Material Safety Data Sheet
Butyl methacrylate, 99%, Stabilized with 25ppm Methylhydroquinone
ACC# 59652
Section 1 - Chemical Product and Company Identification |
MSDS Name: Butyl methacrylate, 99%, Stabilized with 25ppm Methylhydroquinone
Catalog Numbers:
AC216620000, AC216620010, AC216620050, AC216620051, AC216620500
Synonyms:
Methacrylic acid, butyl ester; Butyl 2-methacrylate; Butyl
2-methyl-2-propenoate; 2-Methyl-butylacrylate; 2-Propenoic acid,
2-methyl-, butyl ester
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
97-88-1 |
Butyl methacrylate |
99 | 202-615-1 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: clear, colorless liquid. Flash Point: 41 deg C.
Warning! Lachrymator (substance which increases
the flow of tears). Flammable liquid and vapor.
Causes eye, skin, and respiratory tract irritation. Light sensitive.
May cause reproductive and fetal effects.
Target Organs: Reproductive system.
Potential Health Effects
Eye:
Causes eye irritation. May cause conjunctivitis. Lachrymator
(substance which increases the flow of tears). Causes redness and
pain.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema. Vapors
may cause dizziness or suffocation. Causes irritation of the mucous
membrane and upper respiratory tract.
Chronic:
May cause reproductive and fetal effects.
Section 4 - First Aid Measures
|
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Immediately flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Wash clothing before reuse.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and
drink 2-4 cupfuls of milk or water.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. During a
fire, irritating and highly toxic gases may be generated by thermal
decomposition or combustion. Will burn if involved in a fire. Use
water spray to keep fire-exposed containers cool. Containers may
explode in the heat of a fire. Flammable liquid and vapor. Vapors
may be heavier than air. They can spread along the ground and
collect in low or confined areas. May polymerize explosively when
involved in a fire.
Extinguishing Media:
For small fires, use dry chemical, carbon dioxide, water spray or
alcohol-resistant foam. For large fires, use water spray, fog, or
alcohol-resistant foam. Use water spray to cool fire-exposed
containers. Water may be ineffective. Do NOT use straight streams of
water.
Flash Point: 41 deg C ( 105.80 deg F)
Autoignition Temperature: 290 deg C ( 554.00 deg F)
Explosion Limits, Lower:2.0 vol %
Upper: 8.0 vol %
NFPA Rating:
(estimated) Health: 2; Flammability: 2; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Clean up spills immediately,
observing precautions in the Protective Equipment section. Scoop up
with a nonsparking tool, then place into a suitable container for
disposal. Remove all sources of ignition. Provide ventilation. A
vapor suppressing foam may be used to reduce vapors.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Wash thoroughly after handling.
Remove contaminated clothing and wash before reuse. Ground and bond
containers when transferring material. Use spark-proof tools and
explosion proof equipment. Avoid contact with eyes, skin, and
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep away from heat, sparks and flame.
Use with adequate ventilation. Store protected from light. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames.
Storage:
Keep away from sources of ignition. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Refrigerator/flammables. Store protected from moisture. Do not
exceed 30°C (86°F). Store protected from light. Keep away from
oxidizing agents.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Butyl methacrylate
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
Butyl methacrylate:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
Section 9 - Physical and Chemical Properties
|
Physical State: Liquid
Appearance: clear, colorless
Odor: Ester odor.
pH: Not available.
Vapor Pressure: 4.9 mm Hg @ 20 C
Vapor Density: 4.8
Evaporation Rate:Not available.
Viscosity: 1.1 mPas @ 20 deg C
Boiling Point: 163 deg C
Freezing/Melting Point:-75 deg C
Decomposition Temperature:Not available.
Solubility: Slightly soluble.
Specific Gravity/Density:0.895
Molecular Formula:C8H14O2
Molecular Weight:142.0968
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable at room temperature in closed containers under normal storage
and handling conditions. Polymerization at low temperatures may
occur.
Conditions to Avoid:
High temperatures, mechanical shock, incompatible materials, light,
ignition sources, moisture, oxidizers, temperatures above 30°C, heat.
Incompatibilities with Other Materials:
Strong acids, strong bases, strong oxidizing agents, strong reducing
agents, moisture, heat.
Hazardous Decomposition Products:
Carbon monoxide, carbon monoxide, carbon dioxide.
Hazardous Polymerization: May occur.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 97-88-1:
OZ3675000
LD50/LC50:
CAS# 97-88-1:
Dermal, guinea pig:
LD50 = >20 mL/kg;
Draize test,
rabbit, skin: 500 uL Mild;
Inhalation, rat: LC50 = 4910
ppm/4H;
Oral, mouse: LD50 = 12900
mg/kg;
Oral, rabbit: LD50 = 25
gm/kg;
Oral, rat: LD50 = 16
gm/kg;
Skin, rabbit: LD50 = 11300
uL/kg;
.
Carcinogenicity:
CAS# 97-88-1:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
Experimental reproductive effects have been reported.
Teratogenicity:
Intraperitoneal, rat: TDLo = 690 mg/kg (female 5-15 day(s)
after conception) Effects on Embryo or Fetus -
fetotoxicity (except death, e.g., stunted fetus) and
Specific Developmental Abnormalities - other developmental
abnormalities.
Reproductive Effects:
Intraperitoneal, rat: TDLo = 2304 mg/kg (female 5-15 day(s)
after conception) Fertility - post-implantation mortality
(e.g. dead and/or resorbed implants per total number of
implants).
Mutagenicity:
No information available.
Neurotoxicity:
No information available.
Other Studies:
Section 12 - Ecological Information
|
Ecotoxicity:
Bacteria: Phytobacterium phosphoreum: EC50 = 37-55 mg/L; 5,15,30 min;
Microtox test at 15 C
No data available.
Environmental:
If released to water, Butyl methacrylate should evaporate into the
atmosphere with a volatilization half-life of approximately 13 hours
from a model river. In water, some Butyl methacrylate may also
partition to sediment. In soil, its Koc of about 878 suggests low
soil mobility. No data are available on other potential degradation
processes in soil or water. If released to the atmosphere, vapor
phase Butyl methacrylate is degraded relatively rapidly by reaction
with photochemically-produced hydroxyl radicals (estimated half-life
= 7.5 hours in air).
Physical:
No information available.
Other:
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
N-BUTYL METHACRYLATE, STABILIZED |
No information available. |
Hazard Class: |
3 |
|
UN Number: |
UN2227 |
|
Packing Group: |
III |
|
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 97-88-1 is listed on the TSCA inventory.
Health & Safety Reporting List
CAS# 97-88-1: Effective 4/13/89, Sunset 12/19/95
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 97-88-1 can be found on the
following state right to know lists: New Jersey, Pennsylvania,
Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XI
Risk Phrases:
R 10 Flammable.
R 36/37/38 Irritating to eyes, respiratory system and skin.
R 43 May cause sensitization by skin contact.
Safety Phrases:
S 16 Keep away from sources of ignition - No smoking.
S 33 Take precautionary measures against static discharges.
S 9 Keep container in a well-ventilated place.
WGK (Water Danger/Protection)
CAS# 97-88-1: 1
Canada - DSL/NDSL
CAS# 97-88-1 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of B2, D2A, F.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
Section 16 - Additional Information
|
MSDS Creation Date: 5/20/1999
Revision #4 Date: 11/20/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.