Material Safety Data Sheet
Amyl acetate

ACC# 15270
Section 1 - Chemical Product and Company Identification

MSDS Name: Amyl acetate
Catalog Numbers: S79902, A718-4, A718-500, ZZ036882C2
Synonyms:
Acetic acid, pentyl ester; Acetic acid, amyl ester; n-Amyl acetate; Pentyl acetate; n-Pentyl acetate.
Company Identification:

              Fisher Scientific
              1 Reagent Lane
              Fair Lawn, NJ 07410
For information, call:
201-796-7100
Emergency Number:
201-796-7100
For CHEMTREC assistance, call:
800-424-9300
For International CHEMTREC assistance, call:
703-527-3887

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
628-63-7 Amyl acetate 100 211-047-3

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: colorless liquid. Flash Point: 23 deg C.
Warning! Flammable liquid and vapor. Causes eye irritation. May cause skin irritation. May cause central nervous system depression. May cause liver damage. May cause cardiac disturbances.
Target Organs: Heart, central nervous system, liver.


Potential Health Effects
Eye: Causes eye irritation.
Skin: May cause skin irritation. May be absorbed through the skin. Repeated or prolonged exposure may cause drying and cracking of the skin.
Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause effects similar to those for inhalation exposure. Ingestion of large amounts may cause CNS depression.
Inhalation: Inhalation of high concentrations may cause central nervous system effects characterized by nausea, headache, dizziness, unconsciousness and coma. May cause liver abnormalities. Aspiration may lead to pulmonary edema. Vapors may cause dizziness or suffocation. May cause cardiac abnormalities. Causes irritation of the mucous membrane and upper respiratory tract. May cause burning sensation in the chest.
Chronic: Prolonged or repeated skin contact may cause dermatitis. Chronic exposure may cause liver damage. Chronic exposure will cause neurological degradation and/or abnormalities.

Section 4 - First Aid Measures


Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water runoff can cause environmental damage. Dike and collect water used to fight fire. Vapors may form an explosive mixture with air. Vapors can travel to a source of ignition and flash back. Combustion generates toxic fumes. Will burn if involved in a fire. Use water spray to keep fire-exposed containers cool. Containers may explode in the heat of a fire. Flammable liquid and vapor.
Extinguishing Media: For small fires, use dry chemical, carbon dioxide, water spray or alcohol-resistant foam. For large fires, use water spray, fog, or alcohol-resistant foam. Use water spray to cool fire-exposed containers. Water may be ineffective. Do NOT use straight streams of water.
Flash Point: 23 deg C ( 73.40 deg F)
Autoignition Temperature: 360 deg C ( 680.00 deg F)
Explosion Limits, Lower:1.1 vol %
Upper: 7.5 vol %
NFPA Rating: (estimated) Health: 1; Flammability: 3; Instability: 0

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition. Use a spark-proof tool. Provide ventilation. A vapor suppressing foam may be used to reduce vapors.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use only in a well-ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with skin and eyes. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage: Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a cool, dry, well-ventilated area away from incompatible substances. Flammables-area.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Amyl acetate 50 ppm TWA (listed under Pentyl acetate, all isomers); 100 ppm STEL (listed under Pentyl acetate, all isomers) 100 ppm TWA; 525 mg/m3 TWA 1000 ppm IDLH 100 ppm TWA; 525 mg/m3 TWA

OSHA Vacated PELs: Amyl acetate: 100 ppm TWA; 525 mg/m3 TWA
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - Physical and Chemical Properties


Physical State: Liquid
Appearance: colorless
Odor: odor of pears - banana-like
pH: Not available.
Vapor Pressure: 4 mm Hg @ 20 deg C
Vapor Density: 4.5 (air=1)
Evaporation Rate:0.42 (butyl acetate=1)
Viscosity: 0.91 cps @ 22 deg C
Boiling Point: 142 deg C
Freezing/Melting Point:-70.8 deg C
Decomposition Temperature:Not available.
Solubility: Slightly soluble.
Specific Gravity/Density:0.8760 (water=1)
Molecular Formula:C7H14O2
Molecular Weight:130.0968

Section 10 - Stability and Reactivity


Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: High temperatures, incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials: Strong oxidizing agents, strong bases.
Hazardous Decomposition Products: Carbon monoxide, irritating and toxic fumes and gases, carbon dioxide.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information


RTECS#:      
CAS# 628-63-7: AJ1925000
LD50/LC50:
CAS# 628-63-7:
     Oral, rabbit: LD50 = 7400 mg/kg;
     Oral, rat: LD50 = >1600 mg/kg;
.
Inhalation, human: TCLo = 500 mg/m3/30
Carcinogenicity:
CAS# 628-63-7: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: No information found
Neurotoxicity: No information found
Other Studies:

Section 12 - Ecological Information


Ecotoxicity: Fish: Bluegill/Sunfish: LC50 = 650 mg/L; 96 Hr; Static bioassay at 23CFish: Mosquito Fish: LC50 = 65 mg/L; 24-96 Hr; Unspecified If released on land or in water, volatilization would be important (half-life 5.9 hr in a typical river) and biodegradation, should be a dominant degradative process. Adsorption to soil or sediment would not occur to any significant extent, so leaching into groundwater may occur. Some chemical hydrolysis may occur but only under fairly alkaline conditions. n-Amyl acetate would not be expected to bioconcentrate in aquatic organism.
Environmental: In air, n-amyl acetate will be scavenged by rain and degrade by reaction with photochemically produced hydroxyl radicals estimated half-life 4.5 days).
Physical: No information available.
Other: No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: AMYL ACETATES AMYL ACETATE
Hazard Class: 3 3
UN Number: UN1104 UN1104
Packing Group: III III
Additional Info:FLASHPOINT 16C

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 628-63-7 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     CAS# 628-63-7: 40 CFR 799.5000
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     CAS# 628-63-7: 5000 lb final RQ; 2270 kg final RQ
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 628-63-7: immediate, fire.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 628-63-7 is listed as a Hazardous Substance under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 628-63-7 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
      Not available.
Risk Phrases:

     R 10 Flammable.
     R 66 Repeated exposure may cause skin dryness or cracking.

Safety Phrases:

     S 23 Do not inhale gas/fumes/vapour/spray.
     S 25 Avoid contact with eyes.

WGK (Water Danger/Protection)

     CAS# 628-63-7: 1
Canada - DSL/NDSL
     CAS# 628-63-7 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of B2, D2B.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 628-63-7 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 6/08/1999
Revision #7 Date: 8/23/2006

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.