Material Safety Data Sheet
n-Butyl vinyl ether, 98%
ACC# 50564
Section 1 - Chemical Product and Company Identification |
MSDS Name: n-Butyl vinyl ether, 98%
Catalog Numbers:
AC149700000, AC149700010, AC149700025, AC149700050, AC149700500, AC149705000
AC149705000
Synonyms:
1-(Ethenyloxy)butane; Butoxyethene; Butyl vinyl ether;
1-(Ethenyloxy)butane; Vinyl-n-butyl ether
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
111-34-2 |
n-Butyl vinyl ether |
98 | 203-860-7 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: colorless clear liquid. Flash Point: -9 deg C.
Danger! Extremely flammable liquid and vapor.
Vapor may cause flash fire. Causes eye and skin irritation. May
cause respiratory tract irritation. May form explosive peroxides.
Target Organs: Eyes, skin.
Potential Health Effects
Eye:
Causes mild eye irritation.
Skin:
Causes mild skin irritation.
Ingestion:
May cause irritation of the digestive tract. The toxicological
properties of this substance have not been fully investigated.
Inhalation:
May cause respiratory tract irritation. The toxicological properties
of this substance have not been fully investigated. Vapors may cause
dizziness or suffocation.
Chronic:
No information found.
Section 4 - First Aid Measures
|
Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Use water
spray to keep fire-exposed containers cool. Extremely flammable
liquid and vapor. Water may be ineffective. Material is lighter than
water and a fire may be spread by the use of water. Containers may
explode in the heat of a fire. May form explosive peroxides. Vapors
may be heavier than air. They can spread along the ground and
collect in low or confined areas. Will be easily ignited by heat,
sparks or flame.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. In case of fire, use water, dry chemical,
chemical foam, or alcohol-resistant foam. Use water spray to cool
fire-exposed containers. Water may be ineffective. Use agent most
appropriate to extinguish fire. For large fires, use water spray,
fog or alcohol-resistant foam. Do NOT use straight streams of water.
Flash Point: -9 deg C ( 15.80 deg F)
Autoignition Temperature: 225 deg C ( 437.00 deg F)
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 2; Flammability: 3; Instability: 2
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Remove all
sources of ignition. Use a spark-proof tool. A vapor suppressing foam
may be used to reduce vapors.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Ground and bond containers when
transferring material. Avoid contact with eyes, skin, and clothing.
Empty containers retain product residue, (liquid and/or vapor), and
can be dangerous. Take precautionary measures against static
discharges. Keep away from heat, sparks and flame. Avoid ingestion
and inhalation. Wash clothing before reuse. Do not pressurize, cut,
weld, braze, solder, drill, grind, or expose empty containers to
heat, sparks or open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area. Keep refrigerated. (Store below 4°C/39°F.)
Containers should be dated when opened and tested periodically for
the presence of peroxides. Should crystals form in a peroxidizable
liquid, peroxidation may have occurred and the product should be
considered extremely dangerous. In this instance, the container
should only be opened remotely by professionals. All peroxidizable
substances should be stored away from heat and light and be protected
from ignition sources.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
n-Butyl vinyl ether
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
n-Butyl vinyl ether:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate clothing to prevent skin exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
Section 9 - Physical and Chemical Properties
|
Physical State: Clear liquid
Appearance: colorless
Odor: None reported.
pH: Not available.
Vapor Pressure: 42 mm Hg @ 20 deg C
Vapor Density: 3.45
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 94 deg C @ 760 mm Hg
Freezing/Melting Point:-92 deg C
Decomposition Temperature:Not available.
Solubility: soluble in alcohol and ether
Specific Gravity/Density:.7740g/cm3
Molecular Formula:C6H12O
Molecular Weight:100.16
Section 10 - Stability and Reactivity
|
Chemical Stability:
Under normal storage conditions, peroxidizable compounds can form
and accumulate peroxides which may explode when subjected to heat or
shock. This material is most hazardous when peroxide levels are
concentrated by distillation or evaporation.
Conditions to Avoid:
Ignition sources, exposure to air, excess heat.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will occur.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 111-34-2:
KN5950000
LD50/LC50:
CAS# 111-34-2:
Inhalation, mouse:
LC50 = 62 gm/m3/2H;
Inhalation,
mouse: LC50 = 62000 mg/m3;
Oral,
rat: LD50 = 10 gm/kg;
Skin, rabbit:
LD50 = 4240 uL/kg;
.
Carcinogenicity:
CAS# 111-34-2:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information available.
Teratogenicity:
No information available.
Reproductive Effects:
No information available.
Mutagenicity:
No information available.
Neurotoxicity:
No information available.
Other Studies:
Section 12 - Ecological Information
|
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
BUTYL VINYL ETHER, STABILIZED |
No information available. |
Hazard Class: |
3 |
|
UN Number: |
UN2352 |
|
Packing Group: |
II |
|
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 111-34-2 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 111-34-2 can be found on the
following state right to know lists: New Jersey, Pennsylvania,
Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
F
Risk Phrases:
R 11 Highly flammable.
R 19 May form explosive peroxides.
Safety Phrases:
S 16 Keep away from sources of ignition - No smoking.
S 33 Take precautionary measures against static discharges.
S 9 Keep container in a well-ventilated place.
WGK (Water Danger/Protection)
CAS# 111-34-2: 1
Canada - DSL/NDSL
CAS# 111-34-2 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of B2.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
Section 16 - Additional Information
|
MSDS Creation Date: 10/14/1998
Revision #5 Date: 11/20/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.