Section 2 - Composition, Information on Ingredients

CAS#	Chemical Name	Percent	EINECS/ELINCS
10124-37-5	Calcium nitrate	66	233-332-1
7732-18-5	Water	33	231-791-2
7553-56-2	Iodine	<0.1	231-442-4
7681-11-0	Potassium iodide	<0.1	231-659-4

Section 3 - Hazards Identification

Appearance: Not available.
Danger! Strong oxidizer. Contact with other material may cause a fire. May cause skin sensitization by skin contact. May cause eye and skin irritation. May cause respiratory and digestive tract irritation. May cause methemoglobinemia.
Target Organs: Blood.


Potential Health Effects
Eye: May cause eye irritation.
Skin: May cause skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident upon re-exposure to this material.
Ingestion: May cause irritation of the digestive tract. Ingestion of nitrate containing compounds can lead to methemoglobinemia.
Inhalation: May cause respiratory tract irritation.
Chronic: No information found.

Section 4 - First Aid Measures

Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin: Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical aid if symptoms occur.
Ingestion: If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid.
Inhalation: Remove from exposure and move to fresh air immediately. Get medical aid if cough or other symptoms appear.
Notes to Physician: Treat symptomatically.

Section 5 - Fire Fighting Measures

General Information: Strong oxidizer. Contact with other material may cause fire. Containers may explode when heated.
Extinguishing Media: For small fires, do NOT use dry chemicals, carbon dioxide, halon or foams. USE WATER ONLY.
Flash Point: Not available
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating: (estimated) Health: ; Flammability: ; Instability:; Special Hazard: OX

Section 6 - Accidental Release Measures

General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Remove all sources of ignition.

Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Use with adequate ventilation. Avoid contact with eyes, skin, and clothing. Empty containers retain product residue, (liquid and/or vapor), and can be dangerous. Keep container tightly closed. Keep away from heat, sparks and flame. Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose empty containers to heat, sparks or open flames.
Storage: Keep away from heat, sparks, and flame. Keep away from sources of ignition. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.

Section 8 - Exposure Controls, Personal Protection

Engineering Controls: Use adequate general or local exhaust ventilation to keep airborne concentrations below the permissible exposure limits.
Exposure Limits

Chemical Name	ACGIH	NIOSH	OSHA - Final PELs
Calcium nitrate	none listed	none listed	none listed
Water	none listed	none listed	none listed
Iodine	0.1 ppm Ceiling	2 ppm IDLH	0.1 ppm Ceiling; 1 mg/m3 Ceiling
Potassium iodide	none listed	none listed	none listed

OSHA Vacated PELs: Calcium nitrate: No OSHA Vacated PELs are listed for this chemical. Water: No OSHA Vacated PELs are listed for this chemical. Iodine: No OSHA Vacated PELs are listed for this chemical. Potassium iodide: No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes: Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

Section 9 - Physical and Chemical Properties

Physical State: Liquid
Appearance: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Not available.
Specific Gravity/Density:1.012
Molecular Formula:Not available.
Molecular Weight:Not available.

Section 10 - Stability and Reactivity

Chemical Stability: Stable.
Conditions to Avoid: Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials: Acids (mineral, non-oxidizing, e.g. hydrochloric acid, hydrofluoric acid, muriatic acid, phosphoric acid), acids (organic, e.g. acetic acid, benzoic acid, formic acid, methanoic acid, oxalic acid), alcohols and glycols (e.g. butyl alcohol, ethanol, methanol, ethylene glycol), aldehydes (e.g. acetaldehyde, acrolein, chloral hydrate, formaldehyde), amides (e.g. butyramide, diethyltoluamide, dimethyl formamide), amines (aliphatic and aromatic, e.g. dimethyl amine, propylamine, pyridine, triethylamine), azo, diazo, and hydrazines (e.g. dimethyl hydrazine, hydrazine, methyl hydrazine), carbamates (e.g. carbanolate, carbofuran), cyanides (e.g. potassium cyanide, sodium cyanide), dithiocarbamates (e.g. ferbam, maneb, metham, thiram), esters (e.g. butyl acetate, ethyl acetate, propyl formate), ethers (e.g. dioxane, furfuran, tetrahydrofuran (THF)), hydrocarbons (aromatic, e.g. benzene, chrysene, cumene, toluene), halogenated organics (e.g. dibromoethane, hexachlorobenzene, methyl chloride, trichloroethylene), isocyanates (e.g. methyl isocyanate), ketones (e.g. acetone, acetophenone, MEK, MIBK), mercaptans and other organic sulfides (e.g. butyl mercaptan, carbon disulfide, methanethiol), metals (alkali and alkaline, e.g. cesium, potassium, sodium), metals as powders (e.g. hafnium, raney nickel), metals as non-powders (e.g. brass, bronze, iron), nitrides (e.g. potassium nitride, sodium nitride), nitriles (e.g. acetonitrile, methyl cyanide), nitro compounds (organic, e.g. nitrobenzene, nitroglycerine, picric acid, trinitrotoluene), hydrocarbons (aliphatic, unsaturated, e.g. cyclopentene, ethylene, heptene), hydrocarbons (aliphatic, saturated, e.g. butane, heptane, isooctane), peroxides and hydroperoxides (organic, e.g. acetyl peroxide, benzoyl peroxide, butyl peroxide, methyl ethyl ketone peroxide), phenols and cresols (e.g. carbolic acid, creosote, cresol, phenol, resorcinol), organophosphates, phosphothioates (e.g. methylparathion, parathion, phorate, thionazin), sulfides (i.
Hazardous Decomposition Products: Nitrogen oxides, iodine.
Hazardous Polymerization: Will not occur.

Section 11 - Toxicological Information

RTECS#:      
CAS# 10124-37-5: EW2985000      
CAS# 7732-18-5: ZC0110000      
CAS# 7553-56-2: NN1575000      
CAS# 7681-11-0: TT2975000
LD50/LC50:
CAS# 10124-37-5:
     Oral, rat: LD50 = 302 mg/kg;
.

CAS# 7732-18-5:
     Oral, rat: LD50 = >90 mL/kg;
.

CAS# 7553-56-2:
     Oral, mouse: LD50 = 22 gm/kg;
     Oral, mouse: LD50 = 1000 mg/kg;
     Oral, rabbit: LD50 = 10 gm/kg;
     Oral, rat: LD50 = 14 gm/kg;
.

CAS# 7681-11-0:
.

Carcinogenicity:
CAS# 10124-37-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7732-18-5: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7553-56-2: Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7681-11-0: Not listed by ACGIH, IARC, NTP, or CA Prop 65.

Epidemiology: No data available.
Teratogenicity: No data available.
Reproductive Effects: No data available.
Mutagenicity: No data available.
Neurotoxicity: No data available.
Other Studies:

Section 12 - Ecological Information

No information available.

Section 13 - Disposal Considerations

Chemical waste generators must determine whether a discarded chemical is classified as a hazardous waste. US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3. Additionally, waste generators must consult state and local hazardous waste regulations to ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.

Section 14 - Transport Information

	US DOT	Canada TDG
Shipping Name:	DOT regulated - small quantity provisions apply (see 49CFR173.4)	No information available.
Hazard Class:
UN Number:
Packing Group:

Section 15 - Regulatory Information

US FEDERAL

TSCA
     CAS# 10124-37-5 is listed on the TSCA inventory.
     CAS# 7732-18-5 is listed on the TSCA inventory.
     CAS# 7553-56-2 is listed on the TSCA inventory.
     CAS# 7681-11-0 is listed on the TSCA inventory.
Health & Safety Reporting List
     None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
     None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
     None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
     None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
     None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
     None of the chemicals in this product have a TPQ.
SARA Codes
     CAS # 10124-37-5: immediate, fire.
     CAS # 7553-56-2: immediate, delayed, fire.
     CAS # 7681-11-0: immediate, delayed.
Section 313
     This material contains Calcium nitrate (listed as Water Dissociable Nitrate Compounds), 66%, (CAS# 10124-37-5) which is subject to the reporting requirements of Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
     This material does not contain any hazardous air pollutants.
     This material does not contain any Class 1 Ozone depletors.
     This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
     None of the chemicals in this product are listed as Hazardous Substances under the CWA.
     None of the chemicals in this product are listed as Priority Pollutants under the CWA.
     None of the chemicals in this product are listed as Toxic Pollutants under the CWA.
OSHA:
     None of the chemicals in this product are considered highly hazardous by OSHA.
STATE
     CAS# 10124-37-5 can be found on the following state right to know lists: New Jersey.
     CAS# 7732-18-5 is not present on state lists from CA, PA, MN, MA, FL, or NJ.
     CAS# 7553-56-2 can be found on the following state right to know lists: California, New Jersey, Pennsylvania, Minnesota, Massachusetts.
     CAS# 7681-11-0 is not present on state lists from CA, PA, MN, MA, FL, or NJ.

California Prop 65

California No Significant Risk Level: None of the chemicals in this product are listed.

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
     O
Risk Phrases:
     R 8 Contact with combustible material may cause fire.

Safety Phrases:
     S 17 Keep away from combustible material.
     S 24/25 Avoid contact with skin and eyes.
     S 45 In case of accident or if you feel unwell, seek medical advice
     immediately (show the label where possible).

WGK (Water Danger/Protection)
     CAS# 10124-37-5: 1
     CAS# 7732-18-5: No information available.
     CAS# 7553-56-2: 1
     CAS# 7681-11-0: 1
Canada - DSL/NDSL
     CAS# 10124-37-5 is listed on Canada's DSL List.
     CAS# 7732-18-5 is listed on Canada's DSL List.
     CAS# 7553-56-2 is listed on Canada's DSL List.
     CAS# 7681-11-0 is listed on Canada's DSL List.
Canada - WHMIS
     This product has a WHMIS classification of C.
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
     CAS# 10124-37-5 is not listed on the Canadian Ingredient Disclosure List.
     CAS# 7553-56-2 is listed on the Canadian Ingredient Disclosure List.
     CAS# 7681-11-0 is listed on the Canadian Ingredient Disclosure List.

Section 16 - Additional Information

MSDS Creation Date: 2/05/1998
Revision #4 Date: 10/03/2005

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall Fisher be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Fisher has been advised of the possibility of such damages.