Material Safety Data Sheet
Mercury(ii) thiocyanate, p.a.
ACC# 56241
Section 1 - Chemical Product and Company Identification |
MSDS Name: Mercury(ii) thiocyanate, p.a.
Catalog Numbers:
AC196890000, AC196890500, AC196892500
Synonyms:
None
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
592-85-8 |
Mercury(II) thiocyanate, p.a. |
100.0 | 209-773-0 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: white solid.
Warning! May be fatal if swallowed. May cause
severe eye irritation and possible injury. May cause severe skin
irritation. May be harmful if absorbed through the skin. May cause
severe respiratory and digestive tract irritation with possible
burns. Light sensitive. May cause liver and kidney damage. May cause
central nervous system effects. Moisture sensitive. May cause
reproductive and fetal effects.
Target Organs: Kidneys, liver, nervous system.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns. Causes redness and pain.
Skin:
May cause severe skin irritation. Harmful if absorbed through the
skin. Causes redness and pain.
Ingestion:
May be fatal if swallowed. May cause kidney damage. May cause liver
damage. May cause perforation of the digestive tract. May cause
vascular collapse and damage. Causes severe pain, nausea, vomiting,
diarrhea, and shock. May cause central nervous system effects.
Inhalation:
May cause irritation of the respiratory tract with burning pain in
the nose and throat, coughing, wheezing, shortness of breath and
pulmonary edema. May cause effects similar to those described for
ingestion.
Chronic:
May cause liver and kidney damage. May cause reproductive and fetal
effects. Repeated exposure may cause central nervous system damage.
May cause tremors, irritability, loss of memory and intellect. May
also cause Pink disease characterized by skin, cardiovascular, and
neurobehavioral abnormalities.
Section 4 - First Aid Measures
|
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
SPEED IS ESSENTIAL. A DOCTOR MUST BE NOTIFIED AT ONCE.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
Material will not burn.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
Not published.
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container.
Section 7 - Handling and Storage
|
Handling:
Do not get in eyes, on skin, or on clothing. Do not ingest or
inhale. Use only in a chemical fume hood.
Storage:
Store in a cool, dry place. Do not store in direct sunlight. Store
in a tightly closed container. Poison room locked.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use process enclosure,
local exhaust ventilation, or other engineering controls to control
airborne levels.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Mercury(II) thiocyanate, p.a.
|
0.025 mg/m3 TWA (as Hg) (listed under Mercury inorganic compounds).Skin - potential significant contribution to overall exposure by the cutaneous r oute (listed under Mercury inorganic compounds).
|
0.05 mg/m3 TWA (vapor, except organo alkyls, as Hg) (listed under Mercury compounds).10 mg/m3 IDLH (as Hg, except Organo(alkyl) compounds) (listed under Mercury compounds).
|
none listed
|
OSHA Vacated PELs:
Mercury(II) thiocyanate, p.a.:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Solid
Appearance: white
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:165 deg C dec
Decomposition Temperature:Not available.
Solubility: slightly soluble
Specific Gravity/Density:Not available.
Molecular Formula:C2HgN2S2
Molecular Weight:316.75
Section 10 - Stability and Reactivity
|
Chemical Stability:
Not available.
Conditions to Avoid:
Light, exposure to moist air or water.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Carbon monoxide, oxides of nitrogen, oxides of sulfur, carbon
dioxide, mercury/mercury oxides.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 592-85-8:
XL1550000
LD50/LC50:
CAS# 592-85-8:
Oral, mouse: LD50 =
24500 ug/kg;
Oral, rat: LD50 = 46
mg/kg;
Skin, rat: LD50 = 685
mg/kg;
.
Carcinogenicity:
CAS# 592-85-8:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information available.
Teratogenicity:
No information available.
Reproductive Effects:
No information available.
Mutagenicity:
No information available.
Neurotoxicity:
No information available.
Other Studies:
Section 12 - Ecological Information
|
Ecotoxicity:
No data available.
LC50 (24 hr) fathead minnow: 0.39 mg/l LC50 (48 hr) Daphnia magna:
9.3 ęg/l
Environmental:
No information available.
Physical:
No information available.
Other:
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
MERCURY THIOCYANATE |
MERCURY THIOCYANATE |
Hazard Class: |
6.1 |
6.1 |
UN Number: |
UN1646 |
UN1646 |
Packing Group: |
II |
II |
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 592-85-8 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 592-85-8: 10 lb final RQ; 4.54 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 592-85-8: immediate, delayed.
Section 313
This material contains Mercury(II)
thiocyanate, p.a. (listed as Mercury compounds), 100.0%, (CAS#
592-85-8) which is subject to the reporting requirements of Section
313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
CAS# 592-85-8 (listed as Mercury compounds) is listed as a hazardous a
ir pollutant (HAP).
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 592-85-8 is listed as a Hazardous Substance under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
CAS# 592-85-8 is listed as a Toxic Pollutant under the Clean Water
Act.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 592-85-8 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Massachusetts.
California Prop 65
WARNING: This product contains Mercury(II) thiocyanate, p.a., listed
as `Mercury compounds', a chemical known to the state of California
to cause developmental reproductive toxicity.
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
T+
Risk Phrases:
R 26/27/28 Very toxic by inhalation, in contact with skin and if
swallowed.
R 33 Danger of cumulative effects.
Safety Phrases:
S 13 Keep away from food, drink and animal feeding stuffs.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S 28A After contact with skin, wash immediately with plenty of water
.
WGK (Water Danger/Protection)
CAS# 592-85-8: 3
Canada - DSL/NDSL
CAS# 592-85-8 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D1A, D2A.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 592-85-8 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 9/02/1997
Revision #4 Date: 11/20/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.