Material Safety Data Sheet
p-Anisaldehyde, 99+%
ACC# 56472
Section 1 - Chemical Product and Company Identification |
MSDS Name: p-Anisaldehyde, 99+%
Catalog Numbers:
AC104800000, AC104800050, AC104801000, AC104805000
Synonyms:
4-Methoxybenzaldehyde; Anisic aldehyde; p-Methoxybenzaldehyde;
p-Formylanisole.
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
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CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
123-11-5 |
p-Anisaldehyde |
> 99 | 204-602-6 |
Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: colorless to slight yellow liquid.
Caution! May cause eye, skin, and respiratory
tract irritation. May be harmful if swallowed. Air sensitive.
Target Organs: Eyes, skin, mucous membranes.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. Prolonged or repeated contact may
dry/defat the skin and cause irritation.
Ingestion:
May cause irritation of the digestive tract. May be harmful if
swallowed.
Inhalation:
May cause respiratory tract irritation.
Chronic:
Laboratory experiments have resulted in mutagenic effects.
Organ weight and blood changes reported in 30 day oral rat study with
intermittent dosing at 55.2 mg/kg.
Section 4 - First Aid Measures
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Eyes:
In case of contact, immediately flush eyes with plenty of water for a
t least 15 minutes. Get medical aid.
Skin:
In case of contact, flush skin with plenty of water. Remove
contaminated clothing and shoes. Get medical aid if irritation
develops and persists. Wash clothing before reuse.
Ingestion:
If swallowed, do not induce vomiting unless directed to do so by
medical personnel. Never give anything by mouth to an unconscious
person. Get medical aid.
Inhalation:
If inhaled, remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use extinguishing media most appropriate for the surrounding fire.
Flash Point: 116 deg C ( 240.80 deg F)
Autoignition Temperature: 225 deg C ( 437.00 deg F)
Explosion Limits, Lower:1.4 vol %
Upper: 5.3 vol %
NFPA Rating:
(estimated) Health: 1; Flammability: 1; Instability: 0
Section 6 - Accidental Release Measures
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General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section.
Section 7 - Handling and Storage
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Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Avoid contact with
eyes, skin, and clothing. Avoid breathing vapor or mist.
Storage:
Do not store in direct sunlight. Keep container closed when not in
use. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Storage under
a nitrogen blanket has been recommended.
Section 8 - Exposure Controls, Personal Protection
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Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
p-Anisaldehyde
|
none listed
|
none listed
|
none listed
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OSHA Vacated PELs:
p-Anisaldehyde:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
Section 9 - Physical and Chemical Properties
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Physical State: Liquid
Appearance: colorless to slight yellow
Odor: sweetish odor
pH: Not available.
Vapor Pressure: 3.29E-002 mm Hg @ 25 deg C
Vapor Density: 4.7 (air=1)
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 248 - 249 deg C @ 760mmHg
Freezing/Melting Point:-1 deg C
Decomposition Temperature:> 160 deg C
Solubility: Insoluble.
Specific Gravity/Density:1.1190g/cm3
Molecular Formula:C8H8O2
Molecular Weight:136.15
Section 10 - Stability and Reactivity
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Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Prolonged exposure to air.
Incompatibilities with Other Materials:
Strong bases, strong oxidizing agents, strong reducing agents.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
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RTECS#:
CAS# 123-11-5:
BZ2625000
LD50/LC50:
CAS# 123-11-5:
Draize test,
rabbit, skin: 500 mg/24H Moderate;
Oral, mouse: LD50 = 1859 mg/kg;
Oral, mouse: LD50 = 1858.6 mg/kg;
Oral, rat: LD50 = 1510 mg/kg;
Oral, rat: LD50 = 1847.8 mg/kg;
Skin, rabbit: LD50 = >5 gm/kg;
.
Carcinogenicity:
CAS# 123-11-5:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information available.
Teratogenicity:
No information available.
Reproductive Effects:
No information available.
Mutagenicity:
Sister Chromatid Exchange: Human lymphocyte = 1 mmol/L.;
DNA damage: Mouse lymphocyte = 7020 umol/L.; Mutationin
Mammalian Sommatic Cells: Mouse lymphocyte = 3540 umol/L.
Neurotoxicity:
No information available.
Other Studies:
Section 12 - Ecological Information
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No information available.
Section 13 - Disposal Considerations
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Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
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US DOT |
Canada TDG |
Shipping Name: |
DOT regulated - small quantity provisions apply (see 49CFR173.4) |
No information available. |
Hazard Class: |
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UN Number: |
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Packing Group: |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 123-11-5 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 123-11-5: immediate, delayed.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 123-11-5 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XN
Risk Phrases:
R 22 Harmful if swallowed.
R 36/37/38 Irritating to eyes, respiratory system and skin.
Safety Phrases:
S 23 Do not inhale gas/fumes/vapour/spray.
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 123-11-5: 1
Canada - DSL/NDSL
CAS# 123-11-5 is listed on Canada's DSL List.
Canada - WHMIS
not available.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 123-11-5 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
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MSDS Creation Date: 2/10/1999
Revision #3 Date: 3/04/2004
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.