg C
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 138 deg C @ 760 mm Hg
Freezing/Melting Point:-37 deg C
Decomposition Temperature:Not available.
Solubility: Reacts.
Specific Gravity/Density:1.03 g/ml
Molecular Formula:C4H12Cl2OSi2
Molecular Weight:203.22
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable. May decompose on exposure to moist air or water. This
product rapidly hydrolyzes to form hydrochloric acid.
Conditions to Avoid:
Ignition sources, moisture, excess heat.
Incompatibilities with Other Materials:
Oxidizing agents, acids, bases, moisture.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide, silicon dioxide.
Hazardous Polymerization: Will not occur.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 2401-73-2
unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
CAS# 2401-73-2:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information found
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
No information found
Neurotoxicity:
No information found
Other Studies:
Section 12 - Ecological Information
|
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
DOT regulated - small quantity provisions apply (see 49CFR173.4) |
Chlorosilanes, Flammable, Corrosive, N.O |
Hazard Class: |
|
3 |
UN Number: |
|
UN2985 |
Packing Group: |
|
II |
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 2401-73-2 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 2401-73-2 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
F C
Risk Phrases:
R 11 Highly flammable.
R 34 Causes burns.
Safety Phrases:
S 16 Keep away from sources of ignition - No smoking.
S 25 Avoid contact with eyes.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face pr
otection.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S 9 Keep container in a well-ventilated place.
WGK (Water Danger/Protection)
CAS# 2401-73-2: No information available.
Canada - DSL/NDSL
CAS# 2401-73-2 is listed on Canada's NDSL List.
Canada - WHMIS
This product has a WHMIS classification of B2, E.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
Section 16 - Additional Information
|
MSDS Creation Date: 1/25/2000
Revision #8 Date: 3/16/2007
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.