Material Safety Data Sheet
Potassium tetrachloroplatinate(II)
ACC# 82758
Section 1 - Chemical Product and Company Identification |
MSDS Name: Potassium tetrachloroplatinate(II)
Catalog Numbers:
AC195360000, AC195360010, AC195360050, AC195360250
Synonyms:
Platinous potassium chloride; Potassium chloroplatinite; Potassium
platinochloride; Potassium platinum(II) tetrachloride; Potassium
tetrachlorplatinate(II)
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
10025-99-7 |
Potassium tetrachloroplatinate(II) |
100.0 | 233-050-9 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: red-brown crystalline powder.
Warning! May cause allergic skin reaction. May
cause severe eye and skin irritation with possible burns. Causes
severe digestive tract irritation with pain, nausea, vomiting and
diarrhea. May corrode the digestive tract with hemorrhaging and
possible shock.
Target Organs: No data found.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns. May cause sensitization.
Skin:
May cause skin sensitization, an allergic reaction, which becomes
evident upon re-exposure to this material. May cause severe
irritation and possible burns.
Ingestion:
May cause severe gastrointestinal tract irritation with nausea,
vomiting and possible burns.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema. Causes
chemical burns to the respiratory tract.
Chronic:
Repeated or prolonged exposure may cause allergic reactions in
sensitive individuals.
Section 4 - First Aid Measures
|
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately.
Skin:
Get medical aid immediately. Flush skin with plenty of water for at
least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear.
Extinguishing Media:
For small fires, use water spray, dry chemical, carbon dioxide or
chemical foam.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 3; Flammability: 0; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Sweep up, then place into a suitable container for disposal. Avoid
generating dusty conditions. Provide ventilation.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Do
not get in eyes, on skin, or on clothing. Do not ingest or inhale.
Use only in a chemical fume hood.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Potassium tetrachloroplatinate(II)
|
0.002 mg/m3 TWA (as Pt) (listed under Platinum soluble salts).
|
0.002 mg/m3 TWA (as Pt) (listed under Platinum soluble salts).4 mg/m3 IDLH (as Pt) (listed under Platinum soluble salts).
|
0.002 mg/m3 TWA (as Pt) (listed under Platinum soluble salts).
|
OSHA Vacated PELs:
Potassium tetrachloroplatinate(II):
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to minimize
contact with skin.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
Section 9 - Physical and Chemical Properties
|
Physical State: Crystalline powder
Appearance: red-brown
Odor: None reported.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:dec. @ 250 deg C
Decomposition Temperature:250 deg C
Solubility: Soluble in water.
Specific Gravity/Density:3.499
Molecular Formula:Cl4PtK2
Molecular Weight:415.0886
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Hydrogen chloride, oxides of potassium, chloride fumes.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 10025-99-7:
TP1850000
LD50/LC50:
Not available.
Oral, child: LDLo = 400 mg/kg. Oral, man: TDLo = 8571 ug/kg
(Effects: gastritis, renal function tests depressed, white blood
cell count changes). Intradermal, man: TDLo = 40 mg/kg (Effects:
corrosive after topical exposure).
Carcinogenicity:
CAS# 10025-99-7:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information found
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
Mutation in microorganisms: Salmonella typhimurim = 150
ug/plate.Micronucleus test: Human Lymphocyte = 150 umol/L.
Neurotoxicity:
No information found
Other Studies:
Section 12 - Ecological Information
|
Ecotoxicity:
No data available.
No information available.
Environmental:
No data available.
Physical:
No data available.
Other:
None.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
DOT regulated - small quantity provisions apply (see 49CFR173.4) |
CORROSIVE SOLID NOS (POTASSIUM TETRACHOLOPLA) |
Hazard Class: |
|
8 |
UN Number: |
|
UN1759 |
Packing Group: |
|
III |
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 10025-99-7 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 10025-99-7 can be found on the
following state right to know lists: California, (listed as Platinum
soluble salts), Pennsylvania, (listed as Platinum soluble salts),
Minnesota, (listed as Platinum soluble salts).
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
XI
Risk Phrases:
R 36/38 Irritating to eyes and skin.
R 42/43 May cause sensitization by inhalation and skin contact.
Safety Phrases:
S 22 Do not breathe dust.
S 24/25 Avoid contact with skin and eyes.
WGK (Water Danger/Protection)
CAS# 10025-99-7: 2
Canada - DSL/NDSL
CAS# 10025-99-7 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of E.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 10025-99-7 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 9/02/1997
Revision #9 Date: 11/20/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.