Section 2 - Composition, Information on Ingredients

CAS#	Chemical Name	Percent	EINECS/ELINCS
563-52-0	1-Butene, 3-chloro-	23 - 28	209-252-8
591-97-9	Crotyl Chloride	65+	209-739-5
1190-22-3	Butane, 1,3-dichloro-	<1	214-718-9

Section 3 - Hazards Identification

Appearance: colorless clear liquid. Flash Point: -15 deg C.
Danger! Flammable liquid and vapor. Causes burns by all exposure routes. Harmful if swallowed.
Target Organs: Respiratory system, gastrointestinal system, eyes, skin.


Potential Health Effects
Eye: Causes eye burns.
Skin: Causes skin burns. May be harmful if absorbed through the skin.
Ingestion: Harmful if swallowed. Causes gastrointestinal tract burns.
Inhalation: Causes chemical burns to the respiratory tract. May be harmful if inhaled.
Chronic: No information found.

Section 4 - First Aid Measures

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid imme diately.
Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: Do not induce vomiting. Get medical aid immediately. Call a poison control center.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If breathing is difficult, give oxygen. Do not use mouth-to-mouth resuscitation if victim ingested or inhaled the substance; induce artificial respiration with the aid of a pocket mask equipped with a one-way valve or other proper respiratory medical device.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Vapors may form an explosive mixture with air. Vapors can travel to a source of ignition and flash back. Will burn if involved in a fire. Containers may explode in the heat of a fire. Flammable liquid and vapor.
Extinguishing Media: Use foam, dry chemical, or carbon dioxide.
Flash Point: -15 deg C ( 5.00 deg F)
Autoignition Temperature: 510 deg C ( 950.00 deg F)
Explosion Limits, Lower:4.2
Upper: 19.0
NFPA Rating: (estimated) Health: 3; Flammability: 3; Instability: 0

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Wear a self contained breathing apparatus and appropriate personal protection. (See Exposure Controls, Personal Protection section). Remove all sources of ignition. Use a spark-proof tool. Do not let this chemical enter the environment.

Section 7 - Handling and Storage

Handling: Use spark-proof tools and explosion proof equipment. Do not get in eyes, on skin, or on clothing. Keep away from heat, sparks and flame. Do not ingest or inhale. Use only in a chemical fume hood.
Storage: Keep away from sources of ignition. Store in a tightly closed container. Store in a dry area. Flammables-area. Keep refrigerated. (Store below 4°C/39°F.)

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Use explosion-proof ventilation equipment. Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use only under a chemical fume hood.
Exposure Limits

Chemical Name	ACGIH	NIOSH	OSHA - Final PELs
1-Butene, 3-chloro-	none listed	none listed	none listed
Crotyl Chloride	none listed	none listed	none listed
Butane, 1,3-dichloro-	none listed	none listed	none listed

OSHA Vacated PELs: 1-Butene, 3-chloro-: No OSHA Vacated PELs are listed for this chemical. Crotyl Chloride: No OSHA Vacated PELs are listed for this chemical. Butane, 1,3-dichloro-: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties

Physical State: Clear liquid
Appearance: colorless
Odor: stinging odor
pH: 3 (14g/L aq.sol.)
Vapor Pressure: 494 hPa @ 20 deg C
Vapor Density: 3.12
Evaporation Rate:Not available.
Viscosity: 0.46 mPas 20 deg C
Boiling Point: 80 - 85 deg C @ 760 mmHg
Freezing/Melting Point:-65 deg C
Decomposition Temperature:Not available.
Solubility: +/- 14 g/L (20°C)
Specific Gravity/Density:0.920
Molecular Formula:C4H7Cl
Molecular Weight:90.55

Section 10 - Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials: Strong oxidizing agents.
Hazardous Decomposition Products: Hydrogen chloride, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information

RTECS#:      
CAS# 563-52-0: EM4261000      
CAS# 591-97-9: EM4264000      
CAS# 1190-22-3 unlisted.
LD50/LC50:
Not available.
Not available.
Not available.

Carcinogenicity:
CAS# 563-52-0: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 591-97-9: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 1190-22-3: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Mutagenicity: No information available.
Neurotoxicity: No information available.
Other Studies:

Section 12 - Ecological Information

Ecotoxicity: No data available. No information available.
Environmental: Rapidly volatilizes into the atmosphere.
Physical: No information available.
Other: Do not empty into drains.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

	US DOT	Canada TDG
Shipping Name:	FLAMMABLE LIQUID, CORROSIVE, N.O.S.	FLAMMABLE LIQUID, CORROSIVE, N.O.S.
Hazard Class:	3	3
UN Number:	UN2924	UN2924
Packing Group:	II	II

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 563-52-0 is listed on the TSCA inventory.
     CAS# 591-97-9 is listed on the TSCA inventory.
     CAS# 1190-22-3 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 563-52-0 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
     CAS# 591-97-9 can be found on the following state right to know lists: Pennsylvania, Massachusetts.
     CAS# 1190-22-3 is not present on state lists from CA, PA, MN, MA, FL, or NJ.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
     F C
Risk Phrases:
     R 11 Highly flammable.
     R 22 Harmful if swallowed.
     R 34 Causes burns.

Safety Phrases:
     S 16 Keep away from sources of ignition - No smoking.
     S 26 In case of contact with eyes, rinse immediately with plenty of
     water and seek medical advice.
     S 36/37/39 Wear suitable protective clothing, gloves and eye/face pr
     otection.
     S 45 In case of accident or if you feel unwell, seek medical advice
     immediately (show the label where possible).

WGK (Water Danger/Protection)
     CAS# 563-52-0: 2
     CAS# 591-97-9: 2
     CAS# 1190-22-3: No information available.
Canada - DSL/NDSL
     CAS# 591-97-9 is listed on Canada's DSL List.
     CAS# 563-52-0 is listed on Canada's NDSL List.
     CAS# 1190-22-3 is listed on Canada's NDSL List.
Canada - WHMIS
     This product has a WHMIS classification of B2, D1B, E.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List

Section 16 - Additional Information

MSDS Creation Date: 6/03/1998
Revision #4 Date: 12/10/2007

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.