Material Safety Data Sheet
Selleger's Stain
ACC# 89821
Section 1 - Chemical Product and Company Identification |
MSDS Name: Selleger's Stain
Catalog Numbers:
S79808
Synonyms:
Company Identification:
Fisher Scientific
1 Reagent Lane
Fair Lawn, NJ 07410
For information, call: 201-796-7100
Emergency Number: 201-796-7100
For CHEMTREC assistance, call: 800-424-9300
For International CHEMTREC assistance, call: 703-527-3887
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
10124-37-5 |
Calcium nitrate |
66 | 233-332-1 |
7732-18-5 |
Water |
33 | 231-791-2 |
7553-56-2 |
Iodine |
<0.1 | 231-442-4 |
7681-11-0 |
Potassium iodide |
<0.1 | 231-659-4 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: Not available.
Danger! Strong oxidizer. Contact with other
material may cause a fire. May cause skin sensitization by skin
contact. May cause eye and skin irritation. May cause respiratory
and digestive tract irritation. May cause methemoglobinemia.
Target Organs: Blood.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May cause skin sensitization, an allergic
reaction, which becomes evident upon re-exposure to this material.
Ingestion:
May cause irritation of the digestive tract. Ingestion of nitrate
containing compounds can lead to methemoglobinemia.
Inhalation:
May cause respiratory tract irritation.
Chronic:
No information found.
Section 4 - First Aid Measures
|
Eyes:
Flush eyes with plenty of water for at least 15 minutes, occasionally
lifting the upper and lower eyelids. Get medical aid.
Skin:
Flush skin with plenty of water for at least 15 minutes while
removing contaminated clothing and shoes. Get medical aid if
symptoms occur.
Ingestion:
If victim is conscious and alert, give 2-4 cupfuls of milk or water.
Never give anything by mouth to an unconscious person. Get medical
aid.
Inhalation:
Remove from exposure and move to fresh air immediately. Get medical
aid if cough or other symptoms appear.
Notes to Physician:
Treat symptomatically.
Section 5 - Fire Fighting Measures
|
General Information:
Strong oxidizer. Contact with other material may cause fire.
Containers may explode when heated.
Extinguishing Media:
For small fires, do NOT use dry chemicals, carbon dioxide, halon or
foams. USE WATER ONLY.
Flash Point: Not available
Autoignition Temperature: Not available.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: ; Flammability: ; Instability:; Special Hazard: OX
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Use with adequate ventilation. Avoid
contact with eyes, skin, and clothing. Empty containers retain
product residue, (liquid and/or vapor), and can be dangerous. Keep
container tightly closed. Keep away from heat, sparks and flame.
Avoid ingestion and inhalation. Do not pressurize, cut, weld, braze,
solder, drill, grind, or expose empty containers to heat, sparks or
open flames.
Storage:
Keep away from heat, sparks, and flame. Keep away from sources of
ignition. Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Use adequate general or local exhaust ventilation to keep airborne
concentrations below the permissible exposure limits.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Calcium nitrate
|
none listed
|
none listed
|
none listed
|
Water
|
none listed
|
none listed
|
none listed
|
Iodine
|
0.1 ppm Ceiling
|
2 ppm IDLH
|
0.1 ppm Ceiling; 1 mg/m3 Ceiling
|
Potassium iodide
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
Calcium nitrate:
No OSHA Vacated PELs are listed for this chemical.
Water:
No OSHA Vacated PELs are listed for this chemical.
Iodine:
No OSHA Vacated PELs are listed for this chemical.
Potassium iodide:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Liquid
Appearance: Not available.
Odor: Not available.
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:Not available.
Decomposition Temperature:Not available.
Solubility: Not available.
Specific Gravity/Density:1.012
Molecular Formula:Not available.
Molecular Weight:Not available.
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials, ignition sources, excess heat.
Incompatibilities with Other Materials:
Acids (mineral, non-oxidizing, e.g. hydrochloric acid, hydrofluoric
acid, muriatic acid, phosphoric acid), acids (organic, e.g. acetic
acid, benzoic acid, formic acid, methanoic acid, oxalic acid),
alcohols and glycols (e.g. butyl alcohol, ethanol, methanol, ethylene
glycol), aldehydes (e.g. acetaldehyde, acrolein, chloral hydrate,
formaldehyde), amides (e.g. butyramide, diethyltoluamide, dimethyl
formamide), amines (aliphatic and aromatic, e.g. dimethyl amine,
propylamine, pyridine, triethylamine), azo, diazo, and hydrazines
(e.g. dimethyl hydrazine, hydrazine, methyl hydrazine), carbamates
(e.g. carbanolate, carbofuran), cyanides (e.g. potassium cyanide,
sodium cyanide), dithiocarbamates (e.g. ferbam, maneb, metham,
thiram), esters (e.g. butyl acetate, ethyl acetate, propyl formate),
ethers (e.g. dioxane, furfuran, tetrahydrofuran (THF)), hydrocarbons
(aromatic, e.g. benzene, chrysene, cumene, toluene), halogenated
organics (e.g. dibromoethane, hexachlorobenzene, methyl chloride,
trichloroethylene), isocyanates (e.g. methyl isocyanate), ketones
(e.g. acetone, acetophenone, MEK, MIBK), mercaptans and other
organic sulfides (e.g. butyl mercaptan, carbon disulfide,
methanethiol), metals (alkali and alkaline, e.g. cesium, potassium,
sodium), metals as powders (e.g. hafnium, raney nickel), metals as
non-powders (e.g. brass, bronze, iron), nitrides (e.g. potassium
nitride, sodium nitride), nitriles (e.g. acetonitrile, methyl
cyanide), nitro compounds (organic, e.g. nitrobenzene,
nitroglycerine, picric acid, trinitrotoluene), hydrocarbons
(aliphatic, unsaturated, e.g. cyclopentene, ethylene, heptene),
hydrocarbons (aliphatic, saturated, e.g. butane, heptane, isooctane),
peroxides and hydroperoxides (organic, e.g. acetyl peroxide, benzoyl
peroxide, butyl peroxide, methyl ethyl ketone peroxide), phenols and
cresols (e.g. carbolic acid, creosote, cresol, phenol, resorcinol),
organophosphates, phosphothioates (e.g. methylparathion, parathion,
phorate, thionazin), sulfides (i.
Hazardous Decomposition Products:
Nitrogen oxides, iodine.
Hazardous Polymerization: Will not occur.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 10124-37-5:
EW2985000
CAS# 7732-18-5:
ZC0110000
CAS# 7553-56-2:
NN1575000
CAS# 7681-11-0:
TT2975000
LD50/LC50:
CAS# 10124-37-5:
Oral, rat: LD50 =
302 mg/kg;
.
CAS# 7732-18-5:
Oral, rat:
LD50 = >90 mL/kg;
.
CAS# 7553-56-2:
Oral, mouse:
LD50 = 22 gm/kg;
Oral, mouse: LD50
= 1000 mg/kg;
Oral, rabbit: LD50 =
10 gm/kg;
Oral, rat: LD50 = 14
gm/kg;
.
CAS# 7681-11-0:
.
Carcinogenicity:
CAS# 10124-37-5:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7732-18-5:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7553-56-2:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
CAS# 7681-11-0:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No data available.
Teratogenicity:
No data available.
Reproductive Effects:
No data available.
Mutagenicity:
No data available.
Neurotoxicity:
No data available.
Other Studies:
Section 12 - Ecological Information
|
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
DOT regulated - small quantity provisions apply (see 49CFR173.4) |
No information available. |
Hazard Class: |
|
|
UN Number: |
|
|
Packing Group: |
|
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Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 10124-37-5 is listed on the TSCA inventory.
CAS# 7732-18-5 is listed on the TSCA inventory.
CAS# 7553-56-2 is listed on the TSCA inventory.
CAS# 7681-11-0 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 10124-37-5: immediate, fire.
CAS # 7553-56-2: immediate, delayed, fire.
CAS # 7681-11-0: immediate, delayed.
Section 313
This material contains Calcium
nitrate (listed as Water Dissociable Nitrate Compounds), 66%, (CAS#
10124-37-5) which is subject to the reporting requirements of
Section 313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 10124-37-5 can be found on the
following state right to know lists: New Jersey.
CAS# 7732-18-5 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
CAS# 7553-56-2 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Minnesota, Massachusetts.
CAS# 7681-11-0 is not present on
state lists from CA, PA, MN, MA, FL, or NJ.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
O
Risk Phrases:
R 8 Contact with combustible material may cause fire.
Safety Phrases:
S 17 Keep away from combustible material.
S 24/25 Avoid contact with skin and eyes.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
WGK (Water Danger/Protection)
CAS# 10124-37-5: 1
CAS# 7732-18-5: No information available.
CAS# 7553-56-2: 1
CAS# 7681-11-0: 1
Canada - DSL/NDSL
CAS# 10124-37-5 is listed on Canada's DSL List.
CAS# 7732-18-5 is listed on Canada's DSL List.
CAS# 7553-56-2 is listed on Canada's DSL List.
CAS# 7681-11-0 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of C.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 10124-37-5 is not listed on the Canadian Ingredient Disclosure List.
CAS# 7553-56-2 is listed on the Canadian Ingredient Disclosure List.
CAS# 7681-11-0 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 2/05/1998
Revision #4 Date: 10/03/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.