Material Safety Data Sheet
Sodium Metal
ACC# 92022
Section 1 - Chemical Product and Company Identification |
MSDS Name: Sodium Metal
Catalog Numbers:
AC611144540
Synonyms:
Natrium.
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
7440-23-5 |
Sodium |
100 | 231-132-9 |
Section 3 - Hazards Identification
|
EMERGENCY OVERVIEW
Appearance: light silver solid.
Danger! May ignite spontaneously on exposure to
moist air. Combustible solid. Causes eye burns. Causes digestive
tract burns. Corrosive. Water-reactive. Contact with skin causes
irritation and possible burns, especially if the skin is wet or
moist. Causes respiratory tract burns.
Target Organs: Eyes, skin, mucous membranes.
Potential Health Effects
Eye:
May cause irreversible eye injury. Contact with eyes may cause
severe irritation, and possible eye burns.
Skin:
Causes skin burns. May cause deep, penetrating ulcers of the skin.
Ingestion:
Causes gastrointestinal tract burns.
Inhalation:
May cause severe irritation of the respiratory tract with sore
throat, coughing, shortness of breath and delayed lung edema.
Chronic:
Chronic inhalation and ingestion may cause effects similar to those
of acute inhalation and ingestion.
Section 4 - First Aid Measures
|
Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid imme
diately.
Skin:
Immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Get medical aid if
irritation develops or persists.
Ingestion:
Do not induce vomiting. If victim is conscious and alert, give 2-4
cupfuls of milk or water. Never give anything by mouth to an
unconscious person. Get medical aid immediately.
Inhalation:
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively
Section 5 - Fire Fighting Measures
|
General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Reacts violently with water giving off flammable
gas which may explode. During a fire, irritating and highly toxic
gases may be generated by thermal decomposition or combustion.
Flammable solid. May react violently or explosively on contact with
water. May be ignited by heat, sparks, and flame. May re-ignite after
fire is extinguished.
Extinguishing Media:
DO NOT USE WATER! Do NOT use CO2 or halogenated extinguishing
agents. Smother with dry sand, dry clay, dry ground limestone
(CaCO3), or use approved Class D extinguishers.
Flash Point: Not applicable.
Autoignition Temperature: 250 deg F ( 121.11 deg C)
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 3; Flammability: 3; Instability: 2; Special Hazard: -W-
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Avoid generating dusty conditions. Remove all sources of
ignition. Provide ventilation. Do not expose spill to water.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Do not get in eyes, on skin, or on
clothing. Empty containers retain product residue, (liquid and/or
vapor), and can be dangerous. Keep container tightly closed. Keep
away from heat, sparks and flame. Do not ingest or inhale. Do not
pressurize, cut, weld, braze, solder, drill, grind, or expose empty
containers to heat, sparks or open flames.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Keep away
from water.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Sodium
|
none listed
|
none listed
|
none listed
|
OSHA Vacated PELs:
Sodium:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
|
Physical State: Solid
Appearance: light silver
Odor: odorless
pH: Not applicable.
Vapor Pressure: 1 mm Hg @ 440 deg C
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: 0.680cp @ 100C
Boiling Point: 1621 deg F
Freezing/Melting Point:208 deg F
Decomposition Temperature:Not available.
Solubility: Reacts violently with water
Specific Gravity/Density:0.9684 @ 20 C
Molecular Formula:Na
Molecular Weight:22.99
Section 10 - Stability and Reactivity
|
Chemical Stability:
Reacts violently with water. Reacts violently with a broad range of
materials.
Conditions to Avoid:
Dust generation, exposure to moist air or water.
Incompatibilities with Other Materials:
Water, strong oxidizing agents, strong acids, halogens, chloroform,
sulfur dioxide.
Hazardous Decomposition Products:
Irritating and toxic fumes and gases, sodium oxide.
Hazardous Polymerization: Has not been reported.
Section 11 - Toxicological Information
|
RTECS#:
CAS# 7440-23-5:
VY0686000
LD50/LC50:
Not available.
Carcinogenicity:
CAS# 7440-23-5:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information available.
Teratogenicity:
No information available.
Reproductive Effects:
No information available.
Mutagenicity:
No information avialable.
Neurotoxicity:
No information available.
Other Studies:
Section 12 - Ecological Information
|
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
|
|
US DOT |
Canada TDG |
Shipping Name: |
SODIUM |
No information available. |
Hazard Class: |
4.3 |
|
UN Number: |
UN1428 |
|
Packing Group: |
I |
|
Section 15 - Regulatory Information
|
US FEDERAL
TSCA
CAS# 7440-23-5 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
CAS# 7440-23-5: 10 lb final RQ; 4.54 kg final RQ
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
SARA Codes
CAS # 7440-23-5: immediate, fire, reactive.
Section 313
No chemicals are reportable under Section 313.
Clean Air Act:
This material does not contain any hazardous air pollutants.
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
CAS# 7440-23-5 is listed as a Hazardous Substance under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
None of the chemicals in this
product are listed as Toxic Pollutants under the CWA.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 7440-23-5 can be found on the
following state right to know lists: California, New Jersey,
Pennsylvania, Massachusetts.
California Prop 65
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
F C
Risk Phrases:
R 14/15 Reacts violently with water liberating extremely flammable
gases.
R 34 Causes burns.
Safety Phrases:
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S 5 Keep contents under ... (appropriate liquid to be specified by t
he manufacturer).
S 8 Keep container dry.
S 43H In case of fire, use dry chemical, soda ash, lime or sand. (D
o not use water or foam).
WGK (Water Danger/Protection)
CAS# 7440-23-5: 2
Canada - DSL/NDSL
CAS# 7440-23-5 is listed on Canada's DSL List.
Canada - WHMIS
This product has a WHMIS classification of B4, E, F.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
Section 16 - Additional Information
|
MSDS Creation Date: 11/07/2001
Revision #5 Date: 10/03/2005
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.