Material Safety Data Sheet
Iodine solution
ACC# 89222
Section 1 - Chemical Product and Company Identification |
MSDS Name: Iodine solution
Catalog Numbers:
BP2707-250, BP2707-60, BP2707-60A, BP2707-60C, BP2707250, BP270760,
BP2710-1G, BP2710-250, BP2710250, BP27104, 2300584, 2300585, 23281407B,
66770
Synonyms:
Mixture.
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
7732-18-5 |
Deionized water |
>85 | 231-791-2 |
25655-41-8 |
Poyl(vinylpyrrolidone)-iodine complex |
<13 | unlisted |
7681-11-0 |
Potassium iodide |
1.9 | 231-659-4 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: dark red-brown liquid.
Warning! Eye contact may result in permanent eye
damage. May cause allergic skin reaction. Causes eye and skin
irritation. Causes digestive and respiratory tract irritation. May
cause fetal effects based upon animal studies.
Target Organs: Thyroid.
Potential Health Effects
Eye:
Causes eye irritation and possible injury.
Skin:
Causes skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Ingestion:
Causes gastrointestinal irritation with nausea, vomiting and
diarrhea. Chronic ingestion of iodides during pregnancy has resulted
in fetal death, severe goiter, and cretinoid appearance of the
newborn.
Inhalation:
Causes respiratory tract irritation.
Chronic:
Chronic exposure can lead to iodism characterized by headache,
excess salivation, nasal discharge, conjunctivitis, laryngitis,
bronchitis, stomatitis, enlarged submaxillary glands, and skin
rashes. May interfere with iodine uptake of the thyroid gland and
enlarge it. Chronic ingestion of iodides during pregnancy has
resulted in fetal death, severe goiter, and cretinoid appearance of
the newborn. Prolonged exposure to iodides may produce iodism in
sensitive individuals. Symptoms could include skin rash, running
nose and headache.
Section 4 - First Aid Measures
|
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Wash clothing before reuse. Flush skin with plenty
of soap and water.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If breathing
is difficult, give oxygen. Get medical aid. Do NOT use mouth-to-mouth
resuscitation. If breathing has ceased apply artificial respiration
using oxygen and a suitable mechanical device such as a bag and a
mask.
Notes to Physician:
Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Non-combustible, substance itself does not burn but may decompose
upon heating to produce irritating, corrosive and/or toxic fumes.
Extinguishing Media:
Substance is noncombustible; use agent most appropriate to
extinguish surrounding fire.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 2; Flammability: 0; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Avoid runoff into storm sewers and
ditches which lead to waterways. Clean up spills immediately,
observing precautions in the Protective Equipment section. Provide
ventilation.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Avoid ingestion and
inhalation.
Storage:
Store in a cool, dry, well-ventilated area away from incompatible
substances.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Good general ventilation should be sufficient to control airborne
levels. Facilities storing or utilizing this material should be
equipped with an eyewash facility and a safety shower.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Deionized water
|
none listed
|
none listed
|
none listed
|
Poyl(vinylpyrrolidone)-iodine complex
|
none listed
|
none listed
|
none listed
|
Potassium iodide
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
Deionized water:
No OSHA Vacated PELs are listed for this chemical.
Poyl(vinylpyrrolidone)-iodine complex:
No OSHA Vacated PELs are listed for this chemical.
Potassium iodide:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Liquid
Appearance: dark red-brown
Odor: Iodine
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: >1.00
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 100 deg C
Freezing/Melting Point:> 0 deg C
Decomposition Temperature:Not available.
Solubility: Soluble in water.
Specific Gravity/Density:~1
Molecular Formula:Solution
Molecular Weight:Not available.
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, excess heat.
Incompatibilities with Other Materials:
Incompatabilities with potassium iodide include: salts of alkaloids,
chloral hydrate, calomel(mercurous chloride) potassium chlorate,
metallic salts, tartaric and other acids, bromine trifluoride, and
fluorine perchlorate, oxidizing agents. Incompatibilities with PVP
include oxidizing agents.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, oxides of potassium, iodine.
Hazardous Polymerization: Will not occur.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 7732-18-5:
ZC0110000
CAS# 25655-41-8:
TR1579600
CAS# 7681-11-0:
TT2975000
LD50/LC50:
CAS# 7732-18-5:
Oral, rat: LD50 =
>90 mL/kg;
.
CAS# 25655-41-8:
Draize test,
rabbit, skin: 500 mg Mild;
Oral,
mouse: LD50 = 8100 mg/kg;
Oral,
rat: LD50 = >8 gm/kg;
.
CAS# 7681-11-0:
.
Carcinogenicity:
CAS# 7732-18-5:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 25655-41-8:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7681-11-0:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
Experimental reproductive effects have been reported.
Teratogenicity:
Iodine salts can produce deformity, illness, and death of a
fetus. PVP(iodine complex) has been shown to present a
possible risk of harm to the unborn child.
Reproductive Effects:
PVP(iodine complex) has been shown to produce reproductive
effects when there is overexposure.
Mutagenicity:
No information found
Neurotoxicity:
No information found
Other Studies:
Section 12 - Ecological Information
|
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
Not regulated as a hazardous material |
No information available. |
Hazard Class: |
|
|
UN Number: |
|
|
Packing Group: |
|
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Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 25655-41-8 is listed on the TSCA inventory.
CAS# 7681-11-0 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 7681-11-0: immediate, delayed.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 7732-18-5 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 25655-41-8 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 7681-11-0 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
Not available.
Risk Phrases:
Safety Phrases:
WGK (Water Danger/Protection)
CAS# 7732-18-5: No information available.
CAS# 25655-41-8: 2
CAS# 7681-11-0: 1
Canada - DSL/NDSL
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 25655-41-8 is listed on Canada's DSL List.
CAS# 7681-11-0 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of D2B.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 7681-11-0 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 3/25/1998
Revision #8 Date: 6/01/2006
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.