Material Safety Data Sheet
2-Chloroethyl chloroformate, Manufactured by BASF Distributed by Acros Organics
ACC# 16553
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Section 1 - Chemical Product and Company Identification |
MSDS Name: 2-Chloroethyl chloroformate, Manufactured by BASF Distributed by
Acros Organics
Catalog Numbers:
AC395330000
Synonyms:
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
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Section 2 - Composition, Information on Ingredients
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| CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
| 627-11-2 |
Chloroethyl chloroformate |
98+% | 210-982-4 |
| 107-06-2 |
Ethylene dichloride |
<0.3% | 203-458-1 |
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Not available.
Appearance: colorless to yellow liquid. Flash Point: 79 deg C.
Not available.
Target Organs: Respiratory system,
gastrointestinal system, eyes, skin.
Potential Health Effects
Eye:
Causes eye burns. Lachrymator (substance which increases the flow
of tears).
Skin:
Causes skin burns. May be harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. Causes gastrointestinal tract burns.
Inhalation:
Causes chemical burns to the respiratory tract. Toxic if inhaled.
Chronic:
May cause cancer in humans.
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Section 4 - First Aid Measures
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Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
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Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Water reactive. Material will react with water and
may release a flammable and/or toxic gas.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide. DO NOT USE WATER!
Flash Point: 79 deg C ( 174.20 deg F)
Autoignition Temperature: 470 deg C ( 878.00 deg F)
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
Not published.
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Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Wear a self contained breathing
apparatus and appropriate personal protection. (See Exposure
Controls, Personal Protection section). Do not expose spill to water.
Do not let this chemical enter the environment.
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Section 7 - Handling and Storage
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Handling:
Do not allow water to get into the container because of violent
reaction. Do not breathe dust, mist, or vapor. Do not get in eyes,
on skin, or on clothing. Do not ingest or inhale. Use and store under
nitrogen. Use only in a chemical fume hood.
Storage:
Use only in a chemical fume hood. Store in a tightly closed
container. Store in a dry area. Store protected from moisture.
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Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
| Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
| Chloroethyl chloroformate
|
none listed
|
none listed
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none listed
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| Ethylene dichloride
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10 ppm TWA
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1 ppm TWA; 4 mg/m3 TWA 50 ppm IDLH
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50 ppm TWA; 100 ppm Ceiling
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OSHA Vacated PELs:
Chloroethyl chloroformate:
No OSHA Vacated PELs are listed for this chemical.
Ethylene dichloride:
1 ppm TWA; 4 mg/m3 TWA
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
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Section 9 - Physical and Chemical Properties
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Physical State: Liquid
Appearance: colorless to yellow
Odor: pungent odor
pH: Not available.
Vapor Pressure: 5hPa @20 deg C
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 154 deg C @760mmHg
Freezing/Melting Point:-70 deg C
Decomposition Temperature:Not available.
Solubility: hydrolyzes
Specific Gravity/Density:1.390
Molecular Formula:C3H4Cl2O2
Molecular Weight:142.97
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Section 10 - Stability and Reactivity
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Chemical Stability:
Moisture sensitive.
Conditions to Avoid:
Incompatible materials, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
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Section 11 - Toxicological Information
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RTECS#:
CAS# 627-11-2:
LQ5950000
CAS# 107-06-2:
KI0525000
LD50/LC50:
Not available.
CAS# 107-06-2:
Draize test,
rabbit, eye: 63 mg Severe;
Draize
test, rabbit, eye: 500 mg/24H Mild;
Draize test, rabbit, skin: 500 mg/24H
Mild;
Inhalation, mouse: LC50 =
1060 mg/m3/6H;
Inhalation, rat:
LC50 = 1000 ppm/7H;
Inhalation,
rat: LC50 = 5100 mg/m3/6H;
Oral,
mouse: LD50 = 413 mg/kg;
Oral,
mouse: LD50 = 413 mg/kg;
Oral,
rabbit: LD50 = 860 mg/kg;
Oral,
rabbit: LD50 = 0.7 mL/kg;
Oral,
rat: LD50 = 500 mg/kg;
Skin,
rabbit: LD50 = 2800 mg/kg;
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Carcinogenicity:
CAS# 627-11-2:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 107-06-2:
- ACGIH:
Not listed.
- California:
carcinogen, initial date 10/1/87
- NTP:
Suspect carcinogen
- IARC:
Group 2B carcinogen
Epidemiology:
No data available.
Teratogenicity:
No data available.
Reproductive Effects:
No data available.
Mutagenicity:
No data available.
Neurotoxicity:
No data available.
Other Studies:
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Section 12 - Ecological Information
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Ecotoxicity:
No data available.
No information available.
Environmental:
No information available.
Physical:
No information available.
Other:
Do not empty into drains.
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Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series:
CAS# 107-06-2: waste
number U077.
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Section 14 - Transport Information
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| |
US DOT |
Canada TDG |
| Shipping Name: |
CHLOROFORMATES, TOXIC, CORROSIVE, N.O.S. * |
No information available. |
| Hazard Class: |
6.1 |
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| UN Number: |
UN3277 |
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| Packing Group: |
II |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 627-11-2 is listed on the TSCA inventory.
CAS# 107-06-2 is listed on the TSCA inventory.
Health & Safety Reporting List
CAS# 107-06-2: Effective 6/1/87, Sunset 6/1/97
Chemical Test Rules
CAS# 107-06-2: 40 CFR 799.5115
Section 12b
CAS# 107-06-2: Section 4, 0.1 % de minimus concentration
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 107-06-2: 100 lb final RQ; 45.4 kg final RQ
SARA Section 302 Extremely Hazardous Substances
CAS# 627-11-2: 1000 lb TPQ
SARA Codes
CAS # 107-06-2: immediate, delayed, fire.
Section 313
This material contains Ethylene
dichloride (CAS# 107-06-2, <0.3%),which is subject to the reporting
requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
CAS# 107-06-2 is listed as a hazardous air pollutant (HAP).
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 107-06-2 is listed as a Hazardous Substance under the CWA.
CAS# 107-06-2 is listed as a Priority Pollutant under the Clean Water
Act.
CAS# 107-06-2 is listed as a Toxic Pollutant under the Clean Water
Act.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 627-11-2 can be found on the
following state right to know lists: New Jersey, Pennsylvania,
Massachusetts.
CAS# 107-06-2 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
California Prop 65
WARNING: This product contains Ethylene dichloride, a chemical known
to the state of California to cause cancer.
California No Significant Risk Level:
CAS# 107-06-2: 10 ęg/day NSRL
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
T N
Risk Phrases:
R 22 Harmful if swallowed.
R 23 Toxic by inhalation.
R 29 Contact with water liberates toxic gas.
R 34 Causes burns.
R 45 May cause cancer.
R 51/53 Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 29 Do not empty into drains.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face pr
otection.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S 53 Avoid exposure - obtain special instructions before use.
S 8 Keep container dry.
S 61 Avoid release to the environment. Refer to special instructions
/safety data sheets.
WGK (Water Danger/Protection)
CAS# 627-11-2: No information available.
CAS# 107-06-2: 3
Canada - DSL/NDSL
CAS# 107-06-2 is listed on Canada's DSL List.
CAS# 627-11-2 is listed on Canada's NDSL List.
Canada - WHMIS
not available.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 107-06-2 is listed on the Canadian Ingredient Disclosure List.
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Section 16 - Additional Information
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MSDS Creation Date: 6/08/2007
Revision #0 Date: Original.
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.