Material Safety Data Sheet
n-Propyl isocyanate, 99%
ACC# 46807
Section 1 - Chemical Product and Company Identification |
MSDS Name: n-Propyl isocyanate, 99%
Catalog Numbers:
AC131600000, AC131600050, AC131600250, AC131601000, AC131605000
Synonyms:
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
110-78-1 |
N-PROPYL ISOCYANATE |
| 203-803-6 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: clear yellow liquid. Flash Point: -1 deg C.
Moisture sensitive.
Target Organs: None known.
Potential Health Effects
Eye:
Causes eye irritation. Lachrymator (substance which increases the
flow of tears). Lachrymator (substance which increases the flow of
tears).
Skin:
Causes skin irritation.
Ingestion:
Harmful if swallowed. May cause headache. May cause nausea and
vomiting.
Inhalation:
May be fatal if inhaled. Causes respiratory tract irritation.
Inhalation may be fatal as a result of spasm, inflammation, edema of
the larynx and bronchi, chemical pneumonitis and pulmonary edema. May
cause an allergic response.
Chronic:
Not available.
Section 4 - First Aid Measures
|
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
Ingestion:
Get medical aid immediately. Wash mouth out with water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. Can burn in a fire, releasing toxic vapors. Will burn if
involved in a fire. Water reactive. Material will react with water
and may release a flammable and/or toxic gas. Wear appropriate
protective clothing to prevent contact with skin and eyes. Wear a
self-contained breathing apparatus (SCBA) to prevent contact with
thermal decomposition products. Flammable liquid and vapor.
Extinguishing Media:
Do NOT use alcohol foams. If water is the only media available, use
in flooding amounts. Use carbon dioxide or dry chemical.
Flash Point: -1 deg C ( 30.20 deg F)
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
Not published.
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool. Provide ventilation.
Section 7 - Handling and Storage
|
Handling:
Use only in a well-ventilated area. Use spark-proof tools and
explosion proof equipment. Do not breathe dust, mist, or vapor. Do
not get in eyes, on skin, or on clothing. Take precautionary measures
against static discharges. Do not allow contact with water. Use only
in a chemical fume hood.
Storage:
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Keep under a nitrogen blanket.
Flammables-area.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
N-PROPYL ISOCYANATE
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
N-PROPYL ISOCYANATE:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Liquid
Appearance: clear yellow
Odor: Pungent smell
pH: Not available.
Vapor Pressure: 69 mbar @ 20 deg C
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 83 - 84 deg C @ 760.00mm Hg
Freezing/Melting Point:<-30 deg C
Decomposition Temperature:Not available.
Solubility: reacts
Specific Gravity/Density:.9080g/cm3
Molecular Formula:C4H7NO
Molecular Weight:85.11
Section 10 - Stability and Reactivity
|
Chemical Stability:
Not available.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat, exposure to
moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents - strong bases - acids - alcohols - amines.
Hazardous Decomposition Products:
Hydrogen cyanide, nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: May occur.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 110-78-1:
NR0190000
LD50/LC50:
Not available.
Carcinogenicity:
CAS# 110-78-1:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No data available.
Teratogenicity:
No data available.
Reproductive Effects:
No data available.
Mutagenicity:
No data available.
Neurotoxicity:
No data available.
Other Studies:
Section 12 - Ecological Information
|
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
N-PROPYL ISOCYANATE |
N-PROPYL ISOCYANATE |
Hazard Class: |
6.1 |
6.1(3) |
UN Number: |
UN2482 |
UN2482 |
Packing Group: |
I |
I |
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 110-78-1 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 110-78-1 can be found on the
following state right to know lists: New Jersey.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
T+ F
Risk Phrases:
R 11 Highly flammable.
R 14 Reacts violently with water.
R 22 Harmful if swallowed.
R 26 Very toxic by inhalation.
R 36/37/38 Irritating to eyes, respiratory system and skin.
R 42 May cause sensitization by inhalation.
Safety Phrases:
S 16 Keep away from sources of ignition - No smoking.
S 24/25 Avoid contact with skin and eyes.
S 38 In case of insufficient ventilation, wear suitable respiratory
equipment.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
WGK (Water Danger/Protection)
CAS# 110-78-1: 1
Canada - DSL/NDSL
CAS# 110-78-1 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of B2, D1A, D2B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 110-78-1 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 9/02/1997
Revision #4 Date: 3/25/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.