Material Safety Data Sheet
Styrene-d8, stabilized, 98+ atom% D
ACC# 15476
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Section 1 - Chemical Product and Company Identification |
MSDS Name: Styrene-d8, stabilized, 98+ atom% D
Catalog Numbers:
AC175390000, AC175390010, AC175390050
Synonyms:
Ethenylbenzene; Vinylbenzene
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 19361-62-7 |
Styrene-d8 |
98 | 242-995-6 |
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: colorless clear liquid. Flash Point: 32 deg C.
Cancer suspect agent. This material has been reported to be
susceptible to autoxidation and therefore should be classified as
peroxidizable. Light sensitive. Air sensitive. Hazardous due to
peroxide initiation of polymerization.
Target Organs: Central nervous system,
respiratory system, eyes, skin.
Potential Health Effects
Eye:
Causes severe eye irritation. Contact produces irritation,
tearing, and burning pain. May cause conjunctivitis. Lachrymator
(substance which increases the flow of tears). Causes redness and
pain.
Skin:
Causes moderate skin irritation. May cause dermatitis. Causes
redness and pain.
Ingestion:
May cause central nervous system depression, kidney damage, and
liver damage. May cause gastrointestinal irritation with nausea,
vomiting and diarrhea.
Inhalation:
Harmful if inhaled. Causes respiratory tract irritation. May cause
irritation of the respiratory tract with burning pain in the nose and
throat, coughing, wheezing, shortness of breath and pulmonary edema.
May cause narcotic effects in high concentration.
Chronic:
May cause liver and kidney damage. Prolonged exposure may produce a
narcotic effect. Prolonged or repeated exposure may cause nausea,
dizziness, and headache. Repeated exposure may cause central nervous
system damage.
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Section 4 - First Aid Measures
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Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically
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Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Will burn
if involved in a fire. Water may be ineffective. Material is lighter
than water and a fire may be spread by the use of water. Forms
peroxides of unknown stability. Flammable liquid and vapor.
Extinguishing Media:
Use water spray to cool fire-exposed containers. Use foam, dry
chemical, or carbon dioxide. Water may be ineffective.
Flash Point: 32 deg C ( 89.60 deg F)
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
Not published.
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.
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Section 7 - Handling and Storage
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Handling:
Use spark-proof tools and explosion proof equipment. Avoid breathing
dust, mist, or vapor. Avoid contact with skin and eyes. Use only in a
chemical fume hood.
Storage:
Keep away from sources of ignition. Do not store in direct sunlight.
Store in a tightly closed container. Store in a dry area.
Refrigerator/flammables. Store under an inert atmosphere.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| Styrene-d8
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none listed
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none listed
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none listed
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| Styrene
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20 ppm TWA; 40 ppm STEL
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50 ppm TWA; 215 mg/m3 TWA 700 ppm IDLH
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100 ppm TWA; 200 ppm Ceiling
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OSHA Vacated PELs:
Styrene-d8:
No OSHA Vacated PELs are listed for this chemical.
Styrene:
50 ppm TWA; 215 mg/m3 TWA
Personal Protective Equipment
Eyes:
Not available.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
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Section 9 - Physical and Chemical Properties
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Physical State: Clear liquid
Appearance: colorless
Odor: characteristic odor - penetrating odor - pungent odor
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 50 - 51 deg C @ 25.
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Not available.
Specific Gravity/Density:.9790g/cm3
Molecular Formula:C6D5CD=CD2
Molecular Weight:112.22
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Section 10 - Stability and Reactivity
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Chemical Stability:
Prolonged exposure to air and sunlight may form unstable peroxides.
Conditions to Avoid:
High temperatures, incompatible materials, light, ignition sources,
exposure to air, exposure to moist air or water, temperatures above
40°C.
Incompatibilities with Other Materials:
Oxidizing materials, sulfuric acid, chlorosulfonic acid, oleum,
dibenzoyl peroxide.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: May occur.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 19361-62-7
unlisted.
CAS# 100-42-5:
WL3675000
LD50/LC50:
Not available.
CAS# 100-42-5:
Draize test,
rabbit, eye: 100 mg Severe;
Draize
test, rabbit, eye: 100 mg/24H Moderate;
Draize test, rabbit, skin: 100%
Moderate;
Inhalation, mouse: LC50 =
21000 mg/m3/2H;
Inhalation, mouse:
LC50 = 9500 mg/m3/4H;
Inhalation,
rat: LC50 = 11800 mg/m3/4H;
Oral,
mouse: LD50 = 316 mg/kg;
Oral,
rat: LD50 = 2650 mg/kg;
Oral, rat:
LD50 = 5000 mg/kg;
.
Carcinogenicity:
CAS# 19361-62-7:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 100-42-5:
- ACGIH:
Not listed.
- California:
Not listed.
- NTP:
Not listed.
- IARC:
Group 2B carcinogen
Epidemiology:
CAS#100-42-5: Tumorigenic: inh-rat TCL0: 100 ppm/4H/5D/1Y-I
Teratogenicity:
CAS#100-42-5: In a study of 511 occupationally exposed
woman and their children there was no evidence of an
association with birth defects, in fact the rates were
lower than expected (Harkohen,H. et al Ann.Acad.Med.
(Singapore) 1984, 13, 404-407).In occupationally exposed
workers menstrual and ovulatory disorders reported
(Lemasters,G.K. JOM,J.Occup.Med. 1985, 27(7), 490-494).For
further information see Dictionary of Substances and their
Effects (DOSE).
Reproductive Effects:
CAS#100-42-5: orl-rat TDL0: 8600 mg/kg (1-22D preg)orl-rat
TDL0: 5575 mg/kg (multigenerations)orl-rat TDL0: 4 gm/kg
(6-15D preg)orl-rat TDL0: 11470 mg/kg (6-15D preg)inh-rat
TCL0: 300 ppm/7H (6-15D preg)inh-rat TCL0: 1500 µg/m3/24H
(1-22D preg)inh-mus TCL0: 500 ppm/6H (6-16D preg)inh-ham
TCL0: 1000 ppm/6H (6-18D preg)
Mutagenicity:
CAS#100-42-5: mmo-sat 1 µmol/platemmo-smc 1 mmol/lmrc-smc 1
mmol/ldns-hmn: lym 100 µmol/ldni-hmn: hla 28
mmol/lcyt-hmn-ihl 7500 ppb/8H/5D-Icyt-hmn: lym 300
ppm/72Hsce-hmn-ihl 1204 mg/m3/5Y-Isce-hmn: lym 500
µmol/lotr-rat: emb 145 µg/platednd-rat: lvr 3
mmol/lcyt-rat-ihl 300 ppm/8W-IFor further information see
actual RTECS.
Neurotoxicity:
No data available.
Other Studies:
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Section 12 - Ecological Information
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Ecotoxicity:
No data available.
CAS# 100-42-5: Fish toxicity:LC50 (96 hr) sheepshead minnow, bluegill
sunfish 9.1, 25 mg/l, respectively (Heitmuller, P.T. et al
Bull.Environ.Contam.Toxicol. 1981, 27, 596-604; Pickering,Q.H. et al
J.Water Pollut.Control Fed. 1966, 38, 1419-1429).LC50 (24 hr)
goldfish 26 mg/l (Bridie,A.L. et al Water Res. 1979, 13,
623).Invertebrate toxicity:Cell multiplication inhibition test
Pseudomonas putida, Scenedesmus quadricauda and Entosiphon sulcatum
72, >200 and >256 mg/l, respectively (Bringmann,G. et al Water Res.
1980, 14, 231-241)For further information see DOSE.
Environmental:
CAS#100-42-5: Anaerobic effects:Degraded by methanogenic microbes,
including Enterobacter and Clostridium sp., isolated from anaerobic
sewage sludges, to CO2. Intermediate products were benzoic acid and
phenol. No methane production was seen during incubation for 8
months. Degradation was initiated through an oxidation-reduction
reaction with the most likely mechanism being the addition of water
across the double bond in the alkenyl side chain (Grbic-Galic,D. et
al J.Appl.Bacteriol.1990, 69(2), 247-260).For further information
see DOSE.
Physical:
No information available.
Other:
No information available.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
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Section 14 - Transport Information
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| |
US DOT |
Canada TDG |
| Shipping Name: |
DOT regulated - small quantity provisions apply (see 49CFR173.4) |
STYRENE MONOMER, STABILIZED |
| Hazard Class: |
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3 |
| UN Number: |
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UN2055 |
| Packing Group: |
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III |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 19361-62-7 is listed on the TSCA inventory.
CAS# 100-42-5 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 100-42-5: 1000 lb final RQ; 454 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 100-42-5: immediate, delayed, fire, reactive.
Section 313
This material contains Styrene
(CAS# 100-42-5, -%),which is subject to the reporting requirements
of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
CAS# 100-42-5 is listed as a hazardous air pollutant (HAP).
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 100-42-5 is listed as a Hazardous Substance under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 19361-62-7 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 100-42-5 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XN
Risk Phrases:
R 10 Flammable.
R 36/38 Irritating to eyes and skin.
R 20 Harmful by inhalation.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
WGK (Water Danger/Protection)
CAS# 19361-62-7: No information available.
CAS# 100-42-5: 2
Canada - DSL/NDSL
CAS# 100-42-5 is listed on Canada's DSL List.
CAS# 19361-62-7 is listed on Canada's NDSL List.
Canada - WHMIS
This product has a WHMIS classification of B2.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 100-42-5 is listed on the Canadian Ingredient Disclosure List.
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Section 16 - Additional Information
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MSDS Creation Date: 1/18/2000
Revision #4 Date: 11/20/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.