Material Safety Data Sheet
Mercurochrome, 24-27% Mercury (corrected for volatiles)
ACC# 16795
Section 1 - Chemical Product and Company Identification |
MSDS Name: Mercurochrome, 24-27% Mercury (corrected for volatiles)
Catalog Numbers:
AC190110000, AC190110250, AC190111000
Synonyms:
Merbromin; 2,7-Dibromo-4-hydroxymercurifluoresceine disodium salt;
Disodium 2',7'-dibromo-4'-(hydroxymercury)fluorescein; Disodium
2,7-dibrom-4-hydroxy-mercuri-fluorescein; DOMF; Fluorescein,
2',7'-dibromo-4'-(hydroxymercurio)-, disodium salt;Mercury,
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
129-16-8 |
Mercurochrome |
100 | 204-933-6 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: green crystals.
Danger! May be fatal if inhaled, absorbed through
the skin or swallowed. Danger of cumulative effects. The
toxicological properties of this material have not been fully
investigated.
Target Organs: Nervous system.
Potential Health Effects
Eye:
May cause eye irritation. May cause conjunctivitis.
Skin:
May be fatal if absorbed through the skin. May cause irritation and
dermatitis.
Ingestion:
May be fatal if swallowed. May cause central nervous system
depression. May cause excessive salivation and loosening of the
teeth. May cause nausea, vomiting, and diarrhea, possibly with
blood.
Inhalation:
May be fatal if inhaled. May produce general weakness, vomiting,
diarrhea, chest pains, coughing, shortness of breath, and cardiac
insufficiency. Causes irritation of the mucous membrane and upper
respiratory tract.
Chronic:
There is a danger of cumulative effects. Chronic exposure to mercury
compounds may produce immunologic glomerular disease.
Section 4 - First Aid Measures
|
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Discard contaminated clothing in a manner which limits
further exposure.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Runoff from
fire control or dilution water may cause pollution.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 3; Flammability: 0; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Do not flush into a sewer. Avoid generating dusty
conditions. Provide ventilation.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Minimize dust
generation and accumulation. Do not breathe dust, mist, or vapor. Do
not get in eyes, on skin, or on clothing. Do not ingest or inhale.
Use only in a chemical fume hood. Discard contaminated shoes.
Storage:
Store in a tightly closed container. Poison room locked. Store in a
cool, dry area away from incompatible substances.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Mercurochrome
|
0.1 mg/m3 TWA (as Hg) (listed under Mercury, aryl and inorganic compounds).Skin - potential significant contribution to overall exposure by the cutaneous r oute (listed under Mercury, aryl and inorga
nic compounds).
|
0.05 mg/m3 TWA (vapor, except organo alkyls, as Hg) (listed under Mercury compounds).10 mg/m3 IDLH (as Hg, except organo(alkyl) compounds) (listed under Mercury compounds).
|
none listed
|
OSHA Vacated PELs:
Mercurochrome:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
Section 9 - Physical and Chemical Properties
|
Physical State: Crystals
Appearance: green
Odor: none reported
pH: 8.8 (0.5% aq. soln)
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:> 300 deg C
Decomposition Temperature:Not available.
Solubility: Soluble.
Specific Gravity/Density:Not available.
Molecular Formula:C20H8Br2HgO6Na2
Molecular Weight:750.43
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation.
Incompatibilities with Other Materials:
Acids, alkaloid salts, strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Carbon monoxide, irritating and toxic fumes and gases, carbon
dioxide, hydrogen bromide, mercury/mercury oxides.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 129-16-8:
LM5250000
LD50/LC50:
Not available.
Carcinogenicity:
CAS# 129-16-8:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information found
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
Mutagenic effects have occurred in experimental animals.
Neurotoxicity:
No information found
Other Studies:
Section 12 - Ecological Information
|
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
PHENYLMERCURIC COMPOUNDS, N.O.S. |
PHENYLMERCURIC COMPOUND NOS (MERCUROCHROME) |
Hazard Class: |
6.1 |
6.1 |
UN Number: |
UN2026 |
UN2026 |
Packing Group: |
II |
II |
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 129-16-8 is not listed on the TSCA inventory.
It is for research and development use only.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
This material contains
Mercurochrome (listed as Mercury compounds), 100%, (CAS# 129-16-8)
which is subject to the reporting requirements of Section 313 of SARA
Title III and 40 CFR Part 373.
Clean Air Act:
CAS# 129-16-8 (listed as Mercury compounds) is listed as a hazardous a
ir pollutant (HAP).
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
CAS# 129-16-8 is listed as a Toxic Pollutant under the Clean Water
Act.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 129-16-8 can be found on the
following state right to know lists: California, (listed as Mercury
compounds), New Jersey, (listed as Mercury compounds), Pennsylvania,
(listed as Mercury compounds), Pennsylvania, (listed as Mercury,
aryl and inorganic compounds).
California Prop 65
WARNING: This product contains Mercurochrome, listed as `Mercury
compounds', a chemical known to the state of California to cause
developmental reproductive toxicity.
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
T+
Risk Phrases:
R 26/27/28 Very toxic by inhalation, in contact with skin and if
swallowed.
R 33 Danger of cumulative effects.
Safety Phrases:
S 13 Keep away from food, drink and animal feeding stuffs.
S 36 Wear suitable protective clothing.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S 28A After contact with skin, wash immediately with plenty of water
.
WGK (Water Danger/Protection)
CAS# 129-16-8: No information available.
Canada - DSL/NDSL
CAS# 129-16-8 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D2A, D1B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 129-16-8 (listed as Mercury compounds) is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 9/02/1997
Revision #6 Date: 9/26/2007
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.