Material Safety Data Sheet
Platinum(II) chloride, 73% pt
ACC# 73587
Section 1 - Chemical Product and Company Identification |
MSDS Name: Platinum(II) chloride, 73% pt
Catalog Numbers:
AC195380010, AC195380050
Synonyms:
Platinous chloride
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
10025-65-7 |
Platinum (III) chloride |
73.0 | 233-034-1 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: yellow-green solid.
Caution! Causes respiratory tract irritation.
Causes skin irritation. May cause eye irritation. May cause
digestive tract irritation.
Target Organs: None known.
Potential Health Effects
Eye:
Causes eye irritation. In the eyes, the dusts cause a burning
sensation, tearing, and conjunctival hyperemia (an excess of blood
in a part), sometimes associated with photophobia.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Contact with the skin may cause urticaria (hives).
Ingestion:
May cause irritation of the digestive tract.
Inhalation:
Causes respiratory tract irritation. May cause asthmatic attacks due
to allergic sensitization of the respiratory tract. Causes irritation
of mucous membrane. Inhalation may produce tearing, sneezing,
rhinorrhea (the free discharge of a thin nasal mucus), cough, dyspnea
(labored breathing), bronchial asthma, and cyanosis (bluish
discoloration of skin due to deficient oxygenation of the blood).
Chronic:
Prolonged or repeated skin contact may cause dermatitis. Chronic
inhalation may cause effects similar to those of acute inhalation.
Section 4 - First Aid Measures
|
Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid immediately.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Substance is noncombustible.
Extinguishing Media:
Use agent most appropriate to extinguish fire.
Flash Point: 580 deg C ( 1,076.00 deg F)
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
Not published.
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up or absorb material, then place into a suitable clean, dry,
closed container for disposal. Avoid generating dusty conditions.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Use only in a well-ventilated area.
Minimize dust generation and accumulation. Avoid contact with eyes,
skin, and clothing. Keep container tightly closed. Avoid ingestion
and inhalation.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Platinum (III) chloride
|
0.002 mg/m3 TWA (as Pt) (listed under Platinum soluble salts).
|
0.002 mg/m3 TWA (as Pt) (listed under Platinum soluble salts).4 mg/m3 IDLH (as Pt) (listed under Platinum soluble salts).
|
0.002 mg/m3 TWA (as Pt) (listed under Platinum soluble salts).
|
OSHA Vacated PELs:
Platinum (III) chloride:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Solid
Appearance: yellow-green
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:581 deg C dec
Decomposition Temperature:580 deg C
Solubility: insoluble
Specific Gravity/Density:5.87
Molecular Formula:Cl2Pt
Molecular Weight:266.00
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, dust generation.
Incompatibilities with Other Materials:
Strong oxidizing agents
Hazardous Decomposition Products:
Hydrogen chloride.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 10025-65-7:
TP2275000
LD50/LC50:
CAS# 10025-65-7:
Draize test,
rabbit, skin: 100 mg/24H Mild;
Oral, rat: LD50 = 3423 mg/kg;
.
Carcinogenicity:
CAS# 10025-65-7:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No data available.
Teratogenicity:
No data available.
Reproductive Effects:
No data available.
Mutagenicity:
Mutation data reported
Neurotoxicity:
No data available.
Other Studies:
Section 12 - Ecological Information
|
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
DOT regulated - small quantity provisions apply (see 49CFR173.4) |
CORROSIVE SOLID NOS (PLATINUM CHLORIDE) |
Hazard Class: |
|
8 |
UN Number: |
|
UN1759 |
Packing Group: |
|
II |
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 10025-65-7 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 10025-65-7 can be found on the
following state right to know lists: California, (listed as Platinum
soluble salts), New Jersey, Pennsylvania, (listed as Platinum
soluble salts), Minnesota, (listed as Platinum soluble salts),
Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system and skin.
R 42/43 May cause sensitization by inhalation and skin contact.
Safety Phrases:
S 16 Keep away from sources of ignition - No smoking.
S 24 Avoid contact with skin.
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face protection.
WGK (Water Danger/Protection)
CAS# 10025-65-7: 1
Canada - DSL/NDSL
CAS# 10025-65-7 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of E.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 10025-65-7 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 9/02/1997
Revision #4 Date: 11/07/2006
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.