Material Safety Data Sheet
3,3'-Diaminodipropylamine, 99% (GC)
ACC# 30009
Section 1 - Chemical Product and Company Identification |
MSDS Name: 3,3'-Diaminodipropylamine, 99% (GC)
Catalog Numbers:
AC406370000, AC406370050, AC406371000, AC406375000
Synonyms:
3,3'-Diaminodipropylamine; Bis-(3-aminopropyl)amine;
Dipropylenetriamine; Norspermidine
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
56-18-8 |
3,3'-Iminobispropylamine |
99 | 200-261-2 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: colourless.
Danger! May be fatal if absorbed through the skin.
Corrosive. Causes severe eye and skin irritation with possible burns.
Causes digestive and respiratory tract irritation with possible
burns. May be harmful if swallowed.
Target Organs: Respiratory system,
gastrointestinal system, eyes, skin.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns.
Skin:
May be fatal if absorbed through the skin. May cause severe
irritation and possible burns.
Ingestion:
May cause severe gastrointestinal tract irritation with nausea,
vomiting and possible burns. May be harmful if swallowed.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema. Causes
chemical burns to the respiratory tract.
Chronic:
Not available.
Section 4 - First Aid Measures
|
Eyes:
Get medical aid immediately. Do NOT allow victim to rub eyes or keep
eyes closed. Extensive irrigation with water is required (at least 30
minutes).
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Discard contaminated clothing in a manner which limits
further exposure. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. Do NOT use mouth-to-mouth
resuscitation.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Use agent most appropriate to extinguish
fire. Do NOT get water inside containers. Contact with water or steam
may produce toxic and flammable vapors.
Flash Point: 118 deg C ( 244.40 deg F)
Autoignition Temperature: 280 deg C ( 536.00 deg F)
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 3; Flammability: 2; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation. Do not get water inside containers.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use only in a well-ventilated area. Do not get in
eyes, on skin, or on clothing. Do not ingest or inhale.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances. Corrosives area. Keep containers tightly closed.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
3,3'-Iminobispropylamine
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
3,3'-Iminobispropylamine:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Liquid
Appearance: colourless
Odor: none reported
pH: Not available.
Vapor Pressure: 0.05 mbar @ 20
Vapor Density: 4.52
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 235 deg C @ 760.00mm Hg
Freezing/Melting Point:-14 deg C
Decomposition Temperature:Not available.
Solubility: Not available.
Specific Gravity/Density:.9380g/cm3
Molecular Formula:C6H17N3
Molecular Weight:131.22
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Oxidizing agents, strong acids, acid chlorides, acid anhydrides,
chloroformates.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 56-18-8:
JL9450000
LD50/LC50:
CAS# 56-18-8:
Draize test, rabbit,
eye: 47 mg Severe;
Inhalation, rat:
LC50 = 30 mg/m3/4H;
Oral, mouse:
LD50 = 435 mg/kg;
Oral, rabbit:
LD50 = 210 mg/kg;
Oral, rat: LD50
= 738 mg/kg;
Skin, rabbit: LD50 =
110 uL/kg;
.
Carcinogenicity:
CAS# 56-18-8:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No data available.
Teratogenicity:
No data available.
Reproductive Effects:
No data available.
Mutagenicity:
No data available.
Neurotoxicity:
No data available.
Other Studies:
Section 12 - Ecological Information
|
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
3,3'-IMINODIPROPYLAMINE |
3,3'-IMINODIPROPYLAMINE |
Hazard Class: |
8 |
8 |
UN Number: |
UN2269 |
UN2269 |
Packing Group: |
III |
III |
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 56-18-8 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 56-18-8 can be found on the
following state right to know lists: New Jersey.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
T+ C
Risk Phrases:
R 22 Harmful if swallowed.
R 24 Toxic in contact with skin.
R 26 Very toxic by inhalation.
R 35 Causes severe burns.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face pr
otection.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S 28A After contact with skin, wash immediately with plenty of water
.
WGK (Water Danger/Protection)
CAS# 56-18-8: 2
Canada - DSL/NDSL
CAS# 56-18-8 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of B3, E.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 56-18-8 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 6/25/1998
Revision #4 Date: 11/20/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.