Material Safety Data Sheet
2-(2-Ethoxyethoxy)ethyl acetate

ACC# 32492
Section 1 - Chemical Product and Company Identification
MSDS Name: 2-(2-Ethoxyethoxy)ethyl acetate
Catalog Numbers: AC257420000, AC257420010, AC257420025
Synonyms:
Carbitol acetate; Ethyldiglycolacetate.
Company Identification:

              Acros Organics N.V.
              One Reagent Lane
              Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
112-15-2 2-(2-Ethoxyethoxy)ethyl acetate 99 203-940-1

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: clear, colorless liquid.
Warning! Causes eye, skin, and respiratory tract irritation. May form explosive peroxides.
Target Organs: Kidneys, central nervous system, respiratory system, eyes, skin.


Potential Health Effects
Eye: Causes eye irritation.
Skin: Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion: May cause irritation of the digestive tract. May be harmful if swallowed. May cause central nervous system effects.
Inhalation: Causes respiratory tract irritation. May be harmful if inhaled.
Chronic: May cause kidney damage.

Section 4 - First Aid Measures


Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: Do not induce vomiting. Get medical aid.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Will burn if involved in a fire. May form explosive peroxides.
Extinguishing Media: Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Flash Point: 100 deg C ( 212.00 deg F)
Autoignition Temperature: 310 deg C ( 590.00 deg F)
Explosion Limits, Lower:1.50 vol %
Upper: Not available.
NFPA Rating: (estimated) Health: 2; Flammability: 1; Instability: 2

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Wear a self contained breathing apparatus and appropriate personal protection. (See Exposure Controls, Personal Protection section). Provide ventilation. Do not let this chemical enter the environment.

Section 7 - Handling and Storage


Handling: Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Container should be opened by a technically qualified person. Use only in a chemical fume hood. If peroxide formation is suspected, do not open or move container.
Storage: Store in a cool, dry place. Store in a tightly closed container. Containers should be dated when opened and tested periodically for the presence of peroxides. Should crystals form in a peroxidizable liquid, peroxidation may have occurred and the product should be considered extremely dangerous. In this instance, the container should only be opened remotely by professionals. May form explosive peroxides on prolonged storage.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use only under a chemical fume hood.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
2-(2-Ethoxyethoxy)ethyl acetate none listed none listed none listed

OSHA Vacated PELs: 2-(2-Ethoxyethoxy)ethyl acetate: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties


Physical State: Liquid
Appearance: clear, colorless
Odor: acetic odor
pH: Not available.
Vapor Pressure: 0.3 hPa @ 20 deg C
Vapor Density: 6.08
Evaporation Rate:Not available.
Viscosity: 2.8 MPA 20.00 deg C
Boiling Point: 210 - 220 deg C @ 760 mm Hg
Freezing/Melting Point:-25 deg C
Decomposition Temperature:Not available.
Solubility: Soluble.
Specific Gravity/Density:1.010
Molecular Formula:C8H16O4
Molecular Weight:176.20

Section 10 - Stability and Reactivity


Chemical Stability: May form explosive peroxides.
Conditions to Avoid: Incompatible materials, ignition sources, excess heat, prolonged exposure to air, direct sunlight..
Incompatibilities with Other Materials: Strong oxidizing agents, strong bases.
Hazardous Decomposition Products: Carbon monoxide, carbon dioxide, peroxides.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information


RTECS#:      
CAS# 112-15-2: KK8925000
LD50/LC50:
CAS# 112-15-2:
     Draize test, rabbit, eye: 500 mg Moderate;
     Oral, rabbit: LD50 = 4400 mg/kg;
     Oral, rat: LD50 = 11 gm/kg;
     Skin, rabbit: LD50 = 15100 uL/kg;
.

Carcinogenicity:
CAS# 112-15-2: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: No information found
Neurotoxicity: No information found
Other Studies:

Section 12 - Ecological Information


Ecotoxicity: No data available. No information available.
Environmental: No information available.
Physical: No information available.
Other: Do not empty into drains.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: Not regulated. Not regulated.
Hazard Class:
UN Number:
Packing Group:

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 112-15-2 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 112-15-2: reactive.
Section 313
     This material contains 2-(2-Ethoxyethoxy)ethyl acetate (listed as Glycol ethers), 99%, (CAS# 112-15-2) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
     CAS# 112-15-2 (listed as Glycol ethers (except for EGBE)) is listed as      a hazardous air pollutant (HAP).
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 112-15-2 can be found on the following state right to know lists: New Jersey, (listed as Glycol ethers), Pennsylvania, (listed as Glycol ethers).

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
     XI
Risk Phrases:

     R 19 May form explosive peroxides.
     R 36/37 Irritating to eyes and respiratory system.

Safety Phrases:

     S 26 In case of contact with eyes, rinse immediately with plenty of
     water and seek medical advice.
     S 39 Wear eye/face protection.

WGK (Water Danger/Protection)

     CAS# 112-15-2: 1
Canada - DSL/NDSL
     CAS# 112-15-2 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of D2B, F.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 112-15-2 is not listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 9/02/1997
Revision #8 Date: 8/01/2008

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.