Material Safety Data Sheet
Cadmium acetate dihydrate
ACC# 03735
Section 1 - Chemical Product and Company Identification |
MSDS Name: Cadmium acetate dihydrate
Catalog Numbers:
AC317130000, AC317130050, AC317131000, C4-100, C4-500
Synonyms:
Acetic acid, cadmium salt, dihydrate; Cadmium diacetate dihydrate.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
5743-04-4 |
Cadmium acetate dihydrate |
98 | unlisted |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: white solid.
Danger! Harmful if swallowed, inhaled, or absorbed
through the skin. Contains cadmium. Cancer hazard. Avoid creating
dust. Can cause lung and kidney disease. May cause irritation.
Dangerous for the environment.
Target Organs: Kidneys, lungs, skeletal
structures, prostate.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation.
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Prolonged or repeated exposure may cause permanent bone structure
abnormalities. Chronic inhalation of cadmium compounds has been
associated with lung and prostate cancer. The primary target organ
for chronic cadmium disease is clearly the kidney.
Section 4 - First Aid Measures
|
Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical
aid.
Notes to Physician:
Treat symptomatically and supportively.
Antidote:
The use of Calcium disodium EDTA as a chelating agent should be
determined by qualified medical personnel.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 2; Flammability: 1; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Do not breathe dust.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits. See 29CFR 1910.1027 for regulations applying to all
occupational exposures to cadmium and cadmium compounds, in all
forms.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Cadmium acetate dihydrate
|
0.01 mg/m3 TWA (as Cd); 0.002 mg/m3 TWA (respirable fraction, as Cd) (listed under Cadmium compounds).
|
9 mg/m3 IDLH (dust and fume, as Cd) (listed under Cadmium compounds).
|
2.5 ęg/m3 Action Level (as Cd); 5 ęg/m3 TWA (as Cd, Do not eat, drink or chew to bacco or gum or apply cosmetics in regulated areas. Carcinogen - dust can cause lung and kidney disease. See 29 CFR 19
10.1027) (listed under Cadmium compounds).
|
Cadmium acetate anhydrous
|
0.01 mg/m3 TWA (as Cd); 0.002 mg/m3 TWA (respirable fraction, as Cd) (listed under Cadmium compounds).
|
9 mg/m3 IDLH (dust and fume, as Cd) (listed under Cadmium compounds).
|
2.5 ęg/m3 Action Level (as Cd); 5 ęg/m3 TWA (as Cd, Do not eat, drink or chew to bacco or gum or apply cosmetics in regulated areas. Carcinogen - dust can cause lung and kidney disease. See 29 CFR 19
10.1027) (listed under Cadmium compounds).
|
OSHA Vacated PELs:
Cadmium acetate dihydrate:
No OSHA Vacated PELs are listed for this chemical.
Cadmium acetate anhydrous:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Solid
Appearance: white
Odor: acetic odor - weak odor
pH: Not available.
Vapor Pressure: Not applicable.
Vapor Density: Not available.
Evaporation Rate:Not applicable.
Viscosity: Not applicable.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Soluble.
Specific Gravity/Density:2.01
Molecular Formula:C4H10CdO6
Molecular Weight:266.53
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Dust generation, confined spaces.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, and strong bases.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, cadmium fumes.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 5743-04-4:
AF7505000
CAS# 543-90-8:
EU9810000
LD50/LC50:
CAS# 5743-04-4:
Oral, rat: LD50 =
360 mg/kg;
.
CAS# 543-90-8:
Oral, rat: LD50
= 333 mg/kg;
.
Carcinogenicity:
CAS# 5743-04-4:
- ACGIH:
A2 - Suspected Human Carcinogen (listed as 'Cadmium compounds').
- California:
carcinogen, initial date 10/1/87 (listed as Cadmium compounds).
- NTP:
Known carcinogen (listed as Cadmium compounds).
- IARC:
Group 1 carcinogen (listed as Cadmium compounds).
CAS# 543-90-8:
- ACGIH:
A2 - Suspected Human Carcinogen (listed as 'Cadmium compounds').
- California:
carcinogen, initial date 10/1/87 (listed as Cadmium compounds).
- NTP:
Known carcinogen (listed as Cadmium compounds).
- IARC:
Group 1 carcinogen
Epidemiology:
No data available.
Teratogenicity:
No data available.
Reproductive Effects:
No data available.
Mutagenicity:
No data available.
Neurotoxicity:
No data available.
Other Studies:
Section 12 - Ecological Information
|
Ecotoxicity:
No data available.
No information available.
Environmental:
No information available.
Physical:
No information available.
Other:
Cadmium compounds are considered a severe marine pollutants.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
CADMIUM COMPOUNDS |
Cadmium Compounds |
Hazard Class: |
6.1 |
6.1 |
UN Number: |
UN2570 |
UN2570 |
Packing Group: |
III |
III |
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 5743-04-4 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
CAS# 543-90-8 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 543-90-8: 10 lb final RQ; 4.54 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 5743-04-4: immediate, delayed.
Section 313
This material contains Cadmium
acetate dihydrate (listed as Cadmium compounds), 98%, (CAS#
5743-04-4) which is subject to the reporting requirements of Section
313 of SARA Title III and 40 CFR Part 373.
This material contains Cadmium
acetate anhydrous (listed as Cadmium compounds), -%, (CAS# 543-90-8)
which is subject to the reporting requirements of Section 313 of SARA
Title III and 40 CFR Part 373.
Clean Air Act:
CAS# 5743-04-4 (listed as Cadmium compounds) is listed as a hazardous
air pollutant (HAP).
CAS# 543-90-8 (listed as Cadmium compounds) is listed as a hazardous a
ir pollutant (HAP).
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 543-90-8 is listed as a Hazardous Substance under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
CAS# 5743-04-4 is listed as a Toxic Pollutant under the Clean Water
Act.
CAS# 543-90-8 is listed as a Toxic Pollutant under the Clean Water
Act.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 5743-04-4 can be found on the
following state right to know lists: California, (listed as Cadmium
compounds), New Jersey, (listed as Cadmium compounds), Pennsylvania,
(listed as Cadmium compounds), Minnesota, (listed as Cadmium
compounds).
CAS# 543-90-8 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, (listed as Cadmium compounds),
Massachusetts.
California Prop 65
The following statement(s) is(are) made in order to comply with
the California Safe Drinking Water Act:
WARNING: This product contains Cadmium acetate dihydrate, listed as
`Cadmium compounds', a chemical known to the state of California to
cause cancer.
WARNING: This product contains Cadmium acetate anhydrous, listed as
`Cadmium compounds', a chemical known to the state of California to
cause cancer.
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
T N
Risk Phrases:
R 20/21/22 Harmful by inhalation, in contact with skin and if
swallowed.
R 45 May cause cancer.
R 50/53 Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
Safety Phrases:
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S 53 Avoid exposure - obtain special instructions before use.
S 60 This material and its container must be disposed of as hazardou
s waste.
S 61 Avoid release to the environment. Refer to special instructions
/safety data sheets.
WGK (Water Danger/Protection)
CAS# 5743-04-4: No information available.
CAS# 543-90-8: 3
Canada - DSL/NDSL
CAS# 543-90-8 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D2A.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 5743-04-4 is not listed on the Canadian Ingredient Disclosure List.
CAS# 543-90-8 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 12/12/1997
Revision #6 Date: 11/20/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.