Section 2 - Composition, Information on Ingredients

CAS#	Chemical Name	Percent	EINECS/ELINCS
107-92-6	n-Butyric acid	100.0	203-532-3

Section 3 - Hazards Identification

Appearance: colorless liquid. Flash Point: 69 deg C.
Danger! Corrosive. Causes eye and skin burns. Causes digestive and respiratory tract burns. Harmful if absorbed through the skin. Combustible liquid and vapor.
Target Organs: Respiratory system, eyes, skin.


Potential Health Effects
Eye: Causes eye burns.
Skin: Harmful if absorbed through the skin. Causes skin burns.
Ingestion: May cause severe and permanent damage to the digestive tract. Causes gastrointestinal tract burns. May be harmful if swallowed.
Inhalation: Causes chemical burns to the respiratory tract.
Chronic: No information found.

Section 4 - First Aid Measures

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid imme diately. Do NOT allow victim to rub eyes or keep eyes closed. Extensiv e irrigation with water is required (at least 30 minutes).
Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse. Destroy contaminated shoes.
Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Do NOT use mouth-to-mouth resuscitation. If breathing has ceased apply artificial respiration using oxygen and a suitable mechanical device such as a bag and a mask.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. Use water spray to keep fire-exposed containers cool. Combustible liquid. Containers may explode when heated.
Extinguishing Media: In case of fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. Use water spray to cool fire-exposed containers.
Flash Point: 69 deg C ( 156.20 deg F)
Autoignition Temperature: 425 deg C ( 797.00 deg F)
Explosion Limits, Lower:2.00 vol %
Upper: 10.00 vol %
NFPA Rating: (estimated) Health: 3; Flammability: 2; Instability: 0

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Use water spray to dilute spill to a non-flammable mixture. Avoid runoff into storm sewers and ditches which lead to waterways. Clean up spills immediately, observing precautions in the Protective Equipment section. Use water spray to disperse the gas/vapor. Remove all sources of ignition. Use a spark-proof tool. Absorb spill with an alkaline material such as soda ash or lime. Carefully scoop up and place into appropriate disposal container. Provide ventilation.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Use only in a well-ventilated area. Ground and bond containers when transferring material. Do not get in eyes, on skin, or on clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Do not ingest or inhale. Discard contaminated shoes. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage: Keep away from heat, sparks, and flame. Keep away from heat and flame. Keep away from sources of ignition. Do not store in direct sunlight. Keep container closed when not in use. Store in a tightly closed container. Keep from contact with oxidizing materials. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Local exhaust may be necessary to control concentrations to acceptable levels.
Exposure Limits

Chemical Name	ACGIH	NIOSH	OSHA - Final PELs
n-Butyric acid	none listed	none listed	none listed

OSHA Vacated PELs: n-Butyric acid: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear chemical splash goggles.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to minimize contact with skin.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties

Physical State: Liquid
Appearance: colorless
Odor: unpleasant odor - putrid odor
pH: Not available.
Vapor Pressure: .43 mm Hg @20C
Vapor Density: 3.0 (air=1)
Evaporation Rate:Not available.
Viscosity: 1.6 mPas 20 deg C
Boiling Point: 162 - 165 deg C @ 760.00mm Hg
Freezing/Melting Point:-7 - -5 deg C
Decomposition Temperature:Not available.
Solubility: miscible with almost all common organic
Specific Gravity/Density:.9640g/cm3
Molecular Formula:C4H8O2
Molecular Weight:88.11

Section 10 - Stability and Reactivity

Chemical Stability: Stable.
Conditions to Avoid: Incompatible materials, ignition sources, excess heat, alkaline materials, oxidizers.
Incompatibilities with Other Materials: Oxidizing agents, ammonia, sulfuric acid, isocyanates, epichlorohydrin, aliphatic amines, caustics (e.g. ammonia, ammonium hydroxide, calcium hydroxide, potassium hydroxide, sodium hydroxide).
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information

RTECS#:      
CAS# 107-92-6: ES5425000
LD50/LC50:
CAS# 107-92-6:
     Draize test, rabbit, skin: 20 mg/24H Moderate;
     Oral, rat: LD50 = 2 gm/kg;
     Skin, rabbit: LD50 = 530 uL/kg;
.

Carcinogenicity:
CAS# 107-92-6: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: DNA damage(Human HeLa cell) = 3 mmol/LDNA inhibition(Human Lymphocyte) = 4 mmol/L
Neurotoxicity: No information found
Other Studies:

Section 12 - Ecological Information

Ecotoxicity: Fish: Bluegill/Sunfish: LC50 = 200 mg/L; 24 Hr.; UnspecifiedWater flea EC50 = 61 mg/L; 48 Hr.; UnspecifiedBacteria: Phytobacterium phosphoreum: EC50 = 16.9 - 17.2 mg/L; 5,15, 30 Minutes; Microtox test, 15 degrees C No data available.
Environmental: If released to soil, butyric acid is expected to be relatively mobile, although adsorption may occur by attractive interactions with active sites in the soil. Butyric acid is not expected to significantly volatilize from either moist or dry soil to the atmosphere. If released to water, butyric acid will exist predominately in the dissociated form under environmental conditions. Butyric acid is expected to biodegrade rapidly under both aerobic and anaerobic conditions.
Physical: BOD: 1.150 lb/lb, 5 days; 1.450 lb/lb, 20 days.
Other: No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

	US DOT	Canada TDG
Shipping Name:	BUTYRIC ACID	BUTYRIC ACID
Hazard Class:	8	8
UN Number:	UN2820	UN2820
Packing Group:	III	III

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 107-92-6 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     CAS# 107-92-6: 5000 lb final RQ; 2270 kg final RQ
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 107-92-6: immediate, fire.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 107-92-6 is listed as a Hazardous Substance under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 107-92-6 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Massachusetts.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
     C
Risk Phrases:
     R 34 Causes burns.

Safety Phrases:
     S 26 In case of contact with eyes, rinse immediately with plenty of
     water and seek medical advice.
     S 36 Wear suitable protective clothing.
     S 45 In case of accident or if you feel unwell, seek medical advice
     immediately (show the label where possible).

WGK (Water Danger/Protection)
     CAS# 107-92-6: 1
Canada - DSL/NDSL
     CAS# 107-92-6 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of E.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 107-92-6 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 5/17/1999
Revision #5 Date: 2/13/2008

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.