Material Safety Data Sheet
1,3-Dichloro-2-propanol, 99%
ACC# 65051
Section 1 - Chemical Product and Company Identification |
MSDS Name: 1,3-Dichloro-2-propanol, 99%
Catalog Numbers:
AC180180000, AC180180010, AC180180250, AC180182500
Synonyms:
alpha-Dichlorohydrin; sym-Dichloroisopropyl alcohol.
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
96-23-1 |
1,3-Dichloro-2-propanol |
99 | 202-491-9 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: clear yellow liquid. Flash Point: 85 deg C.
Warning! Causes eye, skin, and respiratory tract
irritation. Harmful if swallowed or absorbed through the
skin. Combustible liquid and vapor.
May cause cancer based on animal studies.
Target Organs: Kidneys, liver, eyes.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes mild skin irritation. Harmful if absorbed through the skin.
Ingestion:
Harmful if swallowed. May cause gastrointestinal irritation with
nausea, vomiting and diarrhea.
Inhalation:
Causes respiratory tract irritation. May cause narcotic effects in
high concentration. May cause liver damage.
Chronic:
Animal studies indicate that the product may affect the liver and
kidneys.
Section 4 - First Aid Measures
|
Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Combustible liquid and vapor. Vapors are heavier
than air and may travel to a source of ignition and flash back.
Vapors can spread along the ground and collect in low or confined
areas.
Extinguishing Media:
Use water fog, dry chemical, carbon dioxide or alcohol type foam.
Flash Point: 85 deg C ( 185.00 deg F)
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 3; Flammability: 2; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Provide ventilation.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Use with adequate ventilation.
Ground and bond containers when transferring material. Avoid contact
with eyes, skin, and clothing. Empty containers retain product
residue, (liquid and/or vapor), and can be dangerous. Avoid ingestion
and inhalation. Do not pressurize, cut, weld, braze, solder, drill,
grind, or expose empty containers to heat, sparks or open flames.
Keep away from heat and flame.
Storage:
Keep away from sources of ignition. Store in a tightly closed
container. Store in a cool, dry, well-ventilated area away from
incompatible substances.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
1,3-Dichloro-2-propanol
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
1,3-Dichloro-2-propanol:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear chemical splash goggles.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Liquid
Appearance: clear yellow
Odor: faint odor - chloroform-like
pH: Not available.
Vapor Pressure: 0.75 mm Hg @ 25 deg C
Vapor Density: 4.45 (air=1)
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 172-176 deg C @ 760 mm Hg
Freezing/Melting Point:-4 deg C
Decomposition Temperature:Not available.
Solubility: Slightly soluble.
Specific Gravity/Density:1.3510g/cm3
Molecular Formula:C3H6Cl2O
Molecular Weight:128.99
Section 10 - Stability and Reactivity
|
Chemical Stability:
Unstable.
Conditions to Avoid:
Ignition sources.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong reducing agents, strong acids, acid
chlorides, acid anhydrides.
Hazardous Decomposition Products:
Hydrogen chloride, phosgene, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 96-23-1:
UB1400000
LD50/LC50:
CAS# 96-23-1:
Oral, mouse: LD50 =
25 mg/kg;
Oral, mouse: LD50 = 93
mg/kg;
Oral, rat: LD50 = 81
mg/kg;
Oral, rat: LD50 = 81
mg/kg;
Skin, rabbit: LD50 = 800
uL/kg;
Skin, rabbit: LD50 = 590
mg/kg;
.
Carcinogenicity:
CAS# 96-23-1:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
Two middle aged men developed severe hepatic injury just
after cleaning a dichloropropanol tank at a plant
producing dichloropropanol. They died from hepatic failure
4 and 11 days respectively, after carrying out the work.
Teratogenicity:
No data available.
Reproductive Effects:
No data available.
Mutagenicity:
No data available.
Neurotoxicity:
No data available.
Other Studies:
Section 12 - Ecological Information
|
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
1,3-DICHLOROPROPANOL-2 |
1,3-DICHLOROPROPANOL-2 |
Hazard Class: |
6.1 |
6.1 |
UN Number: |
UN2750 |
UN2750 |
Packing Group: |
II |
II |
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 96-23-1 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
CAS# 96-23-1: 40 CFR 799.5055
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 96-23-1 can be found on the
following state right to know lists: New Jersey, Pennsylvania,
Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
T
Risk Phrases:
R 21 Harmful in contact with skin.
R 25 Toxic if swallowed.
R 45 May cause cancer.
Safety Phrases:
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S 53 Avoid exposure - obtain special instructions before use.
WGK (Water Danger/Protection)
CAS# 96-23-1: 2
Canada - DSL/NDSL
CAS# 96-23-1 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of B3, D1B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 96-23-1 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 2/23/1998
Revision #5 Date: 11/20/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.