Material Safety Data Sheet
Fluorescein Mercuric Acetate, 96% (UV-Vis)
ACC# 92985
Section 1 - Chemical Product and Company Identification |
MSDS Name: Fluorescein Mercuric Acetate, 96% (UV-Vis)
Catalog Numbers:
AC410660000, AC410660100, AC410660250
Synonyms:
Fluorescein, 2',7'-Bis(Acetoxymercuri)-; Mercury, Bis(acetato)(mu-
(3',6'-Dihydroxy-2',7'-Fluorandiyl))di-.
Company Identification:
Acros Organics N.V.
One Reagent Lane
Fair Lawn, NJ 07410
For information in North America, call: 800-ACROS-01
For emergencies in the US, call CHEMTREC: 800-424-9300
Section 2 - Composition, Information on Ingredients
|
CAS# |
Chemical Name |
Percent |
EINECS/ELINCS |
3570-80-7 |
Fluorescein Mercuric Acetate |
96 | 222-673-1 |
Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
Appearance: red powder.
Danger! Toxic if swallowed, inhaled or absorbed
through the skin. May cause eye and skin irritation. May cause
respiratory and digestive tract irritation. Light sensitive. May
cause central nervous system effects. Danger of cumulative effects.
Dangerous for the environment. The toxicological properties of this
material have not been fully investigated.
Target Organs: Kidneys, central nervous system,
liver, lungs.
Potential Health Effects
Eye:
May cause eye irritation.
Skin:
May cause skin irritation. May be fatal if absorbed through the
skin.
Ingestion:
May be fatal if swallowed. May cause irritation of the digestive
tract. The toxicological properties of this substance have not been
fully investigated. Inorganic mercury compounds may cause central and
peripheral nervous system effects.
Inhalation:
May be fatal if inhaled. The toxicological properties of this
substance have not been fully investigated. Acute exposure to high
concentrations of mercury vapors may cause severe respiratory tract
irritation.
Chronic:
May cause kidney injury. Chronic exposure may lead to liver and lung
damage. Chronic exposure to mercury may cause permanent central
nervous system damage, fatigue, weight loss, tremors, personality
changes. Chronic ingestion may cause accumulation of mercury in body
tissues. Chronic exposure to mercury vapors may produce weakness,
fatigue, anorexia, loss of weight and gastrointestinal disturbances
which is collectively referred to as asthenic-vegetative syndrome or
micromercurialism. Chronic exposure to mercury compounds may produce
immunologic glomerular disease. May cause adverse reproductive
effects.
Section 4 - First Aid Measures
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Eyes:
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes. Wash clothing before reuse.
Ingestion:
Get medical aid immediately. Do NOT induce vomiting. If conscious
and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If breathing is difficult, give oxygen. Do NOT use
mouth-to-mouth resuscitation. If breathing has ceased apply
artificial respiration using oxygen and a suitable mechanical device
such as a bag and a mask.
Notes to Physician:
The concentration of mercury in whole blood is a reasonable measure
of the body-burden of mercury and thus is used for monitoring
purposes.
Section 5 - Fire Fighting Measures
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General Information:
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. During a fire, irritating and highly toxic gases
may be generated by thermal decomposition or combustion.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or appropriate foam.
Flash Point: Not applicable.
Autoignition Temperature: Not applicable.
Explosion Limits, Lower:Not available.
Upper: Not available.
NFPA Rating:
(estimated) Health: 3; Flammability: 0; Instability: 0
Section 6 - Accidental Release Measures
|
General Information: Use proper personal protective equipment as indicated
in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal
container. Clean up spills immediately, observing precautions in the
Protective Equipment section. Avoid generating dusty conditions.
Provide ventilation.
Section 7 - Handling and Storage
|
Handling:
Wash thoroughly after handling. Remove contaminated clothing and
wash before reuse. Use with adequate ventilation. Minimize dust
generation and accumulation. Avoid contact with eyes, skin, and
clothing. Keep container tightly closed. Avoid ingestion and
inhalation. Store protected from light.
Storage:
Store in a tightly closed container. Store in a cool, dry,
well-ventilated area away from incompatible substances. Poison room
locked. Store protected from light.
Section 8 - Exposure Controls, Personal Protection
|
Engineering Controls:
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
Exposure Limits
Chemical Name |
ACGIH |
NIOSH |
OSHA - Final PELs |
Fluorescein Mercuric Acetate
|
0.1 mg/m3 TWA (as Hg) (listed under Mercury, aryl and inorganic compounds).Skin - potential significant contribution to overall exposure by the cutaneous r oute (listed under Mercury, aryl and inorga
nic compounds).
|
0.05 mg/m3 TWA (vapor, except organo alkyls, as Hg) (listed under Mercury compounds).10 mg/m3 IDLH (as Hg, except Organo(alkyl) compounds) (listed under Mercury compounds).
|
none listed
|
OSHA Vacated PELs:
Fluorescein Mercuric Acetate:
No OSHA Vacated PELs are listed for this chemical.
Personal Protective Equipment
Eyes:
Wear appropriate protective eyeglasses or chemical
safety goggles as described by OSHA's eye and face
protection regulations in 29 CFR 1910.133 or European
Standard EN166.
Skin:
Wear appropriate protective gloves to prevent skin
exposure.
Clothing:
Wear appropriate protective clothing to prevent skin
exposure.
Respirators:
A respiratory protection program that meets OSHA's 29
CFR 1910.134 and ANSI Z88.2 requirements or European
Standard EN 149 must be followed whenever workplace
conditions warrant respirator use.
Section 9 - Physical and Chemical Properties
|
Physical State: Powder
Appearance: red
Odor: none reported
pH: Not available.
Vapor Pressure: Not available.
Vapor Density: Not available.
Evaporation Rate:Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point:0 deg C
Decomposition Temperature:Not available.
Solubility: Not available.
Specific Gravity/Density:Not available.
Molecular Formula:C24H16Hg2O9
Molecular Weight:849.57
Section 10 - Stability and Reactivity
|
Chemical Stability:
Stable under normal temperatures and pressures.
Conditions to Avoid:
Incompatible materials, light, dust generation, excess heat, strong
oxidants.
Incompatibilities with Other Materials:
Strong oxidizing agents, strong acids, acetylene.
Hazardous Decomposition Products:
Carbon monoxide, carbon dioxide, mercury/mercury oxides.
Hazardous Polymerization: Has not been reported
Section 11 - Toxicological Information
|
RTECS#:
CAS# 3570-80-7:
OV7352500
LD50/LC50:
Not available.
Carcinogenicity:
CAS# 3570-80-7:
Not listed by ACGIH, IARC, NTP, or CA Prop 65.
Epidemiology:
No information found
Teratogenicity:
No information found
Reproductive Effects:
No information found
Mutagenicity:
Mutagenic effects have occurred in experimental animals.
Neurotoxicity:
No information found
Other Studies:
Section 12 - Ecological Information
|
No information available.
Section 13 - Disposal Considerations
|
Chemical waste generators must determine whether a discarded chemical is classified
as a hazardous waste.
US EPA guidelines for the classification determination are listed in 40 CFR Parts 261.3.
Additionally, waste generators must consult state and local hazardous waste regulations to
ensure complete and accurate classification.
RCRA P-Series: None listed.
RCRA U-Series: None listed.
Section 14 - Transport Information
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US DOT |
Canada TDG |
Shipping Name: |
DOT regulated - small quantity provisions apply (see 49CFR173.4) |
No information available. |
Hazard Class: |
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UN Number: |
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Packing Group: |
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Section 15 - Regulatory Information
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US FEDERAL
TSCA
CAS# 3570-80-7 is listed on the TSCA inventory.
Health & Safety Reporting List
None of the chemicals are on the Health & Safety Reporting List.
Chemical Test Rules
None of the chemicals in this product are under a Chemical Test Rule.
Section 12b
None of the chemicals are listed under TSCA Section 12b.
TSCA Significant New Use Rule
None of the chemicals in this material have a SNUR under TSCA.
CERCLA Hazardous Substances and corresponding RQs
None of the chemicals in this material have an RQ.
SARA Section 302 Extremely Hazardous Substances
None of the chemicals in this product have a TPQ.
Section 313
This material contains Fluorescein
Mercuric Acetate (listed as Mercury compounds), 96%, (CAS#
3570-80-7) which is subject to the reporting requirements of Section
313 of SARA Title III and 40 CFR Part 373.
Clean Air Act:
CAS# 3570-80-7 (listed as Mercury compounds) is listed as a hazardous
air pollutant (HAP).
This material does not contain any Class 1 Ozone depletors.
This material does not contain any Class 2 Ozone depletors.
Clean Water Act:
None of the chemicals in this product
are listed as Hazardous Substances under the CWA.
None of the chemicals in this
product are listed as Priority Pollutants under the CWA.
CAS# 3570-80-7 is listed as a Toxic Pollutant under the Clean Water
Act.
OSHA:
None of the chemicals in this product
are considered highly hazardous by OSHA.
STATE
CAS# 3570-80-7 can be found on the
following state right to know lists: California, (listed as Mercury
compounds), New Jersey, (listed as Mercury, aryl and inorganic
compounds), Pennsylvania, (listed as Mercury compounds),
Pennsylvania, (listed as Mercury, aryl and inorganic compounds).
California Prop 65
WARNING: This product contains Fluorescein Mercuric Acetate, listed
as `Mercury compounds', a chemical known to the state of California
to cause developmental reproductive toxicity.
California No Significant Risk Level:
None of the chemicals in this product are listed.
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols:
T+ N
Risk Phrases:
R 26/27/28 Very toxic by inhalation, in contact with skin and if
swallowed.
R 33 Danger of cumulative effects.
R 50/53 Very toxic to aquatic organisms, may cause long-term
adverse effects in the aquatic environment.
Safety Phrases:
S 13 Keep away from food, drink and animal feeding stuffs.
S 36 Wear suitable protective clothing.
S 37 Wear suitable gloves.
S 45 In case of accident or if you feel unwell, seek medical advice
immediately (show the label where possible).
S 28A After contact with skin, wash immediately with plenty of water
.
WGK (Water Danger/Protection)
CAS# 3570-80-7: No information available.
Canada - DSL/NDSL
CAS# 3570-80-7 is listed on Canada's NDSL List.
Canada - WHMIS
This product has a WHMIS classification of D1A, D2A.
This product has been classified in accordance with the hazard
criteria of the Controlled Products Regulations and the MSDS
contains all of the information required by those regulations.
Canadian Ingredient Disclosure List
CAS# 3570-80-7 is listed on the Canadian Ingredient Disclosure List.
Section 16 - Additional Information
|
MSDS Creation Date: 7/08/1999
Revision #4 Date: 11/20/2008
The information above is believed to be accurate and represents the best
information currently available to us. However, we make no warranty of
merchantability or any other warranty, express or implied, with respect to
such information, and we assume no liability resulting from its use. Users
should make their own investigations to determine the suitability of the
information for their particular purposes. In no event shall Fisher be liable
for any claims, losses, or damages of any third party or for lost profits
or any special, indirect, incidental, consequential or exemplary
damages, howsoever arising, even if Fisher has been advised of
the possibility of such damages.