Material Safety Data Sheet
N,N-Dimethylethanolamine, 99%
ACC# 85083
Section 1 - Chemical Product and Company Identification |
MSDS Name: N,N-Dimethylethanolamine, 99%
Catalog Numbers:
AC116180000, AC116180010, AC116180050, AC116180250, AC116182500, BP2628-1
Synonyms:
Deanol; 2-Dimethylaminoethanol.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
108-01-0 |
N,N-Dimethylethanolamine |
99 | 203-542-8 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: Clear. Flash Point: 40 deg C.
Danger! Causes eye and skin burns. Causes
digestive and respiratory tract burns. Flammable liquid and
vapor. May be harmful if swallowed, inhaled, or
absorbed through the skin. Hygroscopic (absorbs moisture from the
air).
Target Organs: Eyes, skin, mucous membranes.
Potential Health Effects
Eye:
Contact with eyes may cause severe irritation, and possible eye
burns. Lachrymator (substance which increases the flow of tears).
Skin:
May cause severe irritation and possible burns. May be harmful if
absorbed through the skin.
Ingestion:
May cause burns to the digestive tract. May be harmful if swallowed.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema.
Chronic:
Possible risk of harm to the unborn child.
Section 4 - First Aid Measures
|
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately. Do NOT allow victim to rub eyes or keep eyes closed. Extensiv
e irrigation with water is required (at least 30 minutes).
Skin:
Get medical aid. Flush skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash clothing
before reuse. Destroy contaminated shoes.
Ingestion:
Never give anything by mouth to an unconscious person. Get medical
aid immediately. Do NOT induce vomiting. If conscious and alert,
rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Containers
may explode in the heat of a fire. Flammable liquid and vapor. Vapors
may be heavier than air. They can spread along the ground and
collect in low or confined areas.
Extinguishing Media:
In case of fire, use water, dry chemical, chemical foam, or
alcohol-resistant foam. Do NOT get water inside containers. For
large fires, use water spray, fog or alcohol-resistant foam. Cool
containers with flooding quantities of water until well after fire
is out.
Flash Point: 40 deg C ( 104.00 deg F)
Autoignition Temperature: 235 deg C ( 455.00 deg F)
Explosion Limits, Lower:1.60 vol %
Upper: 11.90 vol %
NFPA Rating:
(estimated) Health: 3; Flammability: 2; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Do not flush into a sewer. Remove
all sources of ignition. Use a spark-proof tool. Provide
ventilation. Do not get water inside containers.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Ground and bond containers when transferring
material. Do not get in eyes, on skin, or on clothing. Empty
containers retain product residue, (liquid and/or vapor), and can be
dangerous. Keep container tightly closed. Do not ingest or inhale. Do
not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks or open flames. Use only with
adequate ventilation. Keep away from heat, sparks and flame.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Flammables-area. Store protected from light.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local exhaust ventilation to keep airborne concentrations below the
permissible exposure limits. Ventilation fans and other electrical
service must be non-sparking and have an explosion-proof design.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
N,N-Dimethylethanolamine
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
N,N-Dimethylethanolamine:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear chemical splash goggles and face shield.
Skin:
Wear appropriate protective gloves and clothing to
prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Wear a NIOSH/MSHA or European Standard EN 149
approved full-facepiece airline respirator in the
positive pressure mode with emergency escape
provisions.
Section 9 - Physical and Chemical Properties
|
Physical State: Liquid
Appearance: Clear
Odor: Amine-like
pH: Not available.
Vapor Pressure: 6.12 mbar @ 20
Vapor Density: 3.03
Evaporation Rate:Not available.
Viscosity: 3.8 MPA 20.00 deg C
Boiling Point: 139 deg C @ 760 mmHg
Freezing/Melting Point:-70 deg C
Decomposition Temperature:Not available.
Solubility: miscible with alcohol and ether
Specific Gravity/Density:.8870g/cm3
Molecular Formula:C4H11NO
Molecular Weight:89.14
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Ignition sources.
Incompatibilities with Other Materials:
Oxidizing agents - copper, copper alloys - zinc - acids - galvanized
iron.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide, nitrogen gas.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 108-01-0:
KK6125000
LD50/LC50:
CAS# 108-01-0:
Draize test,
rabbit, eye: 5 uL Severe;
Inhalation, mouse: LC50 = 3250
mg/m3;
Inhalation, rat: LC50 = 1641
ppm/4H;
Oral, rat: LD50 = 2
gm/kg;
Skin, rabbit: LD50 = 1370
uL/kg;
.
Carcinogenicity:
CAS# 108-01-0:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information available.
Teratogenicity:
No information available.
Reproductive Effects:
No information available.
Mutagenicity:
No information available.
Neurotoxicity:
No information available.
Other Studies:
Section 12 - Ecological Information
|
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
2-DIMETHYLAMINOETHANOL |
No information available. |
Hazard Class: |
8 |
|
UN Number: |
UN2051 |
|
Packing Group: |
II |
|
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 108-01-0 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 108-01-0: immediate, fire.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 108-01-0 can be found on the
following state right to know lists: New Jersey, Pennsylvania,
Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
C
Risk Phrases:
R 10 Flammable.
R 20/21/22 Harmful by inhalation, in contact with skin and if
swallowed.
R 34 Causes burns.
Safety Phrases:
S 25 Avoid contact with eyes.
S 26 In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face pr
otection.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
WGK (Water Danger/Protection)
CAS# 108-01-0: 1
Canada - DSL/NDSL
CAS# 108-01-0 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of B3, E.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
Section 16 - Additional Information
|
MSDS Creation Date: 6/29/1999
Revision #6 Date: 6/29/2007
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.