Material Safety Data Sheet
Sodium chromate
ACC# 21130
Section 1 - Chemical Product and Company Identification |
MSDS Name: Sodium chromate
Catalog Numbers:
AC377870000, AC377870050, AC377870250, AC377871000, 61139-5000, S272-250,
S272-500
Synonyms:
Chromic acid, disodium salt.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
7775-11-3 |
Sodium chromate |
100 | 231-889-5 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: yellow solid.
Danger! Toxic if swallowed. Danger of serious
damage to health by prolonged exposure through inhalation. May be
fatal if inhaled. Causes burns by all exposure routes. Strong
oxidizer. Contact with other material may cause a fire. May impair
fertility. May cause harm to the unborn child. Harmful if absorbed
through the skin. Cancer hazard. Toxic to aquatic organisms, may
cause long-term adverse effects in the aquatic environment. May cause
heritable genetic damage. May cause sensitization by inhalation and
by skin contact. Hygroscopic (absorbs moisture from the air).
Target Organs: Blood, kidneys, liver,
respiratory system, gastrointestinal system, eyes, skin.
Potential Health Effects
Eye:
Causes eye burns.
Skin:
Harmful if absorbed through the skin. Causes skin burns. May cause
sensitization by skin contact.
Ingestion:
Causes gastrointestinal tract burns. Toxic if swallowed.
Inhalation:
May be fatal if inhaled. Causes chemical burns to the respiratory
tract. May cause respiratory sensitization.
Chronic:
May cause cancer in humans. Repeated or prolonged exposure may cause
allergic reactions in sensitive individuals. Possible risk of harm to
the unborn child. May impair fertility.
Section 4 - First Aid Measures
|
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Do not induce vomiting. Get medical aid immediately. Call a poison
control center.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do not use
mouth-to-mouth resuscitation if victim ingested or inhaled the
substance; induce artificial respiration with the aid of a pocket
mask equipped with a one-way valve or other proper respiratory
medical device.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
Use foam, dry chemical, or carbon dioxide.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 4; Flammability: 1; Instability: 2; Special Hazard: OX
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Wear a self contained breathing apparatus and appropriate
personal protection. (See Exposure Controls, Personal Protection
section). Avoid generating dusty conditions. Provide ventilation.
Keep combustibles (wood, paper, oil, etc.,) away from spilled
material. Evacuate unnecessary personnel. Do not let this chemical
enter the environment.
Section 7 - Handling and Storage
|
Handling:
Minimize dust generation and accumulation. Do not get in eyes, on
skin, or on clothing. Avoid contact with clothing and other
combustible materials. Do not ingest or inhale. Use only in a
chemical fume hood.
Storage:
Do not store near combustible materials. Store in a cool, dry place.
Store in a tightly closed container.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use only under a
chemical fume hood.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Sodium chromate
|
0.05 mg/m3 TWA (as Cr) (listed under Chromium (VI) compounds- water soluble).
|
0.001 mg/m3 TWA (as Cr) (listed under Chromates).15 mg/m3 IDLH (as Cr(VI)) (listed under Chromates).
|
5 æg/m3 TWA (listed under Chromium (VI) compounds).0.1 mg/m3 Ceiling (as CrO3, applies to any operations or sectors for which the H exavalent Chromium standard [29 CFR 1910.1026] is stayed or is othe
rwise not in effect) (listed under Chromates).2.5 æg/m3 Action Level (as Cr.); 5 æg/m3 TWA (as Cr, Cancer hazard - see 29 CFR 1910.1026) (listed under Chromium (VI) compounds).
|
OSHA Vacated PELs:
Sodium chromate:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Solid
Appearance: yellow
Odor: odorless
pH: 9.2 (100 g/L aq.sol.)
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:792 deg C
Decomposition Temperature:Not available.
Solubility: 530 g/L (20°C)
Specific Gravity/Density:Not available.
Molecular Formula:CrNa2O4
Molecular Weight:161.97
Section 10 - Stability and Reactivity
|
Chemical Stability:
Hygroscopic: absorbs moisture or water from the air.
Conditions to Avoid:
Incompatible materials, dust generation, combustible materials,
exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong reducing agents.
Hazardous Decomposition Products:
Toxic fumes of sodium oxide, toxic chromium oxide fumes.
Hazardous Polymerization: Will not occur.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 7775-11-3:
GB2955000
LD50/LC50:
CAS# 7775-11-3:
Oral, rat: LD50 =
136 mg/kg;
.
Dermal LDLo guinea pig: 206 mg/kg.
Carcinogenicity:
CAS# 7775-11-3:
- ACGIH:
A1 - Confirmed Human Carcinogen (listed as 'Chromium (VI) compounds- water soluble').
- California:
carcinogen, initial date 2/27/87 (listed as Chromium (VI) compounds).
- NTP:
Known carcinogen (listed as Chromium (VI) compounds).
- IARC:
Group 1 carcinogen
Epidemiology:
IARC Group 1: Proven human carcinogenic substance.
Teratogenicity:
No information found.
Reproductive Effects:
Adverse reproductive effects have occurred in experimental
animals.
Mutagenicity:
Mutagenic effects have occurred in humans.
Neurotoxicity:
No information reported
Other Studies:
Section 12 - Ecological Information
|
Ecotoxicity:
No data available.
No information available.
Environmental:
No information available.
Physical:
No information available.
Other:
Do not empty into drains.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
OXIDIZING SOLID, TOXIC, N.O.S. |
OXIDIZING SOLID, TOXIC, N.O.S. |
Hazard Class: |
5.1 |
5.1 |
UN Number: |
UN3087 |
UN3087 |
Packing Group: |
III |
III |
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 7775-11-3 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
CAS# 7775-11-3: Section 6, 0.1 % de minimus concentration [see 40 CFR 749.68]
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 7775-11-3: 10 lb final RQ; 4.54 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 7775-11-3: immediate, delayed.
Section 313
This material contains Sodium
chromate (listed as Chromium (VI) compounds), 100%, (CAS# 7775-11-3)
which is subject to the reporting requirements of Section 313 of
SARA Title III and 40 CFR Part 373.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 7775-11-3 is listed as a Hazardous Substance under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 7775-11-3 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, (listed as Chromium (VI) compounds- water
soluble), Minnesota, (listed as Chromium (VI) compounds),
Massachusetts.
California Prop 65
The following statement(s) is(are) made in order to comply with
the California Safe Drinking Water Act:
WARNING: This product contains Sodium chromate, listed as `Chromium
(VI) compounds', a chemical known to the state of California to
cause cancer.
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
T+ N
Risk Phrases:
R 21 Harmful in contact with skin.
R 25 Toxic if swallowed.
R 26 Very toxic by inhalation.
R 34 Causes burns.
R 42/43 May cause sensitization by inhalation and skin contact.
R 45 May cause cancer.
R 46 May cause heritable genetic damage.
R 48/23 Toxic : danger of serious damage to health by prolonged
exposure through inhalation.
R 60 May impair fertility.
R 61 May cause harm to the unborn child.
R 50/53 Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
Safety Phrases:
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S 53 Avoid exposure - obtain special instructions before use.
S 60 This material and its container must be disposed of as hazardou
s waste.
S 61 Avoid release to the environment. Refer to special instructions
/safety data sheets.
WGK (Water Danger/Protection)
CAS# 7775-11-3: 3
Canada - DSL/NDSL
CAS# 7775-11-3 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D1A, D2A, D2B, E.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 7775-11-3 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 2/23/1998
Revision #12 Date: 5/11/2009
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.