Material Safety Data Sheet
4-Bromotoluene, 99%
ACC# 34636
Section 1 - Chemical Product and Company Identification |
MSDS Name: 4-Bromotoluene, 99%
Catalog Numbers:
AC107480000, AC107480050, AC107480500, AC107481000, AC107482500, AC107485000
AC107485000
Synonyms:
1-Bromo-4-methylbenzene; Benzene,1-bromo-4-methyl;
4-Bromo-1-methylbenzene; 4-methylbromobenzene; p-Methylphenyl
bromide; 4-Methyl-1-bromobenzene
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
106-38-7 |
4-Bromotoluene |
99.0 | 203-391-8 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: white crystals. Flash Point: 85 deg C.
Warning! Causes eye, skin, and respiratory tract
irritation. May be harmful if swallowed. May cause central nervous
system depression. The toxicological properties of this material
have not been fully investigated.
Target Organs: Central nervous system,
respiratory system, eyes, skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation.
Ingestion:
The toxicological properties of this substance have not been fully
investigated. May be harmful if swallowed. Causes gastrointestinal
tract irritation.
Inhalation:
Causes respiratory tract irritation. The toxicological properties of
this substance have not been fully investigated. May cause central
nervous system effects.
Chronic:
No information found.
Section 4 - First Aid Measures
|
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Vapors may
be heavier than air. They can spread along the ground and collect
in low or confined areas.
Extinguishing Media:
Use agent most appropriate to extinguish fire. Use water spray, dry
chemical, carbon dioxide, or appropriate foam.
Flash Point: 85 deg C ( 185.00 deg F)
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 2; Flammability: 2; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Clean up spills immediately, observing precautions in the Protective
Equipment section. Sweep up, then place into a suitable container for
disposal. Avoid generating dusty conditions. Provide ventilation.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Avoid ingestion and inhalation.
Storage:
Keep away from heat, sparks, and flame. Keep container closed when
not in use. Store in a tightly closed container. Store in a cool,
dry, well-ventilated area away from incompatible substances.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
4-Bromotoluene
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
4-Bromotoluene:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate gloves to prevent skin exposure.
Clothing:
Wear appropriate clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
Section 9 - Physical and Chemical Properties
|
Physical State: Crystals
Appearance: white
Odor: None reported.
pH: Not available.
Vapor Pressure: 1.15 mm Hg @deg C
Vapor Density: 5.9(Air =1)
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 184 deg C @ 760.00mmHg
Freezing/Melting Point:26.00 - 29.00 deg C
Decomposition Temperature:Not available.
Solubility: Soluble in ethanol, ether, and acetone
Specific Gravity/Density:1.3900g/cm3
Molecular Formula:C7H7Br
Molecular Weight:171.04
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation, strong oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, hydrogen bromide, bromine fumes.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 106-38-7:
XS7965600
LD50/LC50:
CAS# 106-38-7:
Inhalation, mouse:
LC50 = 2460 mg/m3;
Inhalation,
rat: LC50 = 6800 mg/m3;
Oral,
mouse: LD50 = 1860 mg/kg;
Oral,
rat: LD50 = 1540 mg/kg;
.
Carcinogenicity:
CAS# 106-38-7:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information available.
Teratogenicity:
No information available.
Reproductive Effects:
No information available.
Mutagenicity:
No information available.
Neurotoxicity:
No information available.
Other Studies:
Section 12 - Ecological Information
|
Ecotoxicity:
Bacteria: Phytobacterium phosphoreum: EC50 = 1.46-2.53 mg/L; 5,15,30
Minutes; Microtox test, 15 degrees C
No data available.
Environmental:
If released to water, 4-bromotoluene may be removed from the water
column by volatilization and adsorption. Using an estimated Henry's
Law constant of 2.3X10-3 atm-cu m/mol, volatilization half-lives of
4.3 hr and 5.3 days can be estimated for a model river and model
lake, respectively. The potential effect of adsorption to sediment is
considered in the half-life from an environmental pond which is
estimated to be 14.9 days.
Physical:
If released to the atmosphere, 4-bromotoluene is expected to degrade
by reaction with photochemically produced hydroxyl radicals; the
half-life for this reaction is estimated to be 9.8 days.
Other:
A BCF of 230 was estimated for 4-bromotoluene, using its log Kow of
3.42 and a recommended regression-derived equation. According to a
recommended classification scheme(3), this BCF value suggests that
bioconcentration in fish and aquatic organisms is moderately
high(SRC). [REF-13]
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
Not regulated as a hazardous material |
No information available. |
Hazard Class: |
|
|
UN Number: |
|
|
Packing Group: |
|
|
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 106-38-7 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 106-38-7 can be found on the
following state right to know lists: Pennsylvania, Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face protection.
WGK (Water Danger/Protection)
CAS# 106-38-7: No information available.
Canada - DSL/NDSL
CAS# 106-38-7 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D2B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
Section 16 - Additional Information
|
MSDS Creation Date: 5/05/1999
Revision #4 Date: 11/20/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.