Material Safety Data Sheet
Copper(II) chloride dihydrate
ACC# 05625
Section 1 - Chemical Product and Company Identification |
MSDS Name: Copper(II) chloride dihydrate
Catalog Numbers:
AC206340000, AC206345000, AC270530000, AC270530010, AC270530025,
AC315280000, AC315281000, AC405840000, AC405840050, AC405845000, C454-3,
C454-500, C455-500
Synonyms:
Cupric chloride dihydrate.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
10125-13-0 |
Copper(II) chloride dihydrate |
98 | unlisted |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: green solid.
Warning! Harmful if swallowed. Causes eye, skin,
and respiratory tract irritation. Toxic to aquatic organisms, may
cause long-term adverse effects in the aquatic environment.
Hygroscopic (absorbs moisture from the air).
Target Organs: Respiratory system, eyes, skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause irritation of the digestive tract.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Effects may
be delayed. Individuals with Wilson's disease are unable to
metabolize copper. Thus, copper accumulates in various tissues and
may result in liver, kidney, and brain damage.
Section 4 - First Aid Measures
|
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately. Call a poison
control center.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do not use mouth-to-mouth
resuscitation if victim ingested or inhaled the substance; induce
artificial respiration with the aid of a pocket mask equipped with a
one-way valve or other proper respiratory medical device.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Substance is noncombustible.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 2; Flammability: 0; Instability: 1
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid generating dusty conditions. Provide ventilation. Do
not let this chemical enter the environment.
Section 7 - Handling and Storage
|
Handling:
Minimize dust generation and accumulation. Do not get in eyes, on
skin, or on clothing. Do not ingest or inhale. Use with adequate
ventilation.
Storage:
Store in a cool, dry place. Store in a tightly closed container.
Store under argon.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Copper(II) chloride dihydrate
|
none listed
|
1 mg/m3 TWA (dust and mist, as Cu, except copper fume) (listed under Copper compounds, n.o.s.).100 mg/m3 IDLH (dust and mist, as Cu) (listed under Copper compounds, n.o.s.).
|
none listed
|
Cupric chloride anhydrous
|
none listed
|
1 mg/m3 TWA (dust and mist, as Cu, except copper fume) (listed under Copper compounds, n.o.s.).100 mg/m3 IDLH (dust and mist, as Cu) (listed under Copper compounds, n.o.s.).
|
none listed
|
OSHA Vacated PELs:
Copper(II) chloride dihydrate:
No OSHA Vacated PELs are listed for this chemical.
Cupric chloride anhydrous:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
Section 9 - Physical and Chemical Properties
|
Physical State: Solid
Appearance: blue - green
Odor: odorless
pH: 3 - 3.8 (5% aq.sol.)
Vapor Pressure: Not available.
Vapor Density: 5.9 (air=1)
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:100 deg C (decom)
Decomposition Temperature:> 100 deg C
Solubility: 1150 g/L (20°C)
Specific Gravity/Density:2.54 (water=1)
Molecular Formula:CuCl2.2H2O
Molecular Weight:170.48
Section 10 - Stability and Reactivity
|
Chemical Stability:
Hygroscopic: absorbs moisture or water from the air.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, exposure to
moist air or water.
Incompatibilities with Other Materials:
Alkali metals, strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, metallic oxides.
Hazardous Polymerization: Will not occur.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 10125-13-0:
GL7030000
CAS# 7447-39-4:
GL7000000
LD50/LC50:
Not available.
CAS# 7447-39-4:
Oral, mouse:
LD50 = 233 mg/kg;
Oral, rat: LD50 =
584 mg/kg;
Oral, rat: LD50 = 140
mg/kg;
.
Carcinogenicity:
CAS# 10125-13-0:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7447-39-4:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information found
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
No information found
Neurotoxicity:
No information found
Other Studies:
Section 12 - Ecological Information
|
Ecotoxicity:
No data available.
No information available.
Environmental:
No information available.
Physical:
No information available.
Other:
Do not empty into drains.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
COPPER CHLORIDE |
COPPER CHLORIDE |
Hazard Class: |
8 |
8 |
UN Number: |
UN2802 |
UN2802 |
Packing Group: |
III |
III |
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 10125-13-0 is not on the TSCA Inventory because it is a hydrate.
It is considered to be listed if the CAS number for the anhydrous form
is on the inventory (40CFR720.3(u)(2)).
CAS# 7447-39-4 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 7447-39-4: 10 lb final RQ; 4.54 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 10125-13-0: immediate, delayed.
CAS # 7447-39-4: immediate, delayed.
Section 313
This material contains Copper(II)
chloride dihydrate (listed as Copper compounds, n.o.s.), 98%, (CAS#
10125-13-0) which is subject to the reporting requirements of Section
313 of SARA Title III and 40 CFR Part 373.
This material contains Cupric
chloride anhydrous (listed as Copper compounds, n.o.s.), -%, (CAS#
7447-39-4) which is subject to the reporting requirements of Section
313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 7447-39-4 is listed as a Hazardous Substance under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
CAS# 10125-13-0 is listed as a Toxic Pollutant under the Clean Water
Act.
CAS# 7447-39-4 is listed as a Toxic Pollutant under the Clean Water
Act.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 10125-13-0 can be found on the
following state right to know lists: California, (listed as Copper
compounds, n.o.s.), New Jersey, (listed as Copper compounds,
n.o.s.), Pennsylvania, (listed as Copper compounds, n.o.s.).
CAS# 7447-39-4 can be found on the
following state right to know lists: California, New Jersey, (listed
as Copper compounds, n.o.s.), Pennsylvania, Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XN N
Risk Phrases:
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system and skin.
R 50/53 Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 29 Do not empty into drains.
S 37/39 Wear suitable gloves and eye/face protection.
S 57 Use appropriate containment to avoid environmental contaminatio
n.
WGK (Water Danger/Protection)
CAS# 10125-13-0: No information available.
CAS# 7447-39-4: 2
Canada - DSL/NDSL
CAS# 7447-39-4 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D2B, D1B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 10125-13-0 (listed as Copper compounds, n.o.s.) is listed on the Canadian Ingredient Disclosure List.
CAS# 7447-39-4 (listed as Copper compounds, n.o.s.) is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 6/09/1999
Revision #12 Date: 11/25/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.