Material Safety Data Sheet
Potassium tetrachloroplatinate(II)

ACC# 82758
Section 1 - Chemical Product and Company Identification
MSDS Name: Potassium tetrachloroplatinate(II)
Catalog Numbers: AC195360000, AC195360010, AC195360050, AC195360250
Synonyms:
Platinous potassium chloride; Potassium chloroplatinite; Potassium platinochloride; Potassium platinum(II) tetrachloride; Potassium tetrachlorplatinate(II)
Company Identification:

              Acros Organics N.V.
              One Reagent Lane
              Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300

Section 2 - Composition, Information on Ingredients

CAS# Chemical Name Percent EINECS/ELINCS
10025-99-7 Potassium tetrachloroplatinate(II) 100.0 233-050-9

Section 3 - Hazards Identification

EMERGENCY OVERVIEW

Appearance: red-brown crystalline powder.
Warning! May cause allergic skin reaction. May cause severe eye and skin irritation with possible burns. Causes severe digestive tract irritation with pain, nausea, vomiting and diarrhea. May corrode the digestive tract with hemorrhaging and possible shock.
Target Organs: No data found.


Potential Health Effects
Eye: Contact with eyes may cause severe irritation, and possible eye burns. May cause sensitization.
Skin: May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material. May cause severe irritation and possible burns.
Ingestion: May cause severe gastrointestinal tract irritation with nausea, vomiting and possible burns.
Inhalation: May cause severe irritation of the respiratory tract with sore throat, coughing, shortness of breath and delayed lung edema. Causes chemical burns to the respiratory tract.
Chronic: Repeated or prolonged exposure may cause allergic reactions in sensitive individuals.

Section 4 - First Aid Measures


Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid imme diately.
Skin: Get medical aid immediately. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: Do not induce vomiting. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures


General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media: For small fires, use water spray, dry chemical, carbon dioxide or chemical foam.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: 3; Flammability: 0; Instability: 0

Section 6 - Accidental Release Measures


General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Sweep up, then place into a suitable container for disposal. Avoid generating dusty conditions. Provide ventilation.

Section 7 - Handling and Storage


Handling: Wash thoroughly after handling. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Do not ingest or inhale. Use only in a chemical fume hood.
Storage: Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - Exposure Controls, Personal Protection


Engineering Controls: Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits
Chemical Name ACGIH NIOSH OSHA - Final PELs
Potassium tetrachloroplatinate(II) 0.002 mg/m3 TWA (as Pt) (listed under Platinum soluble salts). 0.002 mg/m3 TWA (as Pt) (listed under Platinum soluble salts).4 mg/m3 IDLH (as Pt) (listed under Platinum soluble salts). 0.002 mg/m3 TWA (as Pt) (listed under Platinum soluble salts).

OSHA Vacated PELs: Potassium tetrachloroplatinate(II): No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves and clothing to prevent skin exposure.
Clothing: Wear appropriate protective clothing to minimize contact with skin.
Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use.

Section 9 - Physical and Chemical Properties


Physical State: Crystalline powder
Appearance: red-brown
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:dec. @ 250 deg C
Decomposition Temperature:250 deg C
Solubility: Soluble in water.
Specific Gravity/Density:3.499
Molecular Formula:Cl4PtK2
Molecular Weight:415.0886

Section 10 - Stability and Reactivity


Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials.
Incompatibilities with Other Materials: Strong oxidizing agents.
Hazardous Decomposition Products: Hydrogen chloride, oxides of potassium, chloride fumes.
Hazardous Polymerization: Has not been reported.

Section 11 - Toxicological Information


RTECS#:      
CAS# 10025-99-7: TP1850000
LD50/LC50:
Not available.
Oral, child: LDLo = 400 mg/kg. Oral, man: TDLo = 8571 ug/kg (Effects: gastritis, renal function tests depressed, white blood cell count changes). Intradermal, man: TDLo = 40 mg/kg (Effects: corrosive after topical exposure).
Carcinogenicity:
CAS# 10025-99-7: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information found
Teratogenicity: No information found
Reproductive Effects: No information found
Mutagenicity: Mutation in microorganisms: Salmonella typhimurim = 150 ug/plate.Micronucleus test: Human Lymphocyte = 150 umol/L.
Neurotoxicity: No information found
Other Studies:

Section 12 - Ecological Information


Ecotoxicity: No data available. No information available.
Environmental: No data available.
Physical: No data available.
Other: None.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

US DOT Canada TDG
Shipping Name: DOT regulated - small quantity provisions apply (see 49CFR173.4) CORROSIVE SOLID NOS (POTASSIUM TETRACHOLOPLA)
Hazard Class: 8
UN Number: UN1759
Packing Group: III

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 10025-99-7 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 10025-99-7 can be found on the following state right to know lists: California, (listed as Platinum soluble salts), Pennsylvania, (listed as Platinum soluble salts), Minnesota, (listed as Platinum soluble salts).

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations

European Labeling in Accordance with EC Directives
Hazard Symbols:
     XI
Risk Phrases:

     R 36/38 Irritating to eyes and skin.
     R 42/43 May cause sensitization by inhalation and skin contact.

Safety Phrases:

     S 22 Do not breathe dust.
     S 24/25 Avoid contact with skin and eyes.

WGK (Water Danger/Protection)

     CAS# 10025-99-7: 2
Canada - DSL/NDSL
     CAS# 10025-99-7 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of E.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 10025-99-7 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 9/02/1997
Revision #9 Date: 11/20/2008

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.