Material Safety Data Sheet
Turpentine Oil

ACC# 24580
Section 1 - Chemical Product and Company Identification

MSDS Name: Turpentine Oil
Catalog Numbers: S80236
Synonyms:
Spirit of Turpentine; oil of turpentine; wood turpentine
Company Identification:

              Fisher Scientific
              1 Reagent Lane
              Fair Lawn, NJ 07410
For information, call:
201-796-7100
Emergency Number:
201-796-7100
For CHEMTREC assistance, call:
800-424-9300
For International CHEMTREC assistance, call:
703-527-3887

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
8006-64-2 Turpentine 100.0 232-350-7

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: colorless liquid. Flash Point: 35 deg C.
Warning! Flammable liquid and vapor. Harmful or fatal if swallowed. May cause severe eye irritation and possible injury. May cause allergic skin reaction. Aspiration hazard if swallowed. Can enter lungs and cause damage. Causes digestive and respiratory tract irritation. May cause skin irritation. May cause central nervous system depression. May cause kidney damage.
Target Organs: None.


Potential Health Effects
Eye: Contact with eyes may cause severe irritation, and possible eye burns.
Skin: Causes skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion: Causes gastrointestinal irritation with nausea, vomiting and diarrhea. May cause kidney damage. May cause central nervous system depression, characterized by excitement, followed by headache, dizziness, drowsiness, and nausea. Advanced stages may cause collapse, unconsciousness, coma and possible death due to respiratory failure. Aspiration of material into the lungs may cause chemical pneumonitis, which may be fatal.
Inhalation: May cause respiratory tract irritation. Aspiration may cause respiratory swelling and pneumonitis.
Chronic: Not available.

Section 4 - First Aid Measures


Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin: Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if irritation develops or persists.
Ingestion: Do not induce vomiting. Get medical aid immediately.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician: Treat symptomatically

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Flammable Liquid. Can release vapors that form explosive mixtures at temperatures above the flashpoint.
Extinguishing Media: Use water fog, dry chemical, carbon dioxide, or regular foam.
Flash Point: 35 deg C ( 95.00 deg F)
Autoignition Temperature: 253.3 deg C ( 487.94 deg F)
Explosion Limits, Lower:0.8% v/v
Upper: None reported
NFPA Rating: (estimated) Health: ; Flammability: ; Instability:

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Use a spark-proof tool.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Wash thoroughly after handling. Use only in a well-ventilated area. Ground and bond containers when transferring material. Use spark-proof tools and explosion proof equipment. Avoid contact with skin and eyes. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid ingestion and inhalation. Do not ingest or inhale. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage: Keep away from sources of ignition. Store in a cool place in the original container and protect from sunlight. Store in a tightly closed container.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Use adequate general or local explosion-proof ventilation to keep airborne levels to acceptable levels.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Turpentine 20 ppm TWA 100 ppm TWA; 560 mg/m3 TWA 800 ppm IDLH 100 ppm TWA; 560 mg/m3 TWA

OSHA Vacated PELs: Turpentine: 100 ppm TWA; 560 mg/m3 TWA
Personal Protective Equipment
Eyes: Wear chemical splash goggles.
Skin: Wear appropriate gloves to prevent skin exposure.
Clothing: Wear appropriate gloves to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties


Physical State: Liquid
Appearance: colorless
Odor: disagreeable odor
pH: Not available.
Vapor Pressure: 577 mm Hg
Vapor Density: 4.7
Evaporation Rate:0.86 (Butyl Acetate=1)
Viscosity: Not available.
Boiling Point: 154-170 deg C
Freezing/Melting Point:-50 - -60 deg C
Decomposition Temperature:Not available.
Solubility: Insoluble in water
Specific Gravity/Density:0.86 at 59 F
Molecular Formula:C10H16
Molecular Weight:136.112

Section 10 - Stability and Reactivity


Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Ignition sources, exposure to air, excess heat.
Incompatibilities with Other Materials: Calcium hypochlorite, chlorine, chromic anhydride, chromyl chloride, hexachloromelamine, stannic chloride, and trichloromelamine.
Hazardous Decomposition Products: Carbon monoxide.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information


RTECS#:      
CAS# 8006-64-2: YO8400000
LD50/LC50:
CAS# 8006-64-2:
     Draize test, rabbit, skin: 500 uL Severe;
     Inhalation, mouse: LC50 = 29 mg/m3/2H;
     Inhalation, mouse: LC50 = 30000 mg/m3;
     Inhalation, rat: LC50 = 12 gm/m3/6H;
     Inhalation, rat: LC50 = 16600 mg/m3/2H;
     Inhalation, rat: LC50 = 13700 mg/m3/4H;
     Oral, rat: LD50 = 5760 mg/kg;
.

Carcinogenicity:
CAS# 8006-64-2: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Mutagenicity: No information available.
Neurotoxicity: No information available.
Other Studies:

Section 12 - Ecological Information


Ecotoxicity: No data available. No information available.
Environmental: No information available.
Physical: No information available.
Other: May be toxic to aquatic organisms; May cause long-term adverse effects in the aquatic environment.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: TURPENTINE No information available.
Hazard Class: 3
UN Number: UN1299
Packing Group: III

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 8006-64-2 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 8006-64-2 can be found on the following state right to know lists: California, New Jersey, Minnesota, Massachusetts.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
     XN F N
Risk Phrases:

     R 10 Flammable.
     R 20/21/22 Harmful by inhalation, in contact with skin and if
     swallowed.
     R 36/38 Irritating to eyes and skin.
     R 43 May cause sensitization by skin contact.
     R 51/53 Toxic to aquatic organisms, may cause long-term adverse
     effects in the aquatic environment.
     R 65 Harmful: may cause lung damage if swallowed.

Safety Phrases:

     S 36/37 Wear suitable protective clothing and gloves.
     S 46 If swallowed, seek medical advice immediately and show this con
     tainer or label.
     S 61 Avoid release to the environment. Refer to special instructions
     /safety data sheets.
     S 62 If swallowed, do not induce vomiting: seek medical advice immed
     iately and show this container or label.

WGK (Water Danger/Protection)

     CAS# 8006-64-2: No information available.
Canada - DSL/NDSL
     CAS# 8006-64-2 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of B2, D2B.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 8006-64-2 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 12/12/1997
Revision #6 Date: 10/29/2007

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.