Section 2 - Composition, Information on Ingredients

CAS#	Chemical Name	Percent	EINECS/ELINCS
79-06-1	Acrylamide	<.2	201-173-7
26628-22-8	Sodium Azide	.02	247-852-1
7732-18-5	Water	Balance	231-791-2

Section 3 - Hazards Identification

Appearance: Clear viscous liquid.
Caution! May cause eye, skin, and respiratory tract irritation. Potential cancer hazard.
Target Organs: None known.


Potential Health Effects
Eye: May cause eye irritation.
Skin: May cause skin irritation.
Ingestion: May cause irritation of the digestive tract.
Inhalation: May cause respiratory tract irritation.
Chronic: Chronic inhalation and ingestion may cause effects similar to those of acute inhalation and ingestion.

Section 4 - First Aid Measures

Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid immediately.
Inhalation: Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid if cough or other symptoms appear.
Notes to Physician: Treat symptomatically.

Section 5 - Fire Fighting Measures

General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media: Substance is noncombustible; use agent most appropriate to extinguish surrounding fire.
Flash Point: Not available.
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: Not published.

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Provide ventilation.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Avoid ingestion and inhalation. Store protected from light.
Storage: Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Use adequate ventilation to keep airborne concentrations low.
Exposure Limits

Chemical Name	ACGIH	NIOSH	OSHA - Final PELs
Acrylamide	0.03 mg/m3 TWA (inhalable fraction and vapor); Skin - potential significant contribution to overall exposure by the cutaneous r oute	0.03 mg/m3 TWA 60 mg/m3 IDLH	0.3 mg/m3 TWA
Sodium Azide	0.29 mg/m3 Ceiling (as NaN3); 0.11 ppm Ceiling (vapor, as hydrazoic acid)	none listed	none listed
Water	none listed	none listed	none listed

OSHA Vacated PELs: Acrylamide: 0.03 mg/m3 TWA Sodium Azide: No OSHA Vacated PELs are listed for this chemical. Water: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties

Physical State: Viscous liquid
Appearance: Clear
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: 100 deg C
Freezing/Melting Point:0 deg C
Decomposition Temperature:Not available.
Solubility: Soluble.
Specific Gravity/Density:Not available.
Molecular Formula:Not available.
Molecular Weight:Not available.

Section 10 - Stability and Reactivity

Chemical Stability: Stable.
Conditions to Avoid: Incompatible materials.
Incompatibilities with Other Materials: Sodium azide is incompatible with acids, ammonium chloride + trichloracetonitrile, barium carbonate, bromine, carbon disulfide, carbonyl dichloride (phosgene), cyanuric chloride, chromyl chloride, 2,5-dinitro-3-methylbenzoic acid + oleum, heavy metals, sulfuric acid, trifluoroacryloyl chloride. Polyacrylamide is incompatible with oxidizing and reducing agents, brass, aluminum
Hazardous Decomposition Products: Carbon monoxide, oxides of nitrogen, carbon dioxide, ammonia.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information

RTECS#:      
CAS# 79-06-1: AS3325000      
CAS# 26628-22-8: VY8050000      
CAS# 7732-18-5: ZC0110000
LD50/LC50:
CAS# 79-06-1:
     Draize test, rabbit, eye: 100 mg/24H Moderate;
     Draize test, rabbit, skin: 50 mg/3D Mild;
     Draize test, rabbit, skin: 500 mg/24H Mild;
     Oral, mouse: LD50 = 107 mg/kg;
     Oral, rabbit: LD50 = 150 mg/kg;
     Oral, rat: LD50 = 124 mg/kg;
     Skin, rabbit: LD50 = 1680 uL/kg;
     Skin, rat: LD50 = 400 mg/kg;
.

CAS# 26628-22-8:
     Inhalation, mouse: LC50 = 32400 ug/m3;
     Inhalation, rat: LC50 = 37 mg/m3;
     Oral, mouse: LD50 = 27 mg/kg;
     Oral, rat: LD50 = 27 mg/kg;
     Skin, rabbit: LD50 = 20 mg/kg;
     Skin, rat: LD50 = 50 mg/kg;
.

CAS# 7732-18-5:
     Oral, rat: LD50 = >90 mL/kg;
.

Carcinogenicity:
CAS# 79-06-1:

• ACGIH: A3 - Confirmed Animal Carcinogen with Unknown Relevance to Humans
  
• California: carcinogen, initial date 1/1/90
  
• NTP: Suspect carcinogen
  
• IARC: Group 2A carcinogen