Material Safety Data Sheet
Aluminum-nickel, Raney-type alloy, powder, Al-Ni 50/50

ACC# 19871
Section 1 - Chemical Product and Company Identification
MSDS Name: Aluminum-nickel, Raney-type alloy, powder, Al-Ni 50/50
Catalog Numbers: AC206230000, AC206230050, AC206231000, AC206235000
Synonyms: Raney-type alloy for the preparation of Raney Nickel catalyst.
Company Identification:
              Acros Organics N.V.
              One Reagent Lane
              Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
12635-29-9 Aluminum-Nickel alloy 100 unlisted

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: grey powder.
Danger! Water-reactive. Contact with water liberates extremely flammable gases. May cause allergic skin reaction. May cause eye, skin, and respiratory tract irritation. Cancer suspect agent.
Target Organs: Skin.


Potential Health Effects
Eye: May cause eye irritation. Aluminum particles may cause corneal necrosis.
Skin: May cause skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. May be harmful if absorbed through the skin. Causes "nickel itch" which is a dermatitis resulting from sensitization to nickel, which is characterized by skin eruptions, followed by discrete ulcers that may discharge and become crusted, or by eczema.
Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. The toxicological properties of this substance have not been fully investigated. May be harmful if swallowed.
Inhalation: May cause respiratory tract irritation. Inhalation of fumes may cause metal fume fever, which is characterized by flu-like symptoms with metallic taste, fever, chills, cough, weakness, chest pain, muscle pain and increased white blood cell count. May cause anosmia (loss of smell). Exposure may cause coughing, shortness of breath, lethargy, and an increased respiration rate. Breathing Nickel (Dust and Fume) can cause a sore or hole in the "bone" (septum) dividing the inner nose.
Chronic: Possible cancer hazard based on tests with laboratory animals. Chronic inhalation of fine dusts may cause lung damage. Chronic inhalation may cause pulmonary fibrosis. Repeated inhalation may cause perforation of the nasal septum.

Section 4 - First Aid Measures


Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water. Wash mouth out with water.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Water reactive. Material will react with water and may release a flammable and/or toxic gas. This material in sufficient quantity and reduced particle size is capable of creating a dust explosion.
Extinguishing Media: Do NOT use water directly on fire. Do NOT use carbon dioxide. Use dry chemical to fight fire.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 2; Flammability: 1; Instability: 2; Special Hazard: -W-

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Vacuum or sweep up material and place into a suitable disposal container. Clean up spills immediately, observing precautions in the Protective Equipment section. Avoid generating dusty conditions. Provide ventilation. Remove ignition sources since flammable hydrogen gas may be generated by reaction with water.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Do not allow contact with water. Keep from contact with moist air and steam.
Storage: Store in a cool, dry place. Store in a tightly closed container. Keep away from water.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Aluminum-Nickel alloy none listed 0.015 mg/m3 TWA (as Ni, except Nickel carbonyl) (listed under Nickel compounds).10 mg/m3 IDLH (as Ni, except Nickel carbonyl) (listed under Nickel compounds). 1 mg/m3 TWA (as Ni) (listed under Nickel soluble compounds).

OSHA Vacated PELs: Aluminum-Nickel alloy: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective gloves to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties


Physical State: Powder
Appearance: grey
Odor: Odorless
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:1350 deg C
Decomposition Temperature:Not available.
Solubility: reacts slowly forming H2
Specific Gravity/Density:3.4600g/cm3
Molecular Formula:AlNi
Molecular Weight:85.68

Section 10 - Stability and Reactivity


Chemical Stability: Water contact produces hydrogen gas.
Conditions to Avoid: Dust generation, contact with water.
Incompatibilities with Other Materials: Strong oxidizing agents, strong acids.
Hazardous Decomposition Products: Aluminum oxide, nickel oxide.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information


RTECS#:      
CAS# 12635-29-9 unlisted.
LD50/LC50:
Not available.

Carcinogenicity:
CAS# 12635-29-9:


Epidemiology: An increased incidence of lung and nasal cavity cancers has been noted among women in nickel smelters and refineries.Epidemiological studies have shown an increased incidence of cancers among nickel refinery workers.
Teratogenicity: No data available.
Reproductive Effects: No data available.
Mutagenicity: No data available.
Neurotoxicity: No data available.
Other Studies:

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: WATER-REACTIVE SOLID, N.O.S. WATER-REACTIVE SOLID NOS (ALUMINUM-NICKEL)
Hazard Class: 4.3 4.3
UN Number: UN2813 UN2813
Packing Group: II III

Section 15 - Regulatory Information

US FEDERAL
TSCA
     CAS# 12635-29-9 is not listed on the TSCA inventory. It is for research and development use only.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 12635-29-9: immediate, delayed, fire.
Section 313
     This material contains Aluminum-Nickel alloy (listed as Nickel compounds), 100%, (CAS# 12635-29-9) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
     CAS# 12635-29-9 (listed as Nickel compounds) is listed as a hazardous      air pollutant (HAP).
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA. CAS# 12635-29-9 is listed as a Toxic Pollutant under the Clean Water Act.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 12635-29-9 can be found on the following state right to know lists: California, (listed as Nickel compounds), New Jersey, (listed as Nickel compounds), Pennsylvania, (listed as Nickel compounds), Minnesota, (listed as Nickel soluble compounds).

California Prop 65
The following statement(s) is(are) made in order to comply with the California Safe Drinking Water Act:
WARNING: This product contains Aluminum-Nickel alloy, listed as `Nickel compounds', a chemical known to the state of California to cause cancer.
California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
     XN F
Risk Phrases:
     R 15 Contact with water liberates extremely flammable gases.
     R 40 Limited evidence of a carcinogenic effect.
     R 43 May cause sensitization by skin contact.

Safety Phrases:
     S 22 Do not breathe dust.
     S 36 Wear suitable protective clothing.
     S 7/8 Keep container tightly closed and dry.
     S 43A In case of fire, use dry chemical (never use water).

WGK (Water Danger/Protection)
     CAS# 12635-29-9: No information available.
Canada - DSL/NDSL
None of the chemicals in this product are listed on the DSL or NDSL list.
Canada - WHMIS
     This product has a WHMIS classification of B6, D2A, D2B.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 12635-29-9 (listed as Nickel soluble compounds) is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 8/24/1997
Revision #7 Date: 3/16/2007

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.