Section 2 - Composition, Information on Ingredients

CAS#	Chemical Name	Percent	EINECS/ELINCS
56-81-5	Glycerine	97.5	200-289-5
10025-69-1	Tin(II) chloride, dihydrate	2.5	unlisted

Section 3 - Hazards Identification

Appearance: clear, colorless liquid.
Warning! May cause severe eye irritation and possible injury. May cause skin irritation. Causes severe respiratory tract irritation. May cause liver damage.
Target Organs: Liver.


Potential Health Effects
Eye: May cause eye irritation and possible burns.
Skin: Contact with skin causes irritation and possible burns, especially if the skin is wet or moist.
Ingestion: May cause gastrointestinal irritation with nausea, vomiting and diarrhea. May cause burns to the digestive tract.
Inhalation: Irritation may lead to chemical pneumonitis and pulmonary edema. May cause severe irritation of the upper respiratory tract with pain, burns, and inflammation.
Chronic: Overexposure may cause delayed kidney injury.

Section 4 - First Aid Measures

Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid imme diately.
Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.
Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician: Treat symptomatically and supportively.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Combustion generates toxic fumes.
Extinguishing Media: Use extinguishing media most appropriate for the surrounding fire.
Flash Point: 193 deg C ( 379.40 deg F)
Autoignition Temperature: 400 deg C ( 752.00 deg F)
Explosion Limits, Lower:1.1
Upper: Not available.
NFPA Rating: (estimated) Health: 1; Flammability: 0; Instability: 0

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Provide ventilation.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Do not get in eyes, on skin, or on clothing. Keep container tightly closed. Do not ingest or inhale.
Storage: Store in a cool, dry, well-ventilated area away from incompatible substances. Keep containers tightly closed.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Use process enclosure, local exhaust ventilation, or other engineering controls to control airborne levels.
Exposure Limits

Chemical Name	ACGIH	NIOSH	OSHA - Final PELs
Glycerine	10 mg/m3 TWA	none listed	15 mg/m3 TWA (total); 5 mg/m3 TWA (respirable fraction)
Tin(II) chloride, dihydrate	2 mg/m3 TWA (as Sn, except Tin hydride) (listed under Tin inorganic compounds).	2 mg/m3 TWA (as Sn, except Tin oxide) (listed under Tin inorganic compounds).100 mg/m3 IDLH (as Sn, except Tin oxides) (listed under Tin inorganic compounds).	2 mg/m3 TWA (as Sn, except oxides) (listed under Tin inorganic compounds).

OSHA Vacated PELs: Glycerine: 10 mg/m3 TWA (total dust); 5 mg/m3 TWA (respirable fraction) Tin(II) chloride, dihydrate: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties

Physical State: Liquid
Appearance: clear, colorless
Odor: odorless
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Not available.
Specific Gravity/Density:Not available.
Molecular Formula:Mixture
Molecular Weight:Not available

Section 10 - Stability and Reactivity

Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: High temperatures, incompatible materials, moisture, exposure to air.
Incompatibilities with Other Materials: Hydrogen peroxide, potassium, sodium, strong bases, strong oxidizers, moisture, nitric acid, sulfuric acid, perchloric acid, lead oxide, alcohols, amines. Reacts vigourously with bromine trifluoride, calcium carbide, hydrazine hydrate, ethylene oxide, metal and organic nitrates.
Hazardous Decomposition Products: Hydrogen chloride, chlorine, tin/tin oxides.
Hazardous Polymerization: Has not been reported

Section 11 - Toxicological Information

RTECS#:      
CAS# 56-81-5: MA8050000      
CAS# 10025-69-1: XP8850000
LD50/LC50:
CAS# 56-81-5:
     Draize test, rabbit, eye: 126 mg Mild;
     Draize test, rabbit, eye: 500 mg/24H Mild;
     Draize test, rabbit, skin: 500 mg/24H Mild;
     Inhalation, rat: LC50 = >570 mg/m3/1H;
     Oral, mouse: LD50 = 4090 mg/kg;
     Oral, rabbit: LD50 = 27 gm/kg;
     Oral, rat: LD50 = 12600 mg/kg;
     Skin, rabbit: LD50 = >10 gm/kg;
.

CAS# 10025-69-1:
     Oral, rat: LD50 = 2274.6 mg/kg;
.

Carcinogenicity:
CAS# 56-81-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 10025-69-1: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No information available.
Teratogenicity: No information available.
Reproductive Effects: No information available.
Mutagenicity: Please refer to RTECS# XP8850000 for specific information.
Neurotoxicity: No information available.
Other Studies:

Section 12 - Ecological Information

Ecotoxicity: No data available. Cas# 56-81-5:LC50 (96 Hr.) rainbow trout = 50-67 mg/L; 12 degrees CLC50 (96 Hr.) goldfish = >5000 mg/L
Environmental: No information reported.
Physical: No information available.
Other: No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

	US DOT	Canada TDG
Shipping Name:	Not regulated as a hazardous material	No information available.
Hazard Class:
UN Number:
Packing Group:

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 56-81-5 is listed on the TSCA inventory.
     CAS# 10025-69-1 is not on the TSCA Inventory because it is a hydrate. It is considered to be listed if the CAS number for the anhydrous form is on the inventory (40CFR720.3(u)(2)).
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 56-81-5: delayed.
     CAS # 10025-69-1: immediate, delayed.
Section 313      No chemicals are reportable under Section 313.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 56-81-5 can be found on the following state right to know lists: Pennsylvania, Minnesota, Massachusetts.
     CAS# 10025-69-1 is not present on state lists from CA, PA, MN, MA, FL, or NJ.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
      Not available.
Risk Phrases:

Safety Phrases:

WGK (Water Danger/Protection)
     CAS# 56-81-5: 0
     CAS# 10025-69-1: No information available.
Canada - DSL/NDSL
     CAS# 56-81-5 is listed on Canada's DSL List.
Canada - WHMIS
     WHMIS: Not available.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 10025-69-1 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 7/20/1999
Revision #5 Date: 5/12/2008

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.