Material Safety Data Sheet
Lead Tetrafluoride, 99%
ACC# 46500
Section 1 - Chemical Product and Company Identification |
MSDS Name: Lead Tetrafluoride, 99%
Catalog Numbers:
AC278570000, AC278575000
Synonyms:
PbF4; Lead Tetrafluoride.
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
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CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
7783-59-7 |
Lead Tetrafluoride |
99 | 232-012-9 |
Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: white crystals.
Danger! Long-term exposure may cause bone and
joint changes. Causes eye and skin irritation. May cause respiratory
and digestive tract irritation. Danger of cumulative effects.
Moisture sensitive. This product contains lead, a chemical known to
the state of California to cause developmental effects. This product
contains lead, a chemical known to the state of California to cause
cancer.
Target Organs: Central nervous system, none,
skeletal structures.
Potential Health Effects
Eye:
May cause eye irritation. May cause visual disturbances.
Skin:
Causes skin irritation.
Ingestion:
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. Inorganic fluorides can be harmful. Acute exposure to
fluorine compounds can lead to digestive tract burns, and abdominal
pain. Exposure to fluoride compounds can result in systemic toxic
effects on the heart, liver, and kidneys. It may also deplete
calcium levels in the body leading to hypocalcemia and death.
Fluoride can reduce calcium levels leading to fatal hypocalcemia.
Ingestion of lead compounds can cause toxic effects in the
blood-forming organs, kidneys and central nervous system. Symptoms of
lead poisoning or plumbism include weakness, weight loss, lassitude,
insomnia, and hypotension. It also includes constipation, anorexia,
abdominal discomfort and colic. Symptoms of lead poisoning include;
weakness, weight loss, lassitude, insomnia, and hypotension. Acute
lead poisoning can cause muscle weakness, "lead line" on the gums,
metallic taste, definite loss of appetite, insomnia, dizziness, high
lead levels in blood and urine with shock, coma and death in extreme
cases.
Inhalation:
May cause respiratory tract irritation. May cause effects similar to
those described for ingestion.
Chronic:
Chronic inhalation and ingestion may cause chronic fluoride
poisoning (fluorosis) characterized by weight loss, weakness,
anemia, brittle bones, and stiff joints. Effects may be delayed.
Chronic exposure to lead may result in plumbism which is
characterized by lead line in gum, headache, muscle weakness, mental
changes. Chronic exposure to fluoride compounds may cause systemic
toxicity. Chronic expsoure to lead may cause adverse effects on
human reproduction, embryonic and fetal development and postnatal
(e.g., mental) development.
Section 4 - First Aid Measures
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Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Use of chelators such as BAL penicillamine and N-acetylpenicillamine
should be considered.
Antidote:
There exists several chelation agents. The determination of there
use should be made only by qualified medical personnel.
Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion. Use water
spray to keep fire-exposed containers cool. Contact with metals may
evolve flammable hydrogen gas. Containers may explode when heated.
Non-combustible, substance itself does not burn but may decompose
upon heating to produce irritating, corrosive and/or toxic fumes.
Extinguishing Media:
Do NOT get water inside containers. For small fires, use dry
chemical, carbon dioxide, or water spray. For large fires, use dry
chemical, carbon dioxide, alcohol-resistant foam, or water spray.
Cool containers with flooding quantities of water until well after
fire is out.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 2; Flammability: 0; Instability: 0
Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid runoff into storm sewers and ditches which lead to
waterways. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
Section 7 - Handling and Storage
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Handling:
Wash thoroughly after handling. Wash thoroughly after handling. Use
only in a well-ventilated area. Minimize dust generation and
accumulation. Avoid contact with eyes, skin, and clothing. Keep
container tightly closed. Avoid ingestion and inhalation. Wash
clothing before reuse.
Storage:
Keep from contact with oxidizing materials. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep
containers tightly closed.
Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Use process enclosure, local exhaust ventilation, or other
engineering controls to control airborne levels below recommended
exposure limits. Facilities storing or utilizing this material should
be equipped with an eyewash facility and a safety shower.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Lead Tetrafluoride
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2.5 mg/m3 TWA (as F) (listed under Fluorides).
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0.050 mg/m3 TWA (as Pb) (listed under Lead compounds).2.5 mg/m3 TWA (inorganic solids, as F, listed under sodium fluoride) (listed under Fluorides, inorganic).100 mg/m3 IDLH (as Pb) (listed under L
ead compounds).
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2.5 mg/m3 TWA (as dust) (listed under Fluorides).2.5 mg/m3 TWA (as F) (listed under Fluorides).50 ęg/m3 TWA (as Pb) (listed under Lead, inorganic compounds).50 ęg/m3 TWA (as Pb); 30 ęg/m3 Action Le
vel (as Pb, Poison - see 29 CFR 1910.102 5) (listed under Lead, inorganic compounds).
|
OSHA Vacated PELs:
Lead Tetrafluoride:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
Section 9 - Physical and Chemical Properties
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Physical State: Crystals
Appearance: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:600 deg C
Decomposition Temperature:Not available.
Solubility: hydrolysis
Specific Gravity/Density:Not available.
Molecular Formula:F4Pb
Molecular Weight:283.19
Section 10 - Stability and Reactivity
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Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions.
Conditions to Avoid:
Incompatible materials, dust generation, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, acids, fluorine, hydrogen peroxides, calcium
carbide.
Hazardous Decomposition Products:
Hydrogen fluoride gas, lead/lead oxides.
Hazardous Polymerization: Has not been reported
Section 11 - Toxicological Information
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RTECS#:
CAS# 7783-59-7
unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
CAS# 7783-59-7:
- ACGIH:
A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans (listed as 'Lead, inorganic compounds').
- California:
carcinogen, initial date 10/1/92 (listed as Lead compounds).
- NTP:
Suspect carcinogen (listed as Lead compounds).
- IARC:
Group 2A carcinogen (listed as Lead, inorganic compounds).
Epidemiology:
Epidemiological studies have not shown a relationship
between lead exposure and the incidence of cancer in lead
workers. A study involving battery plant workers showed a
significant rise in the standardized mortatility ratio for
gastric and lung cancerIARC has concluded that the
evidence for carcinogenicity of lead to humans is
inadequate although there is sufficient evidence of
carcinogenicity of some lead salts to animals.Repeated
exposure to lead has caused many toxic effects including:
neurological changes, kidney damage, and blood
abnormalities.There are several reports that certain lead
compounds administered to animals in high doses are
carcinogenic, primarily producing renal tumors. Salts
demonstrating carcinogenitcity in animals are usually
soluble salts.IARC Group 2B: No data available on human
carcinogenicity, however sufficient evidence of
carcinogenicity in animals.
Teratogenicity:
No information found
Reproductive Effects:
Adverse reproductive effects have occurred in experimental
animals.
Mutagenicity:
No information found
Neurotoxicity:
Neurotoxic effects have occurred in humans.Neurotoxic
effects have occurred in experimental animals.
Other Studies:
Section 12 - Ecological Information
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No information available.
Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
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US DOT |
Canada TDG |
Shipping Name: |
DOT regulated - small quantity provisions apply (see 49CFR173.4) |
No information available. |
Hazard Class: |
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UN Number: |
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Packing Group: |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 7783-59-7 is not listed on the TSCA inventory.
It is for research and development use only.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
This material contains Lead
Tetrafluoride (listed as Lead, inorganic compounds), 99%, (CAS#
7783-59-7) which is subject to the reporting requirements of Section
313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
CAS# 7783-59-7 (listed as Lead compounds) is listed as a hazardous air
pollutant (HAP).
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
CAS# 7783-59-7 is listed as a Toxic Pollutant under the Clean Water
Act.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 7783-59-7 can be found on the
following state right to know lists: California, (listed as
Fluorides), California, (listed as Lead compounds), California,
(listed as Fluorides, inorganic), New Jersey, (listed as Lead
compounds), New Jersey, (listed as Fluorides), Pennsylvania, (listed
as Fluorides), Pennsylvania, (listed as Lead compounds), Minnesota,
(listed as Fluorides, inorganic), Minnesota, (listed as Fluorides),
Minnesota, (listed as Lead, inorganic compounds).
California Prop 65
The following statement(s) is(are) made in order to comply with
the California Safe Drinking Water Act:
WARNING: This product contains Lead Tetrafluoride, listed as `Lead
compounds', a chemical known to the state of California to cause
cancer.
WARNING: This product contains Lead Tetrafluoride, listed as `Lead,
inorganic compounds', a chemical known to the state of California to
cause developmental reproductive toxicity.
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
T
Risk Phrases:
R 20/22 Harmful by inhalation and if swallowed.
R 33 Danger of cumulative effects.
R 61 May cause harm to the unborn child.
R 62 Possible risk of impaired fertility.
Safety Phrases:
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S 53 Avoid exposure - obtain special instructions before use.
WGK (Water Danger/Protection)
CAS# 7783-59-7: No information available.
Canada - DSL/NDSL
None of the chemicals in this product are listed on the DSL or NDSL list.
Canada - WHMIS
This product has a WHMIS classification of D1B, D2B, D2A.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 7783-59-7 (listed as Fluorides, inorganic) is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
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MSDS Creation Date: 9/02/1997
Revision #5 Date: 11/20/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.