Material Safety Data Sheet
Crude Oil
ACC# 05545
Section 1 - Chemical Product and Company Identification |
MSDS Name: Crude Oil
Catalog Numbers:
SRS951020, SRS951500, SRS952020, SRS952500, SRS953020, SRS953500
Synonyms:
Base oil; coal liquid; coal oil; petroleum ether, fuel; rock oil;
seneca oil.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
8002-05-9 |
Petroleum distillates (naphtha) |
100 | 232-298-5 |
Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: dark yellow to brown or green-black liquid.
Warning! Flammable liquid and
vapor. Causes eye and skin irritation. May cause lung
damage. May cause central nervous system effects. May cause
dermatitis.
Target Organs: Central nervous system.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Exposure may cause irritation characterized by redness, dryness, and
inflammation.
Ingestion:
Aspiration hazard. Causes gastrointestinal irritation with nausea,
vomiting and diarrhea. May cause central nervous system depression,
characterized by excitement, followed by headache, dizziness,
drowsiness, and nausea. Advanced stages may cause collapse,
unconsciousness, coma and possible death due to respiratory failure.
Inhalation:
Inhalation of high concentrations may cause central nervous system
effects characterized by nausea, headache, dizziness, unconsciousness
and coma. High vapor concentrations may cause drowsiness.
Chronic:
Prolonged or repeated skin contact may cause dermatitis.
Section 4 - First Aid Measures
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Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
Antidote:
None reported.
Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Extremely flammable liquid and vapor. Vapor may
cause flash fire.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide. Water may be ineffective.
This material is lighter than water and insoluble in water. The fire
could easily be spread by the use of water in an area where the
water cannot be contained.
Flash Point: -6.7 - 32.2 deg
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: ; Flammability: ; Instability:
Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.
Section 7 - Handling and Storage
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Handling:
Use with adequate ventilation. Ground and bond containers when
transferring material. Avoid contact with eyes, skin, and clothing.
Empty containers retain product residue, (liquid and/or vapor), and
can be dangerous. Keep away from heat, sparks and flame. Avoid
ingestion and inhalation. Prevent build up of vapors to explosive
concentration. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Use explosion-proof ventilation equipment. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Petroleum distillates (naphtha)
|
none listed
|
350 mg/m3 TWA 1100 ppm IDLH
|
none listed
|
OSHA Vacated PELs:
Petroleum distillates (naphtha):
400 ppm TWA; 1600 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
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Physical State: Liquid
Appearance: dark yellow to brown or green-black
Odor: mild odor
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: >1.0
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: < 0 - >1093.3 deg C
Freezing/Melting Point:-60 deg C
Decomposition Temperature:Not available.
Solubility: Insoluble in water.
Specific Gravity/Density:0.780-0.970
Molecular Formula:Not available.
Molecular Weight:Not available.
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
May explode with nitrogen tetroxide, potential violent reaction with
strong oxidizers. This material is peroxizable and may form crystals
capable of exploding after prolonged storage.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 8002-05-9:
SE7175000; SE7449000
LD50/LC50:
CAS# 8002-05-9:
Draize test,
rabbit, eye: 100 mg Mild;
Draize
test, rabbit, skin: 500 mg/24H Moderate;
Oral, mouse: LD50 = >4300 mg/kg;
Oral, rat: LD50 = >4300
mg/kg;
.
Carcinogenicity:
CAS# 8002-05-9:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No data available.
Teratogenicity:
No data available.
Reproductive Effects:
No data available.
Mutagenicity:
No data available.
Neurotoxicity:
No data available.
Other Studies:
Section 12 - Ecological Information
|
Ecotoxicity:
No data available.
This chemical is expected to cause some oxygen depletion in aquatic
systems. It has a low potential to affect aquatic systems. It has a
low potential to affect aquatic organisms, secondary waste treatment
microorganisms and the germination of some plants. It has a moderate
potential to affect the germination and growth of some plants.
Environmental:
This chemical does not bioconcentrate.
Physical:
No information found.
Other:
No information found.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
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US DOT |
Canada TDG |
Shipping Name: |
Not regulated as a hazardous material |
No information available. |
Hazard Class: |
|
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UN Number: |
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Packing Group: |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 8002-05-9 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 8002-05-9 can be found on the
following state right to know lists: New Jersey, Pennsylvania,
Minnesota, Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 8002-05-9: 1
Canada - DSL/NDSL
CAS# 8002-05-9 is listed on Canada's DSL List.
Canada - WHMIS
not available.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
Section 16 - Additional Information
|
MSDS Creation Date: 9/02/1997
Revision #5 Date: 10/25/2007
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.