Material Safety Data Sheet
Stoddard solvent
ACC# 13692
Section 1 - Chemical Product and Company Identification |
MSDS Name: Stoddard solvent
Catalog Numbers:
AC419730000, AC419730010
Synonyms:
Mineral spirits; White spirits.
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
8052-41-3 |
Stoddard solvent |
100 | 232-489-3 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: APHA: 25 max clear liquid. Flash Point: > 38 deg C.
Warning! Flammable liquid and
vapor. Toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment. Repeated exposure may
cause skin dryness or cracking. Aspiration hazard if swallowed. Can
enter lungs and cause damage.
Target Organs: Central nervous system, liver.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be harmful if absorbed through the
skin.
Ingestion:
Aspiration hazard. May cause irritation of the digestive tract. May
be harmful if swallowed. May cause lung damage.
Inhalation:
May cause respiratory tract irritation. May cause lung damage. May
be harmful if inhaled. Aspiration hazard.
Chronic:
Prolonged or repeated skin contact may cause dermatitis. May cause
cancer in humans.
Section 4 - First Aid Measures
|
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. If irritation develo
ps, get medical aid.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
Potential for aspiration if swallowed. Get medical aid immediately.
Do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person. If
vomiting occurs naturally, have victim lean forward.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Possible
aspiration hazard. Do not use mouth-to-mouth resuscitation if victim
ingested or inhaled the substance; induce artificial respiration with
the aid of a pocket mask equipped with a one-way valve or other
proper respiratory medical device.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. Will burn if involved in a fire. Flammable liquid and vapor.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide. Water may be ineffective.
Flash Point: > 38 deg C (> 100.40 deg F)
Autoignition Temperature: 400 deg C ( 752.00 deg F)
Explosion Limits, Lower:1.0%
Upper: 7.5%
NFPA Rating:
(estimated) Health: 2; Flammability: 2; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Wear a self contained breathing
apparatus and appropriate personal protection. (See Exposure
Controls, Personal Protection section). Remove all sources of
ignition. Use a spark-proof tool. Do not let this chemical enter the
environment.
Section 7 - Handling and Storage
|
Handling:
Use with adequate ventilation. Use spark-proof tools and explosion
proof equipment. Avoid contact with eyes, skin, and clothing. Keep
away from heat, sparks and flame. Avoid ingestion and inhalation.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Use explosion-proof ventilation equipment. Facilities storing or
utilizing this material should be equipped with an eyewash facility
and a safety shower. Use adequate ventilation to keep airborne
concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Stoddard solvent
|
100 ppm TWA
|
350 mg/m3 TWA 20000 mg/m3 IDLH
|
500 ppm TWA; 2900 mg/m3 TWA
|
OSHA Vacated PELs:
Stoddard solvent:
100 ppm TWA; 525 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Clear liquid
Appearance: APHA: 25 max
Odor: kerosine-like
pH: Not available.
Vapor Pressure: 2 mm Hg @ 20 deg C
Vapor Density: 4.0
Evaporation Rate:0.1 (butyl acetate=1)
Viscosity: 0.91 - 0.95 cp @ 25 deg C
Boiling Point: 149 - 213 deg C
Freezing/Melting Point:-40 deg C
Decomposition Temperature:Not available.
Solubility: Insoluble.
Specific Gravity/Density:0.787
Molecular Formula:Not available.
Molecular Weight:Not available.
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 8052-41-3:
WJ8925000
LD50/LC50:
CAS# 8052-41-3:
Draize test,
rabbit, eye: 500 mg/24H Moderate;
.
Carcinogenicity:
CAS# 8052-41-3:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
Epidemiological studies involving petroleum refinery
workers indicate persons with routine exposure to
petroleum or one of its constituents may be at an
increased risk to the development of benign neoplasms,
digestive tract cancer, and skin cancer.
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
No information found
Neurotoxicity:
No information found
Other Studies:
Section 12 - Ecological Information
|
Ecotoxicity:
No data available.
No information available.
Environmental:
No information available.
Physical:
No information available.
Other:
Do not empty into drains.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
PETROLEUM DISTILLATES, N.O.S. |
PETROLEUM DISTILLATES, N.O.S. |
Hazard Class: |
3 |
3 |
UN Number: |
UN1268 |
UN1268 |
Packing Group: |
III |
III |
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 8052-41-3 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 8052-41-3: immediate, delayed, fire.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 8052-41-3 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XN N
Risk Phrases:
R 10 Flammable.
R 51/53 Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
R 65 Harmful: may cause lung damage if swallowed.
R 66 Repeated exposure may cause skin dryness or cracking.
Safety Phrases:
S 16 Keep away from sources of ignition - No smoking.
S 23 Do not inhale gas/fumes/vapour/spray.
S 24 Avoid contact with skin.
S 36 Wear suitable protective clothing.
S 60 This material and its container must be disposed of as hazardou
s waste.
S 62 If swallowed, do not induce vomiting: seek medical advice immed
iately and show this container or label.
WGK (Water Danger/Protection)
CAS# 8052-41-3: No information available.
Canada - DSL/NDSL
CAS# 8052-41-3 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of B3, D2B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 8052-41-3 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 3/19/1999
Revision #10 Date: 10/03/2007
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.