Material Safety Data Sheet
1,3-Dichloro-2-propanol, 99%

ACC# 65051
Section 1 - Chemical Product and Company Identification
MSDS Name: 1,3-Dichloro-2-propanol, 99%
Catalog Numbers: AC180180000, AC180180010, AC180180250, AC180182500
Synonyms:
alpha-Dichlorohydrin; sym-Dichloroisopropyl alcohol.
Company Identification:

              Acros Organics N.V.
              One Reagent Lane
              Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
96-23-1 1,3-Dichloro-2-propanol 99 202-491-9

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: clear yellow liquid. Flash Point: 85 deg C.
Warning! Causes eye, skin, and respiratory tract irritation. Harmful if swallowed or absorbed through the skin. Combustible liquid and vapor. May cause cancer based on animal studies.
Target Organs: Kidneys, liver, eyes.


Potential Health Effects
Eye: Causes eye irritation.
Skin: Causes mild skin irritation. Harmful if absorbed through the skin.
Ingestion: Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation: Causes respiratory tract irritation. May cause narcotic effects in high concentration. May cause liver damage.
Chronic: Animal studies indicate that the product may affect the liver and kidneys.

Section 4 - First Aid Measures


Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Combustible liquid and vapor. Vapors are heavier than air and may travel to a source of ignition and flash back. Vapors can spread along the ground and collect in low or confined areas.
Extinguishing Media: Use water fog, dry chemical, carbon dioxide or alcohol type foam.
Flash Point: 85 deg C ( 185.00 deg F)
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 3; Flammability: 2; Instability: 0

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition. Provide ventilation.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Use with adequate ventilation. Ground and bond containers when transferring material. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames. Keep away from heat and flame.
Storage: Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
1,3-Dichloro-2-propanol none listed none listed none listed

OSHA Vacated PELs: 1,3-Dichloro-2-propanol: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear chemical splash goggles.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties


Physical State: Liquid
Appearance: clear yellow
Odor: faint odor - chloroform-like
pH: Not available.
Vapor Pressure: 0.75 mm Hg @ 25 deg C
Vapor Density: 4.45 (air=1)
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 172-176 deg C @ 760 mm Hg
Freezing/Melting Point:-4 deg C
Decomposition Temperature:Not available.
Solubility: Slightly soluble.
Specific Gravity/Density:1.3510g/cm3
Molecular Formula:C3H6Cl2O
Molecular Weight:128.99

Section 10 - Stability and Reactivity


Chemical Stability: Unstable.
Conditions to Avoid: Ignition sources.
Incompatibilities with Other Materials: Strong oxidizing agents, strong reducing agents, strong acids, acid chlorides, acid anhydrides.
Hazardous Decomposition Products: Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information


RTECS#:      
CAS# 96-23-1: UB1400000
LD50/LC50:
CAS# 96-23-1:
     Oral, mouse: LD50 = 25 mg/kg;
     Oral, mouse: LD50 = 93 mg/kg;
     Oral, rat: LD50 = 81 mg/kg;
     Oral, rat: LD50 = 81 mg/kg;
     Skin, rabbit: LD50 = 800 uL/kg;
     Skin, rabbit: LD50 = 590 mg/kg;
.

Carcinogenicity:
CAS# 96-23-1: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: Two middle aged men developed severe hepatic injury just after cleaning a dichloropropanol tank at a plant producing dichloropropanol. They died from hepatic failure 4 and 11 days respectively, after carrying out the work.
Teratogenicity: No data available.
Reproductive Effects: No data available.
Mutagenicity: No data available.
Neurotoxicity: No data available.
Other Studies:

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: 1,3-DICHLOROPROPANOL-2 1,3-DICHLOROPROPANOL-2
Hazard Class: 6.1 6.1
UN Number: UN2750 UN2750
Packing Group: II II

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 96-23-1 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     CAS# 96-23-1: 40 CFR 799.5055
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 96-23-1 can be found on the following state right to know lists: New Jersey, Pennsylvania, Massachusetts.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
     T
Risk Phrases:

     R 21 Harmful in contact with skin.
     R 25 Toxic if swallowed.
     R 45 May cause cancer.

Safety Phrases:

     S 45 In case of accident or if you feel unwell, seek medical advice
     immediately (show the label where possible).
     S 53 Avoid exposure - obtain special instructions before use.

WGK (Water Danger/Protection)

     CAS# 96-23-1: 2
Canada - DSL/NDSL
     CAS# 96-23-1 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of B3, D1B.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 96-23-1 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 2/23/1998
Revision #5 Date: 11/20/2008

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.